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{{two other uses| |
{{two other uses|a contested field of scientific research|the computer programming language|ColdFusion|the ''Doctor Who'' novel|Cold Fusion (Doctor Who)}} | ||
] (2005)]] | ] (2005)]] | ||
'''Cold fusion''' is a controversial effect reported by some researchers to have been produced from ] at conditions near ] and ]. | |||
'''Cold fusion''', sometimes called '''low energy nuclear reactions''' (LENR) or '''condensed matter nuclear science''', is a set of effects reported in controversial laboratory experiments at ordinary temperatures and pressures, which some researchers say is caused by ]s. | |||
The first report of such an effect was published by ] and ] from the University of Utah in 1989.<ref name="FleischmannPons_1989_301">{{harvnb|Fleischmann|Pons|1989|p=301}}.</ref> In their paper, they reported the observation of anomalous heating ("excess heat") of an electrolytic cell during ] of ]. Lacking an explanation for the source of such heat, they proposed the ], without supporting evidence, that the heat came from ] of ]. It raised hopes of a cheap and abundant source of energy.<ref name="Browne_1989_para1">{{harvnb|Browne|1989|loc=para. 1}}.</ref> | |||
In 1989, ] and ] reported producing a tabletop nuclear fusion reaction at the University of Utah.<ref name="FleischmannPons_1989_301">{{harvnb|Fleischmann|Pons|1989|p=301}}.</ref> In their press conferences and papers, they reported the observation of anomalous heating ("excess heat") of an electrolytic cell during ] of ] using ] (Pd) electrodes. Lacking an explanation for the source of such heat, they proposed the ] that the heat came from ] of ] (D). The report of their results raised hopes of a cheap and abundant source of energy.<ref name="Browne_1989_para1">{{harvnb|Browne|1989|loc=para. 1}}.</ref> | |||
Cold fusion gained a reputation as a ] after other scientists failed to replicate the results.<ref name="Browne_1989_para29">{{harvnb|Browne|1989|loc=para. 29}}.</ref> A review panel organized by the ] (DOE) in 1989 did not find the evidence persuasive, and said that such "nuclear fusion at room temperature would be contrary to all understanding gained of nuclear reactions in the last half century" and "it would require the invention of an entirely new nuclear process."<ref name="DOE_1989_37">{{harvnb|US DOE|1989|Ref=DOE1989|p=37}}.</ref> | |||
Since then, other reports of anomalous heat production and anomalous ] production have been reported in ] journals{{Ref_label|heat_tritium_reports|α|none}} and have been discussed at scientific conferences.<ref>{{harvnb|Van Noorden|2007|loc=para. 2}}.</ref> | Cold fusion gained a reputation as ] after other scientists failed to replicate the results.<ref name="Browne_1989_para29">{{harvnb|Browne|1989|loc=para. 29}}.</ref> A review panel organized by the ] (DOE) in 1989 did not find the evidence persuasive. Since then, other reports of anomalous heat production and anomalous ] production have been reported in ] journals{{Ref_label|heat_tritium_reports|α|none}} and have been discussed at scientific conferences.<ref>{{harvnb|Van Noorden|2007|loc=para. 2}}.</ref><ref>{{harvnb|Chubb et al.|2006|Ref=APS2006}}.</ref> Most scientists have met these reports with ].<ref>{{harvnb|Feder|2005}},{{harvnb|Hutchinson|2006}},{{harvnb|Kruglinksi|2006}}</ref> In 2004 the US DOE organized another review panel ({{harvnb|US DOE|2004|Ref=DOE2004r}}) which—like the one in 1989—did not recommend a focused federally-funded program for low energy nuclear reactions. The 2004 panel identified basic research areas that could be helpful in resolving some of the controversies in the field. It stated that the field would benefit from the peer-review processes associated with proposal submission to agencies and paper submission to archival academic journals. | ||
<ref>''cf.'' {{harvnb|Chubb et al.|2006|Ref=APS2006}}.</ref> Most scientists have met these reports with ]. <ref>{{harvnb|Feder|2005}}</ref> In 2004 the US DOE organized another review panel ({{harvnb|US DOE|2004|Ref=DOE2004r}}) which—like the one in 1989—did not recommend a focused federally-funded program for low energy nuclear reactions. The 2004 panel identified basic research areas that could be helpful in resolving some of the controversies in the field. They stated that the field would benefit from the peer-review processes associated with proposal submission to agencies and paper submission to archival journals. | |||
Since 2004, two peer-reviewed literature reviews have concluded that cold fusion has been demonstrated by experiments that result in excess heat production and ] products such as ].<ref name="Hubler_2007">{{harvnb|Hubler|2007}}.</ref><ref name="Biberian_2007">{{harvnb|Biberian|2007}}.</ref> The reviews stated that although many explanations have been proposed, several of which do not use new physics, none is yet satisfactory. | |||
==Ongoing controversy== | |||
==History== | |||
The 1989 DOE panel said that it was not possible to state categorically that cold fusion has been convincingly either proved or disproved,<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}.</ref>. The nearly unanimous opinion of the reviewers in the 2004 review was that funding agencies should entertain individual, well-designed proposals for experiments that address specific scientific issues relevant to the question of whether or not there is anomalous energy production in Pd/D systems, or whether or not D-D fusion reactions occur at energies on the order of a few eV. These proposals should meet accepted scientific standards, and undergo the rigors of peer review. No reviewer recommended a focused federally funded program for low energy nuclear reactions.<ref name="DOEr_2004_5">{{harvnb|US DOE|2004|Ref=DOE2004r|p=5}}.</ref> | |||
===Early work=== | |||
The special ability of palladium to absorb hydrogen was recognized as early as the nineteenth century by ].<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> In the late nineteen-twenties, two ] scientists, ] and K. Peters, reported the transformation of hydrogen into helium by spontaneous nuclear catalysis when hydrogen was absorbed by finely divided palladium at room temperature.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> These authors later acknowledged that the helium they measured was due to background from the air. | |||
In 1927, ] scientist J. Tandberg stated that he had fused hydrogen into helium in an ] with palladium electrodes.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> On the basis of his work, he applied for a Swedish patent for "a method to produce helium and useful reaction energy". After deuterium was discovered in 1932, Tandberg continued his experiments with ]. Due to Paneth and Peters' retraction, Tandberg's patent application was eventually denied.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> | |||
The skepticism towards cold fusion results from 3 issues: the lack of consistently reproducible results, the absence of nuclear products in quantities consistent with the excess heat, and the lack of a mainstream theoretical mechanism.<ref name="DOE_1989_6_8">{{harvnb|US DOE|1989|Ref=DOE1989|pp=6-8}}.</ref> | |||
The term "cold fusion" was coined by Dr. Paul Palmer of ] in 1986 in an investigation of "geo-fusion", or the possible existence of fusion in a ].<ref name="Kowalski_2004_IIA2">{{harvnb|Kowalski|2004|loc=II.A2}}.</ref> | |||
===Reproducibility of the result=== | |||
The cold fusion researchers who presented their review document to the 2004 DoE panel on cold fusion said that the observation of excess heat has been reproduced, that it can be reproduced at will under the proper conditions, and that many of the reasons for failure to reproduce it have been discovered.<ref name="DOE_2004_14">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=14}}.</ref> Despite the assertions of these researchers, most reviewers stated that the effects are not repeatable.<sup>''cf.''</sup> <ref name="DOE_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
===Fleischmann-Pons announcement=== | |||
In 1989, the DoE panel noted that "Even a single short but valid cold fusion period would be revolutionary. As a result, it is difficult convincingly to resolve all cold fusion claims since, for example, any good experiment that fails to find cold fusion can be discounted as merely not working for unknown reasons."<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}.</ref> | |||
Fleischmann said that he began investigating the possibility that ] could influence nuclear processes in the 1960s.<ref name="Fleischmann_2003_1">{{harvnb|Fleischmann|2003|p=1}}.</ref> He said that he explored whether collective effects, that would require ] to calculate, might be more significant than the effects predicted by ] calculations.<ref name="Fleischmann_2003_3">{{harvnb|Fleischmann|2003|p=3}}.</ref><ref>{{harvnb|Leggett|1989}}.</ref> He said that, by 1983, he had experimental evidence leading him to believe that condensed phase systems developed ] structures up to 10<sup>-7</sup>m in size.<ref name="Fleischmann_2003_3">{{harvnb|Fleischmann|2003|p=3}}.</ref> In 1984, Fleischmann and Pons began cold fusion experiments.<ref>{{harvnb|Lewenstein|1994}} p. 21.</ref> | |||
] | |||
===Nuclear products=== | |||
In their original set-up, Fleischmann and Pons used a ] (a double-walled vacuum flask) for the ], so that heat conduction would be minimal on the side and the bottom of the cell (only 5 % of the heat loss in this experiment). The cell flask was then submerged in a bath maintained at constant temperature to eliminate the effect of external heat sources. They used an open cell, thus allowing the ]eous deuterium and oxygen resulting from the electrolysis reaction to leave the cell, along with some heat. It was necessary to replenish the cell with ] at regular intervals. The authors said that, since the cell was tall and narrow, the bubbling action of the gas kept the electrolyte well mixed and of a uniform temperature. Special attention was paid to the purity of the palladium cathode and electrolyte to prevent the build-up of material on its surface, especially after long periods of operation. | |||
If the excess heat were generated by the fusion of 2 ] nuclei, the most probable outcome would be the generation of either a ] nucleus and a proton, or a <sup>3</sup>He and a ]. The level of neutrons, tritium and <sup>3</sup>He actually observed in Fleischmann-Pons experiment have been well below the level expected in view of the heat generated, implying that these fusion reactions cannot explain it. If the excess heat were generated by the fusion of 2 deuterium nuclei into <sup>4</sup>He, a reaction which is normally extremely rare, ]s and helium would be generated. In 1989, insufficient levels of helium and gamma rays have been observed to explain the excess heat.<ref name="DOE_1989_5_6">{{harvnb|US DOE|1989|Ref=DOE1989|pp=5-6}}.</ref> | |||
