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{{Chembox
{{orphan|date=January 2025}}
<!-- Images -->

⚫ | ImageFile = R-salt.png
{{chembox
| ImageSize = 180px
⚫ |ImageFile = R-salt.png
| ImageAlt =
<!-- Names -->
| IUPACName =
| OtherNames = {{ubl|TNX|Hexahydro-1,3,5-trinitroso-1,3,5-triazine|Trinitrosotrimethylenetriamine}}
<!-- Sections -->
| Section1 = {{Chembox Identifiers
| CASNo = 13980-04-6
| Beilstein = 14853
| ChEBI = 24557
| ChEMBL = 352556
| ChemSpiderID = 24566
| EC_number = 237-766-2
| PubChem = 26368
| UNII = MK86FR3SN8
| SMILES = C1N(CN(CN1N=O)N=O)N=O
| InChI = 1S/C3H6N6O3/c10-4-7-1-8(5-11)3-9(2-7)6-12/h1-3H2
| InChIKey = HFWOSHMLDRSIDN-UHFFFAOYSA-N
}}
| Section2 = {{Chembox Properties
| C = 3 | H = 6 | N = 6 | O = 3
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
| Solubility =
}}
| Section3 = {{Chembox Explosive
| Explosive_ref =
| ShockSens =
| FrictionSens =
| DetonationV =
| REFactor =
}}
| Section4 = {{Chembox Hazards
| GHS_ref=
| GHSPictograms = {{GHS06}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|301}}
| PPhrases = {{P-phrases|264|270|301+316|321|330|405|501}}
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}
}} }}


'''R-salt''' ('''TNX''', ] '''hexahydro-1,3,5-trinitroso-1,3,5-triazine'''), is an ] that has been used as an ].<ref name="Wilkins">{{cite journal |doi=10.1002/prep.202400028 |title=A comprehensive study on the thermal properties and chemical characterization of 1,3,5-trinitroso-1,3,5-triazine (R-Salt) |date=2024 |last1=Wilkins |first1=Benjamin |last2=Sartain |first2=Hope T. |last3=Schneidereit |first3=Sheana |last4=Ostrow |first4=Benjamin |last5=Aparicio |first5=Joaquin |last6=Horan |first6=Andrew |last7=Pedersen |first7=Kevin |last8=Barber |first8=Jeffrey |last9=Perez |first9=Johnny |last10=Richard |first10=Marc |last11=Pollock |first11=Elizabeth |last12=Brady |first12=John |journal=Propellants, Explosives, Pyrotechnics |volume=49 |issue=6 }}</ref> It is a ], that less ] than other compounds of similar availability.<ref name="Wilkins"/> It has a similar structure to ]—TNX has ] groups as compared to the ] groups of RDX—but is less commonly used. It is also found as a decomposition product of RDX in the environment, such as after RDX detonation.<ref>{{cite journal |doi=10.1002/prep.201600149 |title=An Improved Process Towards Hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX) |date=2017 |last1=Rothstein |first1=Sarah A. |last2=Dubé |first2=Pascal |last3=Anderson |first3=Stephen R. |journal=Propellants, Explosives, Pyrotechnics |volume=42 |issue=2 |pages=126–130 }}</ref> Using chemistry similar to the synthesis of RDX, R-salt can be synthesized by reaction of ] with ] in the presence of an acid catalyst.<ref name="Wilkins"/> '''R-salt''' ('''TNX''', ] '''hexahydro-1,3,5-trinitroso-1,3,5-triazine'''), is an ] that has been used as an ].<ref name="Wilkins">{{cite journal |doi=10.1002/prep.202400028 |title=A comprehensive study on the thermal properties and chemical characterization of 1,3,5-trinitroso-1,3,5-triazine (R-Salt) |date=2024 |last1=Wilkins |first1=Benjamin |last2=Sartain |first2=Hope T. |last3=Schneidereit |first3=Sheana |last4=Ostrow |first4=Benjamin |last5=Aparicio |first5=Joaquin |last6=Horan |first6=Andrew |last7=Pedersen |first7=Kevin |last8=Barber |first8=Jeffrey |last9=Perez |first9=Johnny |last10=Richard |first10=Marc |last11=Pollock |first11=Elizabeth |last12=Brady |first12=John |journal=Propellants, Explosives, Pyrotechnics |volume=49 |issue=6 }}</ref> It is a ], that is less ] than other compounds of similar availability.<ref name="Wilkins"/> It has a similar structure to ]—TNX has ] groups as compared to the ] groups of RDX—but is less commonly used. It is also found as a decomposition product of RDX in the environment, such as after RDX detonation.<ref>{{cite journal |doi=10.1002/prep.201600149 |title=An Improved Process Towards Hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX) |date=2017 |last1=Rothstein |first1=Sarah A. |last2=Dubé |first2=Pascal |last3=Anderson |first3=Stephen R. |journal=Propellants, Explosives, Pyrotechnics |volume=42 |issue=2 |pages=126–130 }}</ref> Using chemistry similar to the synthesis of RDX, R-salt can be synthesized by reaction of ] with ] in the presence of an acid catalyst.<ref name="Wilkins"/>


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Latest revision as of 05:41, 9 January 2025

R-salt
Names
Other names
  • TNX
  • Hexahydro-1,3,5-trinitroso-1,3,5-triazine
  • Trinitrosotrimethylenetriamine
Identifiers
CAS Number
3D model (JSmol)
Beilstein Reference 14853
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.034.319 Edit this at Wikidata
EC Number
  • 237-766-2
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C3H6N6O3/c10-4-7-1-8(5-11)3-9(2-7)6-12/h1-3H2Key: HFWOSHMLDRSIDN-UHFFFAOYSA-N
SMILES
  • C1N(CN(CN1N=O)N=O)N=O
Properties
Chemical formula C3H6N6O3
Molar mass 174.120 g·mol
Hazards
GHS labelling:
Pictograms GHS06: Toxic
Signal word Danger
Hazard statements H301
Precautionary statements P264, P270, P301+P316, P321, P330, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

R-salt (TNX, systematic name hexahydro-1,3,5-trinitroso-1,3,5-triazine), is an organic compound that has been used as an homemade explosive. It is a high explosive, that is less sensitive than other compounds of similar availability. It has a similar structure to RDX—TNX has nitrosamine groups as compared to the nitroamine groups of RDX—but is less commonly used. It is also found as a decomposition product of RDX in the environment, such as after RDX detonation. Using chemistry similar to the synthesis of RDX, R-salt can be synthesized by reaction of hexamine with nitrous acid in the presence of an acid catalyst.

References

  1. ^ Wilkins, Benjamin; Sartain, Hope T.; Schneidereit, Sheana; Ostrow, Benjamin; Aparicio, Joaquin; Horan, Andrew; Pedersen, Kevin; Barber, Jeffrey; Perez, Johnny; Richard, Marc; Pollock, Elizabeth; Brady, John (2024). "A comprehensive study on the thermal properties and chemical characterization of 1,3,5-trinitroso-1,3,5-triazine (R-Salt)". Propellants, Explosives, Pyrotechnics. 49 (6). doi:10.1002/prep.202400028.
  2. Rothstein, Sarah A.; Dubé, Pascal; Anderson, Stephen R. (2017). "An Improved Process Towards Hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX)". Propellants, Explosives, Pyrotechnics. 42 (2): 126–130. doi:10.1002/prep.201600149.
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