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Chloritoid

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Chloritoid
Chloritoid crystal group on matrix from Nuristan Province, Afghanistan (size:6.3 x 3.5 x 3.0 cm)
General
CategoryNesosilicates
Formula
(repeating unit)
(Fe,Mg,Mn)
2Al
4Si
2O
10(OH)
4
IMA symbolCld
Strunz classification9.AF.85
Dana classification52.03.03.01
Crystal system1A polytype: triclinic
2M polytype: monoclinic
Crystal class1A polytype: pinacoidal (1)
2M polytype: prismatic (2/m)
Unit cell1A polytype: a = 9.46 Å,
b = 5.50 Å, c = 9.15 Å;
α = 97.05°, β = 101.56°,
γ = 90.10°
2M polytype: a = 9.50 Å,
b = 5.50 Å, c = 18.22 Å;
β = 101.9°; Z = 4
Identification
ColorDark gray, greenish gray, greenish black
Crystal habitTabular pseudohexagonal crystals; rosettes, commonly coarsely foliated with foliae typically curved or bent; also massive
TwinningCommon on {001}, polysynthetic may be lamellar
CleavagePerfect on {001}, distinct on {110}; parting on {010}
TenacityBrittle
Mohs scale hardness6.5
Lusterpearly on cleavage surfaces
StreakWhite, grayish, or very slightly greenish
DiaphaneityTranslucent
Specific gravity3.46 – 3.80
Optical propertiesBiaxial (+) or (−)
Refractive indexnα = 1.713 – 1.730 nβ = 1.719 – 1.734 nγ = 1.723 – 1.740
Birefringenceδ = 0.010
PleochroismX = olive-green to yellow; Y = grayish blue to blue; Z = colorless to pale greenish yellow
2V angleMeasured: 36° to 89°
Dispersionr > v; strong
References

Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.

Both monoclinic and triclinic polytypes exist and both are pseudohexagonal.

It was first described in 1837 from localities in the Ural Mountains region of Russia. It was named for its similarity to the chlorite group of minerals.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Handbook of Mineralogy
  3. ^ Mindat
  4. ^ Webmineral data
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