The cell was also instrumented with a ] to measure the temperature of the ], and an electrical heater to generate pulses of heat and calibrate the heat loss due to the gas outlet. After ], it was possible to compute the heat generated by the reaction.<ref name="FleischmannPons_1989_301">{{harvnb|Fleischmann|Pons|1989|p=301}}.</ref> | |||
The cold fusion researchers who presented their report to the 2004 DoE panel said that, since then, three independent studies have shown that the rate of helium production measured in the gas stream varies linearly with excess power.<ref name="DOE_2004_8">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=8}}.</ref> | |||
A constant current was applied to the cell continuously for many weeks, and heavy water was added as necessary. For most of the time, the power input to the cell was equal to the power that went out of the cell within measuring accuracy, and the cell temperature was stable at around 30 °C. But then, at some point (and in some of the experiments), the temperature rose suddenly to about 50 °C without changes in the input power, for durations of 2 days or more. The generated power was calculated to be about 20 times the input power during the power bursts. Eventually the power bursts in any one cell would no longer occur and the cell was turned off. | |||
===Theoretical mechanisms=== | |||
Another issue is that current theories describing conventional "hot" nuclear fusion cannot explain how a cold fusion reaction could occur at relatively low temperatures, and that there is currently no accepted theory to explain cold fusion.<ref name="Close_1992_?">{{harvnb|Close|1991|p=?}}.</ref>{{page number}}<ref name="Huizenga_1992_?">{{harvnb|Huizenga|1992|p=?}}.</ref>{{page number}} The 1989 DoE panel noted that "Nuclear fusion at room temperature, of the type discussed in this report, would be contrary to all understanding gained of nuclear reactions in the last half century; it would require the invention of an entirely new nuclear process",<ref name="DOE_1989_37">{{harvnb|US DOE|1989|Ref=DOE1989|p=37}}.</ref> but it also recognized that "the failure of a theory to account for cold fusion can be discounted on the grounds that the correct explanation and theory has not been provided",<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}.</ref> that is, the lack of a satisfactory explanation could not be used to dismiss experimental evidence. | |||
In 1988, Fleischmann and Pons applied to the ] for funding towards a larger series of experiments. Up to this point they had been funding their experiments using a small device built with $100,000 ].<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> The grant proposal was turned over for ], and one of the reviewers was ] of ].<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> Jones had worked on ] for some time, and had written an article on the topic entitled "Cold nuclear fusion" that had been published in '']'' in July 1987. Fleischmann and Pons and co-workers met with Jones and co-workers on occasion in ] to share research and techniques. During this time, Fleischmann and Pons described their experiments as generating considerable "excess energy", in the sense that it could not be explained by ]s alone.<ref name = "vxuvtq">{{harvnb|Fleischmann et al.|1990|Ref=Fleischmann1990|p=293}}</ref> They felt that such a discovery could bear significant commercial value and would be entitled to ]. Jones, however, was measuring neutron flux, which was not of commercial interest.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> In order to avoid problems in the future, the teams appeared to agree to simultaneously publish their results, although their accounts of their ] meeting differ.<ref name="Lewenstein-1994_8">{{harvnb|Lewenstein|1994|p=8}}</ref> | |||
Cold fusion observations are contrary to the conventional physics of nuclear fusion in several ways : | |||
* The average density of deuterium atoms in the palladium rod seems vastly insufficient to force pairs of nuclei close enough for fusion to occur according to mechanisms known to mainstream theories. The average distance is approximately 0.17 ]s, a distance at which the attractive ] cannot overcome the ]. Deuterium atoms are closer together in D<sub>2</sub> gas molecules, which do not exhibit fusion.<ref name="DOE_1989_6_7">{{harvnb|US DOE|1989|Ref=DOE1989|pp=6-7}}.</ref> | |||
* There is no known mechanism that would release fusion energy as heat instead of radiation within the relatively small metal lattice.<ref name="Goodstein_1994_528">{{harvnb|Goodstein|1994|p=528}}.</ref> The direct conversion of fusion energy into heat is not possible because of energy and ] conservation and the laws of ].<ref name="Kee_1999_5">{{harvnb|Kee|1999|p=5}}.</ref> | |||
In mid-March, both research teams were ready to publish their findings, and Fleischmann and Jones had agreed to meet at an airport on ] to send their papers to '']'' via ].<ref name="Lewenstein-1994_8">{{harvnb|Lewenstein|1994|p=8}}</ref> Fleischmann and Pons, however, broke their apparent agreement, submitting their paper to the ''Journal of Electroanalytical Chemistry'' on ], and disclosing their work via a press conference on March 23.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> Jones, upset, faxed in his paper to ''Nature'' after the press conference.<ref name="Lewenstein-1994_8">{{harvnb|Lewenstein|1994|p=8}}</ref> | |||
Cold fusion researchers have proposed various speculative theories (for a full review, see {{harvnb|Storms|2007}}) to explain the reported observations, but none has received mainstream acceptance. Also, because the reported processes may not technically be fusion, the DOE calls it "low energy nuclear reaction."<ref name="DOEr_2004_1">{{harvnb|US DOE|2004|Ref=DOE2004r|p=1}}.</ref> | |||
===Reaction to the announcement=== | |||
==Experimental reports== | |||
The press initially reported on the experiments widely, and due to the surmised beneficial commercial applications of the Utah experiments, "scores of laboratories in the United States and abroad" attempted to repeat the experiments.<ref name="Browne_1989_para13">{{harvnb|Browne|1989|loc=para. 13}}.</ref> The announcement raised hopes of a cheap and abundant source of energy.<ref name="Browne_1989_para1">{{harvnb|Browne|1989|loc=para. 1}}.</ref> | |||
===Excess heat=== | |||
The excess power observed in some experiments is reported to be beyond that attributable to ordinary chemical or solid state sources; this excess power is attributed by proponents to nuclear fusion reactions.<ref name="DOEr_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
On ], ], Fleischmann and Pons, who later suggested pressure from patent attorneys, published a rushed "preliminary note" in the ''Journal of Electroanalytical Chemistry''.<ref name="FleischmannPons_1989_301">{{harvnb|Fleischmann|Pons|1989|p=301}}.</ref> This paper notably contained a gamma peak without its corresponding ], a discrepancy that triggered accusations of fraud.<ref>{{harvnb|Tate|1989|p=1}}.</ref><ref>{{harvnb|Platt|1989}}.</ref> Their "preliminary note" was followed up a year later in July 1990, when a much longer paper, going into details of calorimetry but without any nuclear measurements, was published in the same journal.<ref name = "vxuvtq"/> | |||
The cold fusion researchers who presented their review document to the 2004 DoE panel said that "the hypothesis that the excess heat effect arises only as a consequence of errors in calorimetry was considered, studied, tested, and ultimately rejected".<ref name="DOE_2004_1">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=1}}.</ref> They said that over 50 experiments conducted by ] showed excess power well above the accuracy of measurement. Arata and Zhang said they observed excess heat power averaging 80 watts (1.8 times input energy) over 12 days. The researchers also said that the amount of energy reported in some of the experiments appeared to be too great compared to the small mass of the material in the cell for it to be stored by any chemical process. They said that their control experiments using light water never showed excess heat. There are nearly 200 published reports of excess heat <ref name="Storms_2007_52_61">{{harvnb|Storms|2007|pp=52-61}}.</ref> and other reviews by cold fusion researchers reach similar conclusions.<ref name="Biberian_2007_?">{{harvnb|Biberian|2007|p=?}}.</ref>{{page number}}<ref name="Hubler_2007_?">{{harvnb|Hubler|2007|p=?}}.</ref>{{page number}} | |||
Also occurring on ], a team at ] published their results of excess heat, followed up by a team at the ] who observed production of neutrons.<ref name="Broad_1989">{{harvnb|Broad|1989}}.</ref> Both results were widely reported on in the press, although both Texas A&M and the Georgia Institute of Technology withdrew their results for lack of evidence.<ref name="Broad_1989">{{harvnb|Broad|1989}}.</ref> For the next six weeks, additional competing claims, counterclaims and suggested explanations kept what was referred to as "cold fusion" or "fusion confusion" in the news.<ref>{{harvnb|Bowen|1989}}.</ref> | |||
The 2004 DoE panel noted that significant progress has been made in the sophistication of calorimeters since 1989. Evaluations by the reviewers ranged from: 1) evidence for excess power is compelling, to 2) there is no convincing evidence that excess power is produced when integrated over the life of an experiment. The reviewers were split approximately evenly on this topic. | |||
On ], Pons received a standing ovation from about 7,000 chemists at the semi-annual meeting of the ]. The University of Utah asked Congress to provide $25 million to pursue the research,<ref name="Browne_1989_para8">{{harvnb|Browne|1989|loc=para. 8}}.</ref> and Pons was scheduled to meet with representatives of ] in early May. | |||
Many of the reviewers noted that poor experiment design, documentation, background control and other similar issues hampered the understanding and interpretation of the results presented to the DoE panel. The reviewers who did not find the production of excess power convincing said that excess power in the short term is not the same as net energy production over the entire time of an experiment, that all possible chemical and solid state causes of excess heat had not been investigated and eliminated as an explanation, that the ] of the effect had not increased after over a decade of work, and that production over a period of time is a few percent of the external power applied and hence ] and systematic effects could account for the purported effect.<ref name="DOEr_2004_?#1">{{harvnb|US DOE|2004|Ref=DOE2004r|p=??}}.</ref>{{page number}} | |||
