Misplaced Pages

Tridecylic acid

Article snapshot taken from[REDACTED] with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Tridecanoic acid)
Tridecylic acid
Skeletal formula of tridecylic acid
Skeletal formula of tridecylic acid
Ball-and-sitck model of tridecylic acid
Ball-and-sitck model of tridecylic acid
Names
Preferred IUPAC name Tridecanoic acid
Other names C13:0 (Lipid numbers)
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.010.311 Edit this at Wikidata
EC Number
  • 211-341-1
PubChem CID
RTECS number
  • YD3850000
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C13H26O2/c1-2-3-4-5-6-7-8-9-10-11-12-13(14)15/h2-12H2,1H3,(H,14,15)Key: SZHOJFHSIKHZHA-UHFFFAOYSA-N
SMILES
  • O=C(O)CCCCCCCCCCCC
Properties
Chemical formula C13H26O2
Molar mass 214.349 g·mol
Appearance White crystals or powder
Odor Waxy-type
Density 0.983 g/cm (37 °C)
0.8458 g/cm (80 °C)
Melting point 41.5 °C (106.7 °F; 314.6 K)
Boiling point 236 °C (457 °F; 509 K)
at 100 mmHg
140 °C (284 °F; 413 K)
at 1 mmHg
Solubility in water 21 mg/L (0 °C)
33 mg/L (20 °C)
38 mg/L (30 °C)
53 mg/L (60 °C)
Solubility Soluble in alcohol, ether, CH3COOH
Solubility in acetone 7.52 g/100 g (0 °C)
78.6 g/100 g (20 °C)
316 g/100 g (30 °C)
8.23 kg/100 g (40 °C)
Solubility in methanol 12.6 g/100 g (0 °C)
148 g/100 g (20 °C)
515 g/100 g (30 °C)
Solubility in benzene 42.4 g/100 g (10 °C)
117 g/100 g (20 °C)
354 g/100 g (30 °C)
Solubility in ethyl acetate 10.1 g/100 g (0 °C)
70 g/100 g (20 °C)
281 g/100 g (30 °C)
Vapor pressure 0.01 kPa (109 °C)
0.47 kPa (160 °C)
3.21 kPa (200 °C)
100 kPa (311.5 °C)
Refractive index (nD) 1.4286 (50 °C)
Viscosity 0.583 cP (120 °C)
0.3991 cP (160 °C)
0.2934 cP (200 °C)
Structure
Crystal structure Monoclinic (37 °C)
Space group C2/c
Lattice constant a = 59.88 Å, b = 4.9425 Å, c = 9.8118 Åα = 90°, β = 93.8°, γ = 90°
Thermochemistry
Heat capacity (C) 387.6 J/mol·K
Std enthalpy of
formation
fH298)
−807.2 kJ/mol (liquid)
Std enthalpy of
combustion
cH298)
8024.2 kJ/mol (liquid)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Irritant
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Hazard statements H315, H319, H335
Precautionary statements P261, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2 1 0
Flash point 113 °C (235 °F; 386 K)
Lethal dose or concentration (LD, LC):
LD50 (median dose) 130 mg/kg (mice, intravenous)
Related compounds
Related compounds Dodecanoic acid, Tetradecanoic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Tridecylic acid, or tridecanoic acid, is the organic compound with the formula CH3(CH2)11CO2H. It is a 13-carbon saturated fatty acid. It is a white solid.

A laboratory preparation involves permanganate oxidation of 1-tetradecene (CH3(CH2)12CH=CH2).

See also

References

  1. ^ Bond, Andrew D. (2003). "On the crystal structures and melting point alternation of the n-alkyl carboxylic acids" (PDF). rsc.org. Royal Society of Chemistry. Retrieved 2014-06-15.
  2. ^ Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
  3. ^ Seidell, Atherton; Linke, William F. (1940). Solubilities of Inorganic and Organic Compounds (3rd ed.). New York: D. Van Nostrand Company. p. 756.
  4. ^ Tridecanoic acid in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-06-17)
  5. Yaws, Carl L. (2009). Transport Properties of Chemicals and Hydrocarbons. New York: William Andrew Inc. p. 174. ISBN 978-0-8155-2039-9.
  6. ^ Sigma-Aldrich Co., Tridecanoic acid. Retrieved on 2014-06-17.
  7. ^ "MSDS of n-Tridecanoic acid". fishersci.ca. Fisher Scientific. Retrieved 2014-06-17.
  8. Lee DG, Lamb SE, Chang VS (1981). "Carboxylic Acids from the Oxidation of Terminal Alkenes by Permanganate: Nonadecanoic Acid". Organic Syntheses. 60: 11. doi:10.15227/orgsyn.060.0011.
Lipids: fatty acids
Saturated
ω−3 Unsaturated
ω−5 Unsaturated
ω−6 Unsaturated
ω−7 Unsaturated
ω−9 Unsaturated
ω−10 Unsaturated
ω−11 Unsaturated
ω−12 Unsaturated


Stub icon

This article about an organic compound is a stub. You can help Misplaced Pages by expanding it.

Categories:
Tridecylic acid Add topic