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Dichloro(1,5-cyclooctadiene)palladium

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Dichloro(1,5-cyclooctadiene)palladium
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.953 Edit this at Wikidata
EC Number
  • 235-161-8
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;Key: RRHPTXZOMDSKRS-PHFPKPIQSA-L
SMILES
  • C1CC=CCCC=C1.ClCl
Properties
Chemical formula C8H12Cl2Pd
Molar mass 285.50 g·mol
Appearance yellow solid
Density 2.045 g/cm
Melting point 210 °C (410 °F; 483 K)
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Hazard statements H315, H319, H335
Precautionary statements P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Dichloro(1,5-cyclooctadiene)palladium is the organopalladium compound with the formula PdCl2(C8H12) where C8H12 is cycloocta-1,5-diene (cod) or abbreviated PdCl2(cod). It is a yellow solid that is soluble in chloroform. According to X-ray crystallography, the Pd center is square planar. This complex can be synthesized by reaction of tetrachloropalladate in hydrochloric acid with cycloocta-1,5-diene.

See also

References

  1. Shomir Ghosh; Xiang Wang; Anil Guram (2009). "Dichloro(1,5-cyclooctadiene)palladium(II)". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rd113.pub2. ISBN 978-0471936237.
  2. R. Kumar; A. W. Maverick; F. R. Fronczek; J. R. Doyle; N. C. Baenziger; M. A. M. Howells (1993). "The Pbca polymorph of dichloro(η-1,5-cyclooctadiene)palladium(II)". Acta Crystallogr. C. 49 (10): 1766–1767. Bibcode:1993AcCrC..49.1766K. doi:10.1107/S0108270193003889.
  3. Drew, D.; Doyle, J. R.; Shaver, A. G. (1972). "Cyclic Diolefin Complexes of Platinum and Palladium". Inorganic Syntheses. Vol. 13. pp. 47–55. doi:10.1002/9780470132449.ch11. ISBN 978-0-470-13172-5.


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