Then on ], the ] held a session on cold fusion, which included several reports of experiments that failed to produce evidence of cold fusion. A second session began the next day with other negative reports, and eight of the nine leading speakers stated that they considered the initial Utah claim dead.<ref name="Browne_1989">{{harvnb|Browne|1989}}</ref> Dr. Steven E. Koonin of ] described the Utah report as a result of "the incompetence and delusion of Pons and Fleischmann."<ref name="Browne_1989">{{harvnb|Browne|1989}}</ref> Dr. Douglas R. O. Morrison, a physicist representing ], called the entire episode an example of ].<ref name="Browne_1989_para29">{{harvnb|Browne|1989|loc=para. 29}}.</ref><!-- The following citation does not support that statement: {{citation|editor-last=Krumhansi|editor-first=J. A.|title=APS Special Session on Cold Fusion, May 1-2, 1989|year=1989|url=http://www.ibiblio.org/pub/academic/physics/Cold-fusion/vince-cate/aps.ascii}} -->''Nature'' published papers critical of cold fusion in July and November.<ref>{{harvnb|Gai et al.|Ref=Gai1989|1989|pp=29-34}}.</ref><ref>{{harvnb|Williams et a.|1989|Ref=Williams1989|pp=375-384}}.</ref> | |||
===Nuclear products=== | |||
].<ref>{{harvnb|Mosier-Boss|Szpak|Gordon|2007|loc=slide 7}}<br />reported in {{harvnb|Krivit|2007|p=2}}.</ref>]] The cold fusion researchers who presented their review document to the 2004 DoE panel on cold fusion said that there are insufficient chemical reaction products to account for the excess heat by several orders of magnitude.<ref name="DOE_2004_7">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=7}}.</ref> They said that three independent studies have shown that the rate of helium production measured in the gas stream varies linearly with excess power. Extensive precautions were taken to ensure that the samples were not contaminated by helium from the ] (5.2 ]). Bursts of excess energy were time-correlated with bursts of <sup>4</sup>He in the gas stream. However, the amount of helium in the gas stream was about half of what would be expected for a heat source of the type D + D -> <sup>4</sup>He. Searches for ] and other energetic emissions commensurate with excess heat have uniformly produced null results. Although there appears to be evidence of ]s and ] anomalies near the cathode surface in some experiments,<sup>''cf.''</sup> <ref name="SzpakMosierBossYoungGordon_2005_2">{{harvnb|Szpak|Mosier-Boss|Young|Gordon|2005|p=2}}.</ref> <sup>and</sup> <ref name="IwamuraSakanoItoh_2002_4647">{{harvnb|Iwamura|Sakano|Itoh|2002|p=4647}}.</ref> evidence which introduce additional discrepancies between observations and conventional theory because of the increased Coulomb barrier, they said that it is generally accepted that these anomalies are not the ash associated with the primary excess heat effect. There are over 60 published reports of anomalous tritium production<ref name="Storms_2007_79_81">{{harvnb|Storms|2007|p=79-81}}.</ref> and other reviews by cold fusion researchers reach similar conclusions.<ref name="Biberian_2007_?">{{harvnb|Biberian|2007|p=?}}.</ref>{{page number}}<ref name="Hubler_2007_?">{{harvnb|Hubler|2007|p=?}}.</ref>{{page number}} | |||
===1989 DOE panel=== | |||
When asked about evidence of low energy nuclear reactions, twelve of the eighteen members of the 2004 DoE panel did not feel that there was any conclusive evidence, five found the evidence "somewhat convincing" and one was entirely convinced. The evidence of D+D fusion was taken as convincing or somewhat convincing by some reviewers; for others the lack of consistency was an indication that the overall hypothesis was not justified. Contamination of apparatus or samples by air containing 4He was cited as one possible cause for false positive results in some measurements.<ref name="DOEr_2004_?#2">{{harvnb|US DOE|2004|Ref=DOE2004r|p=??}}.</ref> | |||
In November, a special panel formed by the Energy Research Advisory Board, under a charge of the ], said that it was not possible to state categorically that cold fusion has been convincingly either proved or disproved.<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}</ref> The experimental results of excess heat from calorimetric cells reported to them did not present convincing evidence that useful sources of energy will result from the phenomena attributed to cold fusion. These experiments did not present convincing evidence to associate the reported anomalous heat with a nuclear process. Current understanding of hydrogen in solids gives no support for the occurrence of cold fusion in solids. Nuclear fusion at room temperature, of the type discussed in this report, would be contrary to all understanding gained of nuclear reactions in the last half century; it would require the invention of an entirely new nuclear process. | |||
The panel "recommended against the establishment of special programs or research centers to develop cold fusion", but was "sympathetic toward modest support for carefully focused and cooperative experiments within the present funding system." The Panel recommended that "the cold fusion research efforts in the area of heat production focus primarily on confirming or disproving reports of excess heat" and stated that "investigations designed to check the reported observations of excess tritium in electrolytic cells are desirable.". <ref name="DOE_1989_37">{{harvnb|US DOE|1989|Ref=DOE1989|p=37}}.</ref> | |||
In 2007, the ] reported their observation of pits in ] detectors during D/Pd codeposition experiments in the ]. They said that those pits have features consistent with those observed for nuclear generated tracks, that the Pd cathode is the source of those pits, that they are not due to contamination or chemical reactions. They attributed some pits to knock-ons due to neutrons, and said that other pits are consistent with those obtained for ]s. They said that the experiment is reproducible.<ref>{{harvnb|Mosier-Boss|Szpak|Gordon|Forsley|2007|p=?}}.</ref>{{page number}}<!--removed reference to ... www.dailytech.com/article.aspx?newsid=7168 which is a blog and anyway irrelevant to "They said..." --> | |||
===Further developments (1989-2004)=== | |||
===Nuclear Transmutations=== | |||
The first published replication of excess heat was reported by Richard Oriani while he was professor of physical chemistry at the ], in December 1990. The results were published in his paper, "Calorimetric Measurements of Excess Power Output During the Cathodic Charging of Deuterium Into Palladium", in ''Fusion Technology''.<ref>{{harvnb|Oriani|Nelson|Lee|Broadhurst|1990|pp=652-662}}, cited by {{harvnb|Krivit|2005}}..</ref> | |||
A transmutation is the transformation of a ] into another. Nuclear ]s have been reported in many cold fusion experiments since 1992. Transmutations in such experiments would be contrary to all understanding gained of nuclear reactions in the last half century; they would require the invention of an entirely new nuclear process. At the same time, the lack of a satisfactory explanation cannot be used to dismiss experimental evidence. | |||
In 1991, Dr. ] stated that the negative report issued by the ] in 1989, which was highly influential in the controversy, was fraudulent because data was shifted without explanation, obscuring a possible positive excess heat result at MIT.<!-- the following citation is not valid (or is OR) for the previous statement. {{cite web|last=Krivit|first=Steven|title=Controversial MIT. Cold Fusion Graphs|url=http://newenergytimes.com/Reports/HistoricalAnalysisSummaryCharts.htm#mit}}</ref> --> In protest of ]'s failure to discuss and acknowledge the significance of this data shift, Mallove resigned from his post as chief science author at the MIT news office on ], ]. He maintained that the data shift was biased to support the conventional belief in the non-existence of the cold fusion effect as well as to protect the financial interests of the plasma fusion center's research in hot fusion.<ref>{{harvnb|Mallove|1999}}.</ref> | |||
They are over 60 reports of nuclear transmutations.<sup>''cf''.</sup> <ref name="Storms_2007_93_95">{{harvnb|Storms|2007|p=93-95}}.</ref> Tadahiko Mizuno was among the first to contribute a paper ({{harvnb|Mizuno|2000}}) and a book on the subject ({{harvnb|Mizuno|1998}}). Dr. Miley, who also contributed{{clarifyme}} to ],<ref>{{harvnb|Prow|2001}}.</ref> wrote a review of these experiments.<ref name="MileyShrestha_2003_?#1">{{harvnb|Miley|Shrestha|2003}}</ref> He reports that several dozen laboratories are studying these effects. Some experiments result in the creation of only a few elements, while others result in a wide variety of elements from the ]. Calcium, copper, zinc, and iron were the most commonly reported elements. ]s were also found: this is significant since they are unlikely to enter as impurities. In addition, the isotopic ratios of the observed elements differ from their natural isotopic ratio or ]. Many elements have multiple ]s and the percentages of the different isotopes are constant on earth within one tenth of one percent. In general it requires gaseous diffusion, thermal diffusion, electromagnetic separation or other exotic processes of ] or a nuclear reaction to change an element from its natural isotope ratio. The presence of an unnatural isotope ratio makes contamination an implausible explanation. Some experiments reported both transmutations and excess heat, but the correlation between the two effects has not been established. Radiations have also been reported. Miley also reviews possible theories to explain these observations.<ref name="MileyShrestha_2003_?#2">{{harvnb|Miley|Shrestha|2003|p=?}}.</ref>{{page number}} | |||
The late Nobel Laureate ] (1918 - 1994) also stated in 1991 that he had experienced "the pressure for conformity in editor's rejection of submitted papers, based on venomous criticism of anonymous reviewers," and that "the replacement of impartial reviewing by censorship will be the death of science."<ref>{{harvnb|Schwinger|1991}}.</ref> He resigned as Member and Fellow of the ] in protest of its peer review practice on cold fusion. | |||
Further evidence for transmutation has come from an experiment made by Iwamura and associates, and published in 2002 in the Japanese Journal of Applied Physics.<ref name="IwamuraSakanoItoh_2002_full">{{harvnb|Iwamura|Sakano|Itoh|2002|pp=4642-4650}}.</ref> Instead of using electrolysis, they forced deuterium gas to ] through a thin layer of ] (also known as cesium) deposited on ] and palladium, while periodically analyzing the nature of the surface through ]. As the deuterium gas permeated over a period of a week, the amount of caesium progressively decreased while the amount of ] increased, so that caesium appeared to be transmuted into praseodymium. When caesium was replaced by ], it was transmuted into ] with anomalous isotopic composition. In both cases this represents an addition of four deuterium nuclei to the original element. They have produced these results six times, and reproducibility was good. The energy released by these transmutations was too low to be observed as heat. No gamma rays were observed. When the calcium oxide was removed or when the deuterium gas was replaced by hydrogen in control experiments, no transmutation was observed. The authors analyzed, and then rejected, the possibility to explain these various observations by contaminations or migration of impurities from the palladium interior: | |||
