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Tin(IV) iodate

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Tin(IV) iodate
Names
IUPAC name triiodyloxystannyl iodate
Identifiers
CAS Number
3D model (JSmol)
PubChem CID
InChI
  • InChI=1S/4HIO3.Sn/c4*2-1(3)4;/h4*(H,2,3,4);/q;;;;+4/p-4Key: WGVVTQUSFDMILB-UHFFFAOYSA-J
SMILES
  • O=I(=O)O(OI(=O)=O)(OI(=O)=O)OI(=O)=O
Properties
Chemical formula Sn(IO3)4
Molar mass 818.29
Appearance colourless columnal crystals
Density 5.107 g·cm（23 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Tin(IV) iodate is an inorganic compound with the chemical formula Sn(IO3)4. It was first obtained in 2020 through the hydrothermal reaction of tin(II) oxide and iodic acid in water at 220 °C. It is a colorless columnar crystal, crystallized in the triclinic P1 space group. It has an indirect band gap (experimental 4.0 eV; calculated 2.75 eV).

References

  1. ^ Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
  2. Liang, Akun; Rodriguez-Hernandez, Placida; Muñoz, Alfonso; Rahman, Saqib; Segura, Alfredo; Errandonea, Daniel (2021). "Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons". Inorganic Chemistry Frontiers. 8 (22): 4780–4790. doi:10.1039/D1QI00870F. ISSN 2052-1553.
Tin compounds
Sn(II)
Sn(IV)
Iodates
HIO3 He
LiIO3 Be +BO3 C (NH4)IO3
+NO3 		O +F
-F 		Ne
NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
Fe(IO3)3 		Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
Hg(IO3)2 		TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No


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