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Yttrium acetylacetonate

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Yttrium acetylacetonate
Identifiers
CAS Number
ECHA InfoCard 100.035.991 Edit this at Wikidata
Properties
Chemical formula C15H27O9Y
Molar mass 440.278 g·mol
Melting point 131 °C (404 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Yttrium acetylacetonate is a coordination compound with the chemical formula Y(C5H7O2)3(H2O)x, or Y(acac)3(H2O)x for short. The value of x can vary from 1 to 3.

Upon heating under vacuum, the hydrates convert to the oxo-cluster Y4O(C5H7O2)10. This behavior is also observed for gadolinium acetylacetonate, europium acetylacetonate, lanthanum acetylacetonate, and erbium acetylacetonate.


References

  1. Jantsch, G.; Meyer, E. Addition compounds in the acetylacetonates of the rare earths. Berichte der Deutschen Chemischen Gesellschaft B: Abhandlungen, 1920. 53B: 1577-1587. ISSN 0365-9488.
  2. Cunningham, James A.; Sands, Donald E.; Wagner, William Frederick (1967). "Crystal and Molecular Structure of Yttrium Acetylacetonate Trihydrate". Inorganic Chemistry. 6 (3): 499–503. doi:10.1021/ic50049a014.
  3. Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael (2020). "Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters". Nat. Catal. 3 (2): 154–162. doi:10.1038/s41929-019-0405-5. S2CID 209897045.
Yttrium compounds
Yttrium(II)
Yttrium(III)
Organoyttrium(III) compounds
  • Y(C5H5)3
  • Y2(C2O4)3
  • Metal acetylacetonate complexes
    H(acac) He
    Li Be B C N O F Ne
    Na(acac) Mg Al(acac)3 Si P S Cl Ar
    K Ca Sc(acac)3 Ti(acac)2Cl2
    Ti(acac)3
    V(acac)3
    VO(acac)2
    Cr(acac)2
    Cr(acac)3
    Mn Fe(acac)2
    Fe(acac)3
    Co(acac)2
    Co(acac)3
    3 Cu(acac)2 Zn(acac)2 Ga(acac)3 Ge As Se Br Kr
    Rb Sr Y(acac)3 Zr(acac)4 Nb MoO2(acac)2 Tc Ru(acac)3 Rh(acac)(CO)2
    Rh(acac)3
    Pd(acac)2 Ag Cd In(acac)3 Sn Sb Te I Xe
    Cs Ba(acac)2 * Lu(acac)3 Hf(acac)4 Ta W Re Os Ir(acac)3 Pt(acac)2 Au Hg Tl(acac) Pb Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(acac)3 Ce(acac)3 Pr(acac)3 Nd(acac)3 Pm Sm(acac)3 Eu(fod)3
    Eu(acac)3
    Gd(acac)3 Tb(acac)3 Dy(acac)3 Ho(acac)3 Er(acac)3 Tm(acac)3 Yb(acac)3
    ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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