:"Since the detected material, Pr, belongs to rare earth elements, it is difficult to assume that Pr accumulated on the Pd complex test pieces by an ordinary process. The purity of the used D2 gas is over 99.6% and most of the impurity is H2. The other impurities detected by a mass spectrometer are N2, D2O, O2, CO2 , CO and hydrocarbons; their amounts are all under 10 ppm. It is impossible for all of the distributed Pr in the Pd test piece to gather in the narrow surface area against the flow of D2 gas without the application of a specific force on Pr, because such a phenomenon breaks the law of thermodynamics. The third point is that the isotope ratio of produced elements is anomalous. In this paper, we show the isotopic anomaly of Mo. It provides evidence that the detected material, Mo, was produced by certain nuclear processes. If the Mo were a contaminant, such efficient isotope separations would not be possible. The last point is that the elements detected the D2 gas permeation vary depending on the given elements at the beginning of the experiments. It is very difficult to assume that the detected elements change depending on the given elements by external contamination. The above discussion strongly suggests the existence of low-energy nuclear transmutations induced by a simple method."<ref name="IwamuraSakanoItoh_2002_4648">{{harvnb|Iwamura|Sakano|Itoh|2002|p=4648-4649}}.</ref> | |||
In 1992, workers at General Electric challenged the Fleischmann-Pons 1990 report in the ''Journal of Electroanalytical Chemistry'', stating that the claims of excess heat had been overstated.<ref>{{harvnb|Wilson|1992|p=1}}, cited by {{harvnb|Krivit|2005}}.</ref> The challenge concluded that the Fleischmann and Pons cell generated 40% excess heat, more than ten times larger than the initial error estimate. Despite the apparent confirmation, Fleischmann and Pons replied to General Electric and published a rebuttal in the same journal.<ref>{{harvnb|Beaudette|2002|pp=188, 357-360}}.</ref><!-- commented out extraordinary statement lacking extraordinary sources: "...which has never been refuted in scientific literature."<ref>{{cite web|last=Krivit|first=Steven|title=The Seminal Papers of Cold Fusion|publisher=New Energy Times|url=http://newenergytimes.com/PR/TheSeminalPapers.htm}}</ref> --> | |||
At the conclusion of their report, Iwamura et al. are cautious in presenting how such transmutations could be explained. Their conclusions are qualified by the reliance on several assumptions and by their model being presented as a hypothesis rather than an established theory. "If several assumptions are accepted, they (the results) are basically explained by the EINR model, which is one of the working hypotheses in the investigation of the nature of this phenomenon."<ref name="IwamuraSakanoItoh_2002_?#3">{{harvnb|Iwamura|Sakano|Itoh|2002|p=??}}.</ref> | |||
Fleischmann and Pons relocated their laboratory to France under a grant from the ]. The laboratory, IMRA, was closed in 1998 after spending £12 million on cold fusion work. By comparison, research on the proven hot fusion reaction has run into the billions.<ref>{{harvnb|Voss|1999}}.</ref> | |||
The experiment was replicated<ref name="Higashiyama_2003_1">{{harvnb|Higashiyama|Sakano|Miyamaru|Takahashi|2003|p=1}}</ref> by researchers from Osaka University using ] to analyze the nature of the surface (the Pd ] samples were provided by Iwamura). In later similar experiments by Iwamura, ] 138 was transmuted to ] 150 and Barium 137 was transmuted into Samarium 149. The Barium 138 experiment used a natural isotope ratio of Barium. The Barium 137 experiment used a Barium 137 enriched isotope ratio. These transmutations represent an addition of six deuterium nuclei.<ref name="Iwamura_2004_1">{{harvnb|Iwamura|2004|p=1}}.</ref> | |||
], a cold fusion proponent, contends that by 1991, 92 groups of researchers from 10 different countries had reported excess heat, tritium, helium4, neutrons or other nuclear effects.<ref>{{harvnb|Mallove|1991|p=246-248}}.</ref> Proponents estimate that 3,000 cold fusion papers have been published, <ref>{{harvnb|Anderson|2007}}</ref> including over 1,000 journal papers and books, where the latter number includes both pro and con articles.{{Ref_label|heat_tritium_reports|α|none}} | |||
Szpak et al have also reported transmutations in electrolytic cells,<ref name="SzpakMosierBossYoungGordon_2005_?#2">{{harvnb|Szpak|Mosier-Boss|Young|Gordon|2005|p=??}}.</ref>{{page number}} and Bush and Eagleton have reported the appearance of radioactive isotopes with an average half-life of 3.8 days in electrolytic cells, an observation that is difficult to explain by contamination or migration.<ref name="BushEagleton_1994_334">{{harvnb|Bush|Eagleton|1994|p=334}}.</ref> | |||
] | |||
==Excess heat by electrolysis experiments== | |||
The generation of excess heat has been reported by (among others): | |||
* ], while he was professor at ], Japan, | |||
* Robert A. Huggins, while he was professor at ] (in March 1990), | |||
* Michael McKubre, of ], | |||
* T. Mizuno (], Japan), | |||
* T. Ohmori (Japan), | |||
* Richard A. Oriani, while he was professor at ] (in December 1990), | |||
* the late ], while he was at ], and | |||
* Edmund Storms, while he was at ]. | |||
Many of these researchers continued their research in the phenomena after retirement. | |||
Researchers share their results at the International Conference on Cold Fusion, recently renamed the International Conference on Condensed Matter Nuclear Science. The conference is held every 12 to 18 months in various countries around the world, and is hosted by , a scientific organization that was founded as a professional society to support research efforts and to communicate experimental results. A few periodicals emerged in the 1990s that covered developments in cold fusion and related new energy sciences (''Fusion Facts, Cold Fusion Magazine, Infinite Energy Magazine'', and ''New Energy Times''). | |||
=== The Fleischmann and Pons experiment === | |||
] | |||
In their original set-up, Fleischmann and Pons used a ] (a double-walled vacuum flask) for the ], so that heat conduction would be minimal on the side and the bottom of the cell (only 5 % of the heat loss in this ]). The cell flask was then submerged in a bath maintained at constant temperature to eliminate the effect of external heat sources. They used an open cell, thus allowing the ]eous deuterium and oxygen resulting from the ] reaction to leave the cell (with some heat too). It was necessary to replenish the cell with ] at regular intervals. The authors said that, since the cell was tall and narrow, the bubbling action of the gas kept the electrolyte well mixed and of a uniform temperature. The efficacy of this stirring method and thus the validity of the temperature measurements would later be disputed.<ref>Browne M. "''Physicists Debunk Claim Of a New Kind of Fusion''", New York Times, May 3, 1989 </ref> Special attention was paid to the purity of the palladium cathode and electrolyte to prevent the build-up of material on its surface, especially after long periods of operation. | |||
] of the open type, used at the New Hydrogen Energy Institute in Japan. ''Source: SPAWAR/US Navy TR1862'']] Between 1992 and 1997, Japan's ] sponsored a "New Hydrogen Energy Program" of US$20 million to research cold fusion. Announcing the end of the program, Dr. Hideo Ikegami stated in 1997 "We couldn't achieve what was first claimed in terms of cold fusion." He added, "We can't find any reason to propose more money for the coming year or for the future."<ref>{{harvnb|Pollack|1997|p=C4}}.</ref> | |||
The cell was also instrumented with a ] to measure the temperature of the ], and an electrical heater to generate pulses of heat and calibrate the heat loss due to the gas outlet. After ], it was possible to compute the heat generated by the reaction.{{Fact|date=November 2007}} | |||
In 1994, Dr. ] described cold fusion as "a pariah field, cast out by the scientific establishment. Between and respectable science there is virtually no communication at all. Cold fusion papers are almost never published in refereed scientific journals, with the result that those works don't receive the normal critical scrutiny that science requires. On the other hand, because the Cold-Fusioners see themselves as a community under siege, there is little internal criticism. Experiments and theories tend to be accepted at face value, for fear of providing even more fuel for external critics, if anyone outside the group was bothering to listen. In these circumstances, crackpots flourish, making matters worse for those who believe that there is serious science going on here."<ref name="Goodstein_1994">{{harvnb|Goodstein|1994}}.</ref> | |||
A constant current was applied to the cell continuously for many weeks, and heavy water was added as necessary. For most of the time, the power input to the cell was equal to the power that went out of the cell within measuring accuracy, and the cell temperature was stable at around 30 °C. But then, at some point (and in some of the experiments), the temperature rose suddenly to about 50 °C without changes in the input power, for durations of 2 days or more. The generated power was calculated to be about 20 times the input power during the power bursts. Eventually the power bursts in any one cell would no longer occur and the cell was turned off. | |||
Cold fusion researchers said that cold fusion was being suppressed, and that skeptics suffered from "]".<ref>{{harvnb|Josephson|2004}}.</ref> They said that there was virtually no possibility for funding in cold fusion in the United States, and no possibility of getting published.<ref name="Feder_2004_27">{{harvnb|Feder|2004|p=27}}.</ref> They said that people in universities refused to work on it because they would be ridiculed by their colleagues.<ref>{{harvnb|Rusbringer|2005}}</ref> | |||
===The Faraday-efficiency effect=== | |||
