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The municipality Pangaio was formed at the 2011 local government reform by the merger of the following 5 former municipalities, that became municipal units:
The municipality has an area of 701.427 km, the municipal unit 79.634 km.
Province
The province of Pangaio (Greek: Επαρχία Παγγαίου) was one of the provinces of the Kavala Prefecture. It had the same territory as the present municipality, except a part of the municipal unit Eleftheroupoli. It was abolished in 2006.