Misplaced Pages

Cerium(III) acetylacetonate

Article snapshot taken from[REDACTED] with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Cerium acetylacetonate)
Cerium(III) acetylacetonate
Names
IUPAC name cerium; (Z)-4-hydroxypent-3-en-2-one
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.094 Edit this at Wikidata
EC Number
  • 239-720-7
PubChem CID
InChI
  • InChI=1S/3C5H8O2.Ce/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;Key: PYPNFSVOZBISQN-LNTINUHCSA-K
  • InChI=1/3C5H8O2.Ce/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;Key: PYPNFSVOZBISQN-QQVDQASFBR
SMILES
  • .O=C(/C=C(\)C)C.\C(=C/C(=O)C)C.\C(=C/C(=O)C)C
Properties
Chemical formula C15H21CeO6
Molar mass 437.443 g·mol
Appearance Crystalline powder
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Cerium(III) acetylacetonate is a compound with formula Ce(C5H7O2)3(H2O)x. It is typically isolated as the trihydrate. Partial dehydration gives the dihydrate, a red-brown solid.

Reactions

Cerium acetylacetonate is a precursor to mesoporous nanocrystalline ceria using the sol-gel process. It can also be used along with gadolinium acetylacetonate to synthesize gadolinia-doped ceria (GDC) gel powders.

See also

  • Cerium(IV) tetrakis(acetylacetonate)

References

  1. Cerium acetylacetonate at American Elements
  2. Behrsing, Thomas; Bond, Alan M.; Deacon, Glen B.; Forsyth, Craig M.; Forsyth, Maria; Kamble, Kalpana J.; Skelton, Brian W.; White, Allan H. (2003). "Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O". Inorganica Chimica Acta. 352: 229–237. doi:10.1016/S0020-1693(03)00147-6.
  3. "Formation of mesoporous nanocrystalline ceria from cerium nitrate, acetate or acetylacetonate"
  4. "Synthesis of Gadolinia-Doped Ceria Gels and Powders from Acetylacetonate Precursors"
Cerium compounds
Cerium(II)
Cerium(III)
Organocerium(III)
Cerium(III,IV)
Cerium(IV)
Metal acetylacetonate complexes
H(acac) He
Li Be B C N O F Ne
Na(acac) Mg Al(acac)3 Si P S Cl Ar
K Ca Sc(acac)3 Ti(acac)2Cl2
Ti(acac)3 		V(acac)3
VO(acac)2 		Cr(acac)2
Cr(acac)3 		Mn Fe(acac)2
Fe(acac)3 		Co(acac)2
Co(acac)3 		3 Cu(acac)2 Zn(acac)2 Ga(acac)3 Ge As Se Br Kr
Rb Sr Y(acac)3 Zr(acac)4 Nb MoO2(acac)2 Tc Ru(acac)3 Rh(acac)(CO)2
Rh(acac)3 		Pd(acac)2 Ag Cd In(acac)3 Sn Sb Te I Xe
Cs Ba(acac)2 * Lu(acac)3 Hf(acac)4 Ta W Re Os Ir(acac)3 Pt(acac)2 Au Hg Tl(acac) Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(acac)3 Ce(acac)3 Pr(acac)3 Nd(acac)3 Pm Sm(acac)3 Eu(fod)3
Eu(acac)3 		Gd(acac)3 Tb(acac)3 Dy(acac)3 Ho(acac)3 Er(acac)3 Tm(acac)3 Yb(acac)3
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
Stub icon

This article about an organic compound is a stub. You can help Misplaced Pages by expanding it.

Categories:
Cerium(III) acetylacetonate Add topic