Lacking any other plausible explanation, the anomalous excess heat produced during such electrolysis was attributed by Pons and Fleischmann to cold ]. It was discovered that, in some circumstances, such excess heat can be the product of conventional chemistry, i.e. internal recombination of hydrogen and oxygen. Such recombination leads to a reduction in the Faraday efficiency of the electrolysis. The '''Faraday-efficiency effect''' is the observation of apparent excess heat due to a reduction in the Faraday efficiency. | |||
In February 2002, a laboratory within the United States Navy released a report<ref>{{harvnb|Szpak|Mosier-Boss|2002a}}</ref><ref>{{harvnb|Szpak|Mosier-Boss|2002b}}</ref> that came to the conclusion that the cold fusion phenomenon was in fact real and deserved an official funding source for research.<ref>{{harvnb|Szpak|Mosier-Boss|2002a|p=iv-v}}</ref> Navy researchers say that, since 1990, they have published roughly 10 papers on cold fusion in ].<ref>{{harvnb|Szpak|Mosier-Boss|2002a|p=113}}</ref> | |||
A group of investigators<ref name="ShkediMcDonaldBreenMaguireVeranth_1995_full">{{harvnb|Shkedi et al.|1995|Ref=Shkedi1995|pp=1720-1731}}.</ref><ref>{{harvnb|Shkedi|1996|Ref=Shkedi1996|p=133}}.</ref> led by Zvi Shkedi, built in 1991-1993 several well-insulated cells and ]s which included the capability to measure the actual Faraday efficiency in real time during the experiments. The cells were of the light-water type; with a fine-wire nickel cathode; a platinum anode; and K<sub>2</sub>CO<sub>3</sub> electrolyte. | |||
===2004 DOE panel=== | |||
The calorimeters were calibrated to an accuracy of 0.02% of input power. The long-term stability of the calorimeters was verified over a period of 9 months of continuous operation. In their publication, the investigators show details of their calorimeters' design and how they achieved high calorimetric accuracy. | |||
In 2004, the DOE organized another panel to take a look at cold fusion developments since 1989 to determine if their policies towards cold fusion should be altered.<ref name="DOEr_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
It concluded: "While significant progress has been made in the sophistication of calorimeters since the review of this subject in 1989, the conclusions reached by the reviewers today are similar to those found in the 1989 review." "The nearly unanimous opinion of the reviewers in the 2004 review was that funding agencies should entertain individual, well-designed proposals for experiments that address specific scientific issues relevant to the question of whether or not there is anomalous energy production in Pd/D systems, or whether or not D-D fusion reactions occur at energies on the order of a few ]s (eV). These proposals should meet accepted scientific standards and undergo the rigors of peer review. No reviewer recommended a focused federally funded program for low energy nuclear reactions." "The reviewers believed that this field would benefit from the peer-review processes associated with proposal submission to agencies and paper submission to archival journals."<ref name="DOEr_2004_5">{{harvnb|US DOE|2004|Ref=DOE2004r|p=5}}.</ref> | |||
A total of 64 experiments were performed in which the actual Faraday efficiency was measured. The results were analyzed twice; once with the popular assumption that the Faraday efficiency is 100%, and, again, taking into account the measured Faraday efficiency in each experiment. The average Faraday efficiency measured in these experiments was 78%. | |||
===Recent developments=== | |||
The first analysis, assuming a Faraday efficiency of 100%, yielded an average apparent excess heat of 21% of input power. The term "apparent excess heat" was coined by the investigators to indicate that the actual Faraday efficiency was ignored in the analysis. | |||
The reports of excess heat and anomalous tritium production{{Ref_label|heat_tritium_reports|α|none}} have met by most scientists with ],<ref>{{harvnb|Feder|2005}}</ref> although discussion in professional settings still continues. The American Chemical Society's (ACS) 2007 conference in Chicago held an "invited symposium" on cold fusion and low-energy nuclear reactions, and thirteen papers were presented at the "Cold Fusion" session of the 2006 American Physical Society (APS) March Meeting in Baltimore.<ref>{{harvnb|Van Noorden|2007|loc=para. 2}}.</ref><ref>{{harvnb|Chubb et al.|2006|Ref=APS2006}}.</ref> Articles supporting cold fusion have been published in ]ed journals such as ''Naturwissenschaften, European Physical Journal A, European Physical Journal C, Journal of Solid State Phenomena, Journal of Electroanalytical Chemistry, ]'', and ''Journal of Fusion Energy''. <ref> cited by Krivit, Steven, "Selected Papers - Low Energy Nuclear Reactions," </ref> | |||
In 2008, the government of India reviewed the field.<ref>{{harvnb|Jayaraman|2008}}</ref> Dr. M. R. Srinivasan, former chairman of the ] said: "There is some science here that needs to be understood. We should set some people to investigate these experiments. There is much to be commended for the progress in the work. The neglect should come to an end".<ref>{{harvnb|Srinivasan|2008}}</ref> On May 22, 2008, Arata and Zhang publicly demonstrated what they say is a cold fusion reactor at Osaka University.<ref>{{harvnb|Cartwright|2008}}</ref><ref>{{harvnb|Cartwright|2008b}}</ref> | |||
The second analysis, taking into account the measured Faraday efficiency, yielded an actual excess heat of 0.13% +/- 0.48%. In other words, when the actual Faraday efficiency was measured and taken into account, the energy balance of the cells was zero, with no excess heat. | |||
==Summary of evidence for cold fusion== | |||
This investigation has shown how conventional chemistry, i.e. internal recombination of hydrogen and oxygen, accounted for the entire amount of apparent excess heat in this experiment. The investigators concluded their publication with the following word of caution: "All reports claiming the observation of excess heat should be accompanied by simultaneous measurements of the actual Faraday efficiency."<ref name="ShkediMcDonaldBreenMaguireVeranth_1995_?">{{harvnb|Shkedi et al.|1995|Ref=Shkedi1995|p=??}}.</ref>{{page number}} | |||
Cold fusion experiments have been conducted with many types of apparatus. The main constituents are: | |||
* a metal, such as Palladium or Nickel, in bulk, thin films or powder; | |||
* heavy or light water, hydrogen or deuterium gas or plasma; | |||
* an excitation in the form of electricity or magnetism, of temperature or pressure cycle, of laser beam, or of acoustic waves.<ref>{{harvnb|Storms|2007|p=144-150}}</ref> | |||
Cold fusion has remained controversial, but several experimenters have reported excess heat, helium-4, low-level neutron production, X-ray emission, and/or transmutation of elements. | |||
Jones et al. confirmed the Shkedi et al. findings with the same conclusion: "Faradaic efficiencies less than 100% during electrolysis of water can account for reports of excess heat in 'cold fusion' cells."<ref name="JonesHansenJonesSheltonThorne_1995_1">{{harvnb|Jones et al.|1995|Ref=Jones1995|p=1}}.</ref> | |||
===Excess heat=== | |||
Fleischmann did measure Faraday efficiency in his experiments: it was better than 99%.<ref name="FleischmannPonsAndersonLiHawkins_1990_?">{{harvnb|Fleischmann et al.|1990|Ref=Fleischmann1990|p=301}}.</ref> Fritz Will, former president of the Electrochemical Society, noted in his review of Jones' paper that " fraction of 0 2 recombining with H 2 decreases significantly with increasing current density. On the basis of their results at low current densities, a group of researchers recently concluded that H 2 + 0 2 recombination is the source for the "excess heat' reported by other groups and attributed by some to 'cold fusion'. However, reported excess heat values, ranging from a low of 23% at 14mAcm -2 to a high of 3700% at 6mAcm -2, are much larger than can be explained by recombination. Whatever the explanation for the large amounts of excess heat reported by various groups, H2 + 02 recombination must be rejected as a tenable explanation."<ref>{{harvnb|Will|1997|p=177}}.</ref> | |||
The excess power observed in some experiments is reported to be beyond that attributable to ordinary chemical or solid state sources; proponents attribute this excess power to nuclear fusion reactions.<ref name="DOEr_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
The cold fusion researchers who presented their review document to the 2004 DOE panel said that "the hypothesis that the excess heat effect arises only as a consequence of errors in calorimetry was considered, studied, tested, and ultimately rejected".<ref name="DOE_2004_1">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=1}}.</ref> They said that numerous experiments conducted by ] showed excess power well above the accuracy of measurement.<ref>{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=22}}.</ref> The researchers also said that the amount of energy reported in some of the experiments appeared to be too great compared to the small mass of the material in the cell for it to be stored by any chemical process. They said that their control experiments using light water did not show excess heat. | |||
Edmund Storms observed that " values attributed to Jones et al gives a good example of biased reasoning. They measured the recombination fraction at very low currents, where is high, and used these values to dismiss all measurements using open cells, without acknowledging that most successful studies used much higher currents or closed cells where this correction is unnecessary."<ref name="Storms_2007_195">{{harvnb|Storms|2007|p=195}}.</ref> | |||
In 2007, a cold fusion proponent wrote a review by of experiments with a solid ] cathode and an electrolyte with ], or with D<sub>2</sub> gas loaded in palladium powders. The author said that more than 10 groups worldwide have reported the measurement of excess heat in 1/3 of their experiments and that most of the research groups have reported occasionally seeing 50-200% excess heat for hours to days.<ref name="Hubler_2007"/> | |||
==History== | |||
=== |
===Nuclear products=== | ||
].<ref>{{harvnb|Mosier-Boss|Szpak|Gordon|2007|loc=slide 7}}<br />reported in {{harvnb|Krivit|2007|p=2}}.</ref>]] The cold fusion researchers who presented their review document to the 2004 DOE panel on cold fusion said that there are insufficient chemical reaction products to account for the excess heat by several orders of magnitude.<ref name="DOE_2004_7">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=7}}.</ref> They said that several independent studies have shown that the rate of helium production measured in the gas stream varies linearly with excess power. Bursts of excess energy were time-correlated with bursts of <sup>4</sup>He in the gas stream. Extensive precautions were taken to ensure that the samples were not contaminated by helium from the ] (5.2 ]). They say that "numerous investigators" <!--direct quote from source--> have reported that <sup>4</sup>He was produced at levels above that of the concentration in air.<ref>{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=10}}.</ref> However, the amount of helium in the gas stream was about half of what would be expected for a heat source of the type D + D -> <sup>4</sup>He. Searches for ] and other energetic emissions commensurate with excess heat have uniformly produced null results. | |||
Cold fusion revolves around the idea that ] or ] might catalyze fusion stemmed from the special ability of these metals to absorb large quantities of ], including its deuterium isotope, the hope being that the deuterium atoms would be close enough together to induce fusion at ordinary temperatures.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> The special ability of palladium to absorb hydrogen was recognized as early as the nineteenth century by ].<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> In the late nineteen-twenties, two ] scientists, F. Paneth and K. Peters, reported the transformation of hydrogen into helium by spontaneous nuclear catalysis when hydrogen was adsorbed by finely divided palladium at room temperature.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> These authors later acknowledged that the helium they measured was due to background from the air. | |||
In 2007, the ] reported their observation of pits in ] detectors during D/Pd codeposition experiments in the '']''. They said that those pits have features consistent with those observed for nuclear-generated tracks, that the Pd cathode is the source of those pits, and that they are not due to contamination or chemical reactions. They attributed some pits to knock-ons due to neutrons, and said that other pits are consistent with those obtained for ]s.<ref>{{harvnb|Mosier-Boss|Szpak|Gordon|Forsley|2007}}.</ref> | |||
In 1927, ] scientist J. Tandberg stated that he had fused hydrogen into helium in an ] with palladium electrodes.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> On the basis of his work he applied for a Swedish patent for "a method to produce helium and useful reaction energy." After deuterium was discovered in 1932, Tandberg continued his experiments with ]. Due to Paneth and Peters' retraction, Tandberg's patent application was eventually denied.<ref name="DOE_1989_7">{{harvnb|US DOE|1989|Ref=DOE1989|p=7}}.</ref> | |||
===Nuclear transmutations=== | |||
The term "cold fusion" was coined by Dr Paul Palmer of ] in 1986 in an investigation of "geo-fusion," or the possible existence of fusion in a ].<ref name="Kowalski_2004_IIA2">{{harvnb|Kowalski|2004|loc=II.A2}}.</ref> | |||
In nuclear reactions, a ] may be ] into another. There are numerous reports of nuclear transmutations and ] anomalies in cold fusion experiments.<ref name="Storms_2007_93_95">{{harvnb|Storms|2007|p=93-95}}.</ref> Cold fusion proponents say that it is generally accepted that these anomalies are not the ash associated with the primary excess heat effect.<ref name="DOE_2004_7">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=7}}.</ref> | |||
Tadahiko Mizuno was among the first to contribute a paper<ref>{{harvnb|Mizuno|1996}}</ref> and a book on the subject.<ref>{{harvnb|Mizuno|1998}}, cited by {{harvnb|Britz|2008}}</ref> Dr. Miley, who also developed a process for making small ] devices to serve as portable fusion neutron sources,<ref>{{harvnb|Prow|2001}}.</ref> wrote a review of these experiments.<ref name="MileyShrestha_2003_?#1">{{harvnb|Miley|Shrestha|2003}}</ref> Some report the creation of only a few elements, while others report a wide variety of elements from the ]. Calcium, copper, zinc, and iron were the most commonly reported elements, often with ].<ref name="MileyShrestha_2003_?#2">{{harvnb|Miley|Shrestha|2003}}.</ref> | |||
===Pre-announcement and announcement=== | |||
In the 1960s, Fleischmann and his research team began investigating the possibility that ] could influence nuclear processes.<ref name="Fleischmann_2003_1">{{harvnb|Fleischmann|2003|p=1}}.</ref> Simple ] calculations indicate that such effects should be negligibly small,<ref>{{harvnb|Evans|1982|p=??}}.</ref> but Fleischmann started to explore whether collective effects, that would require ] to calculate, might be significant.<ref name="Fleischmann_2003_3">{{harvnb|Fleischmann|2003|p=3}}.</ref> By 1983, Fleischmann had experimental evidence leading him to believe that condensed phase systems developed ] structures up to 10<sup>-7</sup>m in size.<ref name="Fleischmann_2003_3">{{harvnb|Fleischmann|2003|p=3}}.</ref> | |||
Iwamura and associates published what they say to be further evidence of transmutations in the ''Japanese Journal of Applied Physics'' in 2002.<ref name="IwamuraSakanoItoh_2002_full">{{harvnb|Iwamura|Sakano|Itoh|2002|pp=4642-4650}}.</ref> Instead of using electrolysis, they forced deuterium gas to ] through a thin layer of ] or ] deposited on ] and palladium, while periodically analyzing the nature of the surface through ]. They said that as the deuterium gas permeated over a period of a week, cesium appeared to be progressively transmuted into praseodymium while strontium appeared to be transmuted into ] with anomalous isotopic composition representing an addition of four deuterium nuclei to the original nuclide. When the deuterium gas was replaced by hydrogen in control experiments, no transmutation was reported to be observed. The authors said that they analyzed, and then rejected, the possibility of explaining these various observations by contaminations or migration of impurities from the palladium interior.<ref name="IwamuraSakanoItoh_2002_4648">{{harvnb|Iwamura|Sakano|Itoh|2002|p=4648-4649}}.</ref> | |||
In 1988, Fleischmann and Pons applied to the ] for funding towards a larger series of experiments. Up to this point they had been funding their experiments using a small device built with $100,000 ].<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> | |||
==Criticism== | |||
The grant proposal was turned over for ], including ] of ].<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> Jones had worked on ] for some time, and had written an article on the topic entitled ''Cold Nuclear Fusion'' that had been published in '']'' in July 1987. Similar to Fleischmann and Pons, Jones claimed that he detected fusion but with a more modest claim, but it was discredited because the rates were far too low to be commercially practical.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> | |||
The skepticism towards cold fusion results from four issues: the precision of calorimetry, the lack of consistently reproducible results, the absence of nuclear products in quantities consistent with the excess heat, and the lack of a mainstream theoretical mechanism.<ref name="DOE_1989_6_8">{{harvnb|US DOE|1989|Ref=DOE1989|pp=6-8}}.</ref> | |||
===Precision of calorimetry=== | |||
Both Fleischmann and Pons`, and Jones research teams met on occasion in ] to discuss sharing research and techniques. During this time, Fleischmann and Pons described their experiments as generating considerable "excess energy", in the sense that it could not be explained by ]s alone.{{cn|date=February 2008}} This could bear significant commercial value and would be protected by ]. Jones, however, was measuring neutron flux, which was not of commercial interest.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> In order to avoid problems in the future, the teams ''apparently'' agreed to simultaneously publish their results, although their accounts of their ] meeting differ.{{cn|date=February 2008}} | |||
{{main|Calorimetry in cold fusion experiments}} | |||
The efficacy of the stirring method in the Fleischmann-Pons experiment, and thus the validity of the temperature measurements has been disputed by Browne.<ref name="Browne_1989_para16">{{harvnb|Browne|1989|loc=para. 16}}.</ref> The experiment has also been criticized by Wilson.<ref name="Wilson_1992">{{harvnb|Wilson|1992}}</ref> Other experiments using open cells have been criticized by Shkedi<ref name="ShkediMcDonaldBreenMaguireVeranth_1995_?">{{harvnb|Shkedi et al.|1995|Ref=Shkedi1995}}.</ref> and Jones.<ref name="JonesHansenJonesSheltonThorne_1995_1">{{harvnb|Jones et al.|1995|Ref=Jones1995|p=1}}.</ref> Other experiments using mass flow calorimetry have been criticized by Shanahan.<ref>{{harvnb|Shanahan|2002}}</ref><ref>{{harvnb|Shanahan|2005}}.</ref><ref>{{harvnb|Shanahan|2006}}</ref> | |||
Cold fusion researchers find these critique unconvincing, and not applicable to other experimental design.<ref name="Fleischmann_1992">{{harvnb|Fleischmann|1992|Ref=Fleischmann1992}}</ref><ref>{{harvnb|Will|1997|p=177}}.</ref><ref name="Storms_2007_195">{{harvnb|Storms|2007|p=195}}.</ref><ref>{{harvnb|Storms|2006}}.</ref> | |||
In mid-March, both research teams were ready to publish their findings, and Fleischmann and Jones had agreed to meet at an airport on March 24 to send their papers to ] via ].{{cn|date=February 2008}} Fleischmann and Pons, however, broke their apparent agreement, submitting their paper to the ''Journal of Electroanalytical Chemistry'' on March 11, and disclosing their work via a press conference on March 23.<ref name="LADN_092489">{{harvnb|Crease|Samios|1989|p=V1}}.</ref> | |||
The 2004 DOE panel noted that significant progress has been made in the sophistication of calorimeters since 1989. Evaluations by the reviewers ranged from: 1) evidence for excess power is compelling, to 2) there is no convincing evidence that excess power is produced when integrated over the life of an experiment. The reviewers were split approximately evenly on this topic.<ref name="DOEr_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
Jones, upset, faxed in his paper to Nature after the press announcement was made.<ref name="Kowalski_2004_V">{{harvnb|Kowalski|2004|loc=V}}.</ref> | |||
Many of the reviewers noted that poor experiment design, documentation, background control and other similar issues hampered the understanding and interpretation of the results presented to the DOE panel. The reviewers who did not find the production of excess power convincing said that excess power in the short term is not the same as net energy production over the entire time of an experiment, that such short-term excess power is only a few percent of the total external power applied and hence ] and systematic effects could account for the purported effect, that all possible chemical and solid state causes of excess heat had not been investigated and eliminated as an explanation, that the ] of the effect had not increased after over a decade of work.<ref name="DOEr_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
===Post-announcement=== | |||
The press initially reported on the experiments widely, and due to the surmised beneficial commercial applications of the Utah experiments, "scores of laboratories in the United States and abroad" attempted to repeat the experiments.<ref name="Browne_1989">{{harvnb|Browne|1989}}.</ref> | |||
===Lack of reproducibility of excess heat=== | |||
On ], ], Fleischmann and Pons, who later suggested pressure from patent attorneys, published a rushed "preliminary note" in the ''Journal of Electroanalytical Chemistry''.<ref name="Krivit_2005">{{harvnb|Krivit|2005}}.</ref> This paper notably contained a gamma peak without its corresponding ], a discrepancy that triggered accusations of fraud.<ref>{{harvnb|Tate|1989|p=1}}.</ref><ref>{{harvnb|Platt|1989}}.</ref> Their earlier paper was followed up a year later in July 1990, when a much longer paper, going into details of calorimetry but abandoning mention of any nuclear measurements, was published in the same journal. | |||
The cold fusion researchers who presented their review document to the 2004 DOE panel on cold fusion said that the observation of excess heat has been reproduced, that it can be reproduced at will under the proper conditions, and that many of the reasons for failure to reproduce it have been discovered.<ref name="DOE_2004_14">{{harvnb|Hagelstein et al.|2004|Ref=DOE2004|p=14}}.</ref> Contrary to these assertions, most reviewers stated that the effects are not repeatable, the magnitude of the effect has not increased in over a decade of work, and that many of the reported experiments were not well documented.<ref name="DOE_2004_3">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3}}.</ref> | |||
In 1989, the DOE panel noted that "Even a single short but valid cold fusion period would be revolutionary. As a result, it is difficult convincingly to resolve all cold fusion claims since, for example, any good experiment that fails to find cold fusion can be discounted as merely not working for unknown reasons."<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}.</ref> | |||
Also occurring on April 10, a team at ] published their results of excess heat, followed up by a team at the ] in regards to neutron production.{{cn|date=February 2008}} Both results were widely reported on in the press, although both Texas A&M and Georgia Institute of Technology withdrew their results for lack of evidence.{{cn|date=February 2008}} For the next six weeks, additional competing claims, counterclaims and suggested explanations kept the topic of Cold Fusion paramount, and led some journalists refer to the situation as "fusion confusion."<sup>''cf.'' </sup><ref>{{harvnb|Bowen|1989}}.</ref> | |||
===Missing nuclear products=== | |||
On ], Pons received a standing ovation from about 7,000 chemists at the semi-annual meeting of the ]. The University of Utah asked Congress to provide $25 million to pursue the research, and Pons was scheduled to meet with representatives of ] early May.<ref name="Browne_1989">{{harvnb|Browne|1989}}.</ref> | |||
The fusion of two ] nuclei usually produces either a ] nucleus and a ], or a ] (<sup>3</sup>He) nucleus and a ]. The level of neutrons, tritium and <sup>3</sup>He actually observed in the Fleischmann-Pons experiments have been well below the level expected in view of the heat generated, implying that these fusion reactions cannot explain it. If the excess heat were generated by the fusion of two deuterium nuclei into helium (<sup>4</sup>He), a reaction which is normally extremely rare, ]s and helium (alpha particles) would be expected. In 1989, insufficient levels of helium (alpha particles) and gamma rays were observed to explain the excess heat.<ref name="DOE_1989_5_6">{{harvnb|US DOE|1989|Ref=DOE1989|pp=5-6}}.</ref> | |||
When asked about evidence of low energy nuclear reactions, twelve of the eighteen members of the 2004 DOE panel did not feel that there was any conclusive evidence, five found the evidence "somewhat convincing", and one was entirely convinced. The evidence of D+D fusion was taken as convincing or somewhat convincing by some reviewers; for others the lack of consistency was an indication that the overall hypothesis was not justified. Contamination of apparatus or samples by air containing <sup>4</sup>He was cited as one possible cause for false positive results in some measurements.<ref name="DOEr_2004_34">{{harvnb|US DOE|2004|Ref=DOE2004r|p=3-4}}.</ref> | |||
One month later, on ], the ] held a session on cold fusion, reported a string of failed experiments. A second session began the next day with other negative reports, and eight of the nine leading speakers stated that they ruled the initial Utah claim as dead.{{cn|date=February 2008}} Dr. Steven E. Koonin of ] called the Utah report a result of "the incompetence and delusion of Pons and Fleischmann."{{cn|date=February 2008}} Dr. Douglas R. O. Morrison, a physicist representing ], called the entire episode an example of ].<ref name="Browne_1989_para29">{{harvnb|Browne|1989|loc=para. 29}}.</ref><!-- The following citation does not support that statement: {{citation|editor-last=Krumhansi|editor-first=J. A.|title=APS Special Session on Cold Fusion, May 1-2, 1989|year=1989|url=http://www.ibiblio.org/pub/academic/physics/Cold-fusion/vince-cate/aps.ascii}} --> | |||
===Lack of theoretical explanations=== | |||
By the end of May, much of the ] attention had faded due to not only to the competing results and counterclaims, but also to the limited attention span of modern media.{{cn|date=February 2008}} While the research efforts cooled significantly, similar cold fusion projects continued around the world.{{cn|date=February 2008}} | |||
Temperatures and pressures similar to those in ]s are required for conventional nuclear fusion. The 1989 DOE panel said that such "nuclear fusion at room temperature would be contrary to all understanding gained of nuclear reactions in the last half century" and "it would require the invention of an entirely new nuclear process."<ref name="DOE_1989_37">{{harvnb|US DOE|1989|Ref=DOE1989|p=37}}.</ref> but it also recognized that "the failure of a theory to account for cold fusion can be discounted on the grounds that the correct explanation and theory has not been provided",<ref name="DOE_1989_36">{{harvnb|US DOE|1989|Ref=DOE1989|p=36}}.</ref> that is, the lack of a satisfactory explanation could not be used to dismiss experimental evidence. | |||
Cold fusion observations are contrary to the conventional physics of nuclear fusion in several ways : | |||
In July, the first successful replication of the excess heat was completed by Richard Oriani, a professor of physical chemistry at the ].<ref name="Krivit_2005">{{harvnb|Krivit|2005}}.</ref> The results were published in his paper, "Calorimetric Measurements of Excess Power Output During the Cathodic Charging of Deuterium Into Palladium," in Fusion Technology.<ref>{{harvnb|Oriani|Nelson|Lee|Broadhurst|1990|pp=652-662}}.</ref><ref name="Krivit_2005">{{harvnb|Krivit|2005}}.</ref> | |||
* The average density of deuterium atoms in the palladium rod seems vastly insufficient to force pairs of nuclei close enough for fusion to occur according to mechanisms known to mainstream theories. The average distance is approximately 0.17 ]s, a distance at which the attractive ] cannot overcome the ]. Deuterium atoms are closer together in D<sub>2</sub> gas molecules, which do not exhibit fusion.<ref name="DOE_1989_6_7">{{harvnb|US DOE|1989|Ref=DOE1989|pp=6-7}}.</ref> | |||
''Nature'' published papers critical of cold fusion in July and November.<ref>{{harvnb|Gai et al.|Ref=Gai1989|1989|pp=29-34}}.</ref><ref>{{harvnb|Williams et a.|1989|Ref=Williams1989|pp=375-384}}.</ref> | |||
* There is no known mechanism that would release fusion energy as heat instead of radiation within the relatively small metal lattice.<ref name="Goodstein_1994_528">{{harvnb|Goodstein|1994|p=528}}.</ref> The direct conversion of fusion energy into heat is not possible because of energy and ] conservation and the laws of ].<ref name="Kee_1999_5">{{harvnb|Kee|1999|p=5}}.</ref> | |||
* Transmutations introduce additional discrepancies between observations and conventional theory because of the increased Coulomb barrier. | |||
In November, a special panel formed by the ''Energy Research Advisory Board'', under a charge of the ], reported the result of their investigation into cold fusion. The scientists in the panel found the evidence for cold fusion to be unconvincing. Nevertheless, the panel was "sympathetic toward modest support for carefully focused and cooperative experiments within the present funding system."<ref name="DOE_1989_37">{{harvnb|US DOE|1989|Ref=DOE1989|p=37}}.</ref> As 1989 wore on, cold fusion was considered by ] to be self-deception, experimental error and even fraud, and was held out as a prime example of ].{{cn|date=February 2008}} The ] has rejected most patent applications related to cold fusion since then.{{cn|date=February 2008}} | |||
In 1991, Dr. ] stated that the negative report issued by ]'s ''Plasma Fusion Center'' in 1989, which was highly influential in the controversy, was fraudulent because data was shifted without explanation, and as a consequence, this action obscured a possible positive excess heat result at MIT.<!-- the following citation is not valid (or is OR) for the previous statement. {{cite web|last=Krivit|first=Steven|title=Controversial MIT. Cold Fusion Graphs|url=http://newenergytimes.com/Reports/HistoricalAnalysisSummaryCharts.htm#mit}}</ref> --> In protest of MIT's failure to discuss and acknowledge the significance of this data shift, Mallove resigned from his post of chief science author at the MIT news office on ], ]. He maintained that the data shift was biased to support the conventional belief in the non-existence of the cold fusion effect as well as to protect the financial interests of the plasma fusion center's research in hot fusion.<ref>{{harvnb|Mallove|1999|p=??}}.</ref> | |||
Nobel Laureate ] also stated in 1991 that he had experienced "the pressure for conformity in editor's rejection of submitted papers, based on venomous criticism of anonymous reviewers," and that "the replacement of impartial reviewing by censorship will be the death of science."<ref>{{harvnb|Schwinger|1991|p=??}}.</ref> He resigned as Member and Fellow of the ''American Physical Society'', in protest of its peer review practice on cold fusion. | |||
In 1992, General Electric challenged the Fleischmann-Pons 1990 report in the ''Journal of Electroanalytical Chemistry'', stating that the claims of excess heat had been overstated.<ref>{{harvnb|Wilson|1992|p=1}}.</ref><ref name="Krivit_2005">{{harvnb|Krivit|2005}}.</ref> The challenge concluded that the Fleischmann and Pons cell generated 40% excess heat, more than ten times larger than the initial error estimate. Despite the apparent confirmation, Fleischmann and Pons replied to General Electric and published a rebuttal in the same journal.<ref>{{harvnb|Beaudette|2002|pp=188, 357-360}}.</ref><!-- commented out extraordinary statement lacking extraordinary sources: "...which has never been refuted in scientific literature.<ref>{{cite web|last=Krivit|first=Steven|title=The Seminal Papers of Cold Fusion|publisher=New Energy Times|url=http://newenergytimes.com/PR/TheSeminalPapers.htm}}</ref>" --> | |||
===Moving beyond the initial controversy=== | |||
In the 1990s, there was little cold fusion research in the United States, and much of the research during this time occurred in Europe and Asia.{{cn|date=February 2008}} Fleischmann and Pons relocated their laboratory to France under a grant from the ], and later sued ], an ] newspaper and a journalist for their suggestion that cold fusion was a scientific fraud. They lost the ] case in an Italian court.{{cn|date=February 2008}} In 1996, they announced in ''Nature'' that they would appeal the court's decision, but never did.{{cn|date=February 2008}} | |||
By 1991, 92 groups of researchers from 10 different countries had reported excess heat, tritium, neutrons or other nuclear effects.<ref>{{harvnb|Mallove|1991|p=246-248}}.</ref> Over 3,000 cold fusion papers have been published including about 1,000 in peer-reviewed journals (see indices in ], below). In March 1995, Dr. Edmund Storms compiled a list of 21 published papers reporting excess heat and rticles have been published in ]ed journals such as Naturwissenschaften, European Physical Journal A, European Physical Journal C, Journal of Solid State Phenomena, ], Journal of Electroanalytical Chemistry, ], and Journal of Fusion Energy (see indices in ], below). | |||
] | |||
The generation of excess heat has been reported by (among others): | |||
* Michael McKubre, director of the Energy Research Center at ], | |||
* G. Preparata (]) | |||
* Richard A. Oriani (], in December 1990), | |||
* Robert A. Huggins (at ] in March 1990), | |||
* Y. Arata (], ]), | |||
* T. Mizuno (], ]), | |||
* T. Ohmori (]), | |||
The most common experimental set-ups are the electrolytic (electrolysis) cell and the gas (glow) discharge cell, but many other set-ups have been used. Electrolysis is popular because it was the original experiment and more commonly known way of conducting the cold fusion experiment; gas discharge is often used because it is believed to be the set-up that provides an experimenter a better chance at replication of the excess heat results. | |||
Researchers share their results at the International Conference on Cold Fusion, recently renamed International Conference on Condensed Matter Nuclear Science. The conference is held every 12 to 18 months in various countries around the world, and is hosted by , a scientific organization that was founded as a professional society to support research efforts and to communicate experimental results. Proceedings of these conferences and other papers published in scientific journals have been collected in a . A few periodicals emerged in the 1990s that covered developments in cold fusion and related new energy sciences (Fusion Facts, Cold Fusion Magazine, Infinite Energy Magazine, New Energy Times). | |||
] of the open type, used at the New Hydrogen Energy Institute in Japan. ''Source: SPAWAR/US Navy TR1862'']] Between 1992 and 1997, Japan's ] sponsored a "New Hydrogen Energy Program" of $20 million to research cold fusion. Announcing the end of the program, Dr. Hideo Ikegami stated in 1997 "We couldn't achieve what was first claimed in terms of cold fusion." He added, "We can't find any reason to propose more money for the coming year or for the future."<ref>{{harvnb|Pollack|1997|p=C4}}.</ref> | |||
In 1994, Dr. ] described cold fusion as "a pariah field, cast out by the scientific establishment. Between and respectable science there is virtually no communication at all. Cold fusion papers are almost never published in refereed scientific journals, with the result that those works don't receive the normal critical scrutiny that science requires. On the other hand, because the Cold-Fusioners see themselves as a community under siege, there is little internal criticism. Experiments and theories tend to be accepted at face value, for fear of providing even more fuel for external critics, if anyone outside the group was bothering to listen. In these circumstances, crackpots flourish, making matters worse for those who believe that there is serious science going on here.''<ref name="Goodstein_1994_?">{{harvnb|Goodstein|1994|p=??}}.</ref> | |||
Cold fusion researchers said that cold fusion is suppressed, and that skeptics suffer from "]".<ref>{{harvnb|Josephson|2004|p=??}}.</ref> They said that there is virtually no possibility for funding in cold fusion in the United States, and no possibility of getting published.<ref name="Feder_2004_27">{{harvnb|Feder|2004|p=27}}.</ref> They said that people in universities refuse to work on it because they would be ridiculed by their colleagues.<ref>{{harvnb|Rusbringer|2005}}</ref> | |||
In February 2002, a laboratory within the United States Navy released a report<ref>{{harvnb|Szpak|Mosier-Boss|2002a}}</ref><ref>{{harvnb|Szpak|Mosier-Boss|2002b}}</ref> that came to the conclusion that the cold fusion phenomenon was in fact real and deserved an official funding source for research.{{page number}} Navy researchers have published on cold fusion. | |||
In 2004, the United States Department of Energy (USDOE) decided to take another look at cold fusion to determine if their policies towards cold fusion should be altered due to new experimental evidence. They set up a panel on cold fusion. | |||
==Other kinds of fusion== | |||
Some other kinds of fusion may be termed "cold" in some sense but are separate from the cold fusion controversy. "Cold" may be taken in the sense that no part of the reaction is actually hot (except for the reaction products), or that the energies required are low and the bulk of the material is at a relatively low temperature. Some other kinds of fusion are "hot", involving reactions which create macroscopic regions of very high temperature and pressure. | |||
===Locally cold fusion=== | |||
* ] is a well-established and reproducible fusion process which occurs at low temperatures. It has been studied in detail by ] in the early 1980s. Because of the energy required to create ]s, it is not able to produce net energy. | |||
===Generally cold, locally hot fusion=== | |||
* In ], microscopic droplets of ] (on the order of 100-1000 molecules) are accelerated to collide with a target, so that their temperature at impact reaches at most 10<sup>5</sup> ], 10,000 times smaller than the temperature required for hot fusion. In 1989, Friedlander and his coworkers observed 10<sup>10</sup> more fusion events than expected with standard fusion theory. Recent research<sup>''cf.'' </sup><ref>{{harvnb|Kim|Yoon|Rice|Rabinowitz|1992|pp=373-376}}.</ref> suggests that the calculation of effective temperature may have failed to account for certain molecular effects which raise the effective collision temperature, so that this is a microscopic form of hot fusion. | |||
* In ], acoustic shock waves create temporary bubbles that collapse shortly after creation, producing very high temperatures and pressures. In 2002, Rusi P. Taleyarkhan explored the possibility that ] occurs in those collapsing bubbles. If this is the case, it is because the temperature and pressure are sufficiently high to produce hot fusion. | |||
* The ] is a tabletop device in which fusion occurs. This fusion comes from high effective temperatures produced by electrostatic acceleration of ions. The device can be built inexpensively, but it too is unable to produce a net power output. | |||
* ] uses small amounts of antimatter to trigger a tiny fusion explosion. This has been studied primarily in the context of making ] feasible. | |||
Several of these systems are "nonequilibrium systems", in which very high temperatures and pressures are produced in a relatively small region adjacent to material of much lower temperature. In his doctoral thesis for ], Todd Rider did a theoretical study of all non-equilibrium fusion systems. He demonstrated that all such systems will leak energy at a rapid rate due to ], radiation produced when ]s in the ] hit other electrons or ]s at a cooler temperature and suddenly decelerate. The problem is not as pronounced in a hot plasma because the range of temperatures, and thus the magnitude of the deceleration, is much lower. | |||
Cold fusion researchers acknowledge these issues and have proposed various speculative theories (for a full review, see {{harvnb|Storms|2007}}) to explain the reported observations, but none has received mainstream acceptance.<ref name="Biberian_2007" /> | |||
===Hot fusion=== | |||
* "Standard" fusion, in which the fuel reaches tremendous temperature and pressure inside a ], ], or ]. | |||
==Notes== | ==Notes== | ||
{{refbegin}} | {{refbegin}} | ||
* '''α'''.{{Note_label|heat_tritium_reports|α|none}} References to publications are listed in {{harvnb|Storms|2007|pp=52-61,79-81}} and in {{harvnb|Hagelstein et al.|2004|Ref=DOE2004|pp=25-29}}, to include {{harvnb|Arata|Zhang|1998}}, {{harvnb|Iwamura|Sakano|Itoh|2002}}, {{harvnb|Mizuno|Ohmori|Akimoto|Takahashi|2000}}, {{harvnb|Miles et al.|1993|Ref=MilesEtAl1993}} and {{harvnb|Bush|Langowski|Miles|Ostrom|1991}}. Electrochemist , who has remained neutral on the question of whether cold fusion exists,<!-- http://groups.google.com/group/sci.physics.fusion/msg/cd82ea9f80a813c0 --> has compiled which includes |
* '''α'''.{{Note_label|heat_tritium_reports|α|none}} References to publications are listed in {{harvnb|Storms|2007|pp=52-61,79-81}} and in {{harvnb|Hagelstein et al.|2004|Ref=DOE2004|pp=25-29}}, to include {{harvnb|Arata|Zhang|1998}}, {{harvnb|Iwamura|Sakano|Itoh|2002}}, {{harvnb|Mizuno|Ohmori|Akimoto|Takahashi|2000}}, {{harvnb|Miles et al.|1993|Ref=MilesEtAl1993}} and {{harvnb|Bush|Langowski|Miles|Ostrom|1991}}. Electrochemist , who has remained neutral on the question of whether cold fusion exists,<!-- http://groups.google.com/group/sci.physics.fusion/msg/cd82ea9f80a813c0 --> has compiled which includes numerous published scientific journal articles marked "res+", indicating positive research results or supportive theoretical calculations. | ||
{{refend}} | {{refend}} | ||
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{{refbegin}} | {{refbegin}} | ||
*{{citation|last=Anderson|first=Mark|title=Cold-Fusion Graybeards Keep the Research Coming|journal=Wired Magazine|year=2007|volume=2007|issue=8|url=http://www.wired.com/science/discoveries/news/2007/08/cold_fusion}} | *{{citation|last=Anderson|first=Mark|title=Cold-Fusion Graybeards Keep the Research Coming|journal=Wired Magazine|year=2007|volume=2007|issue=8|url=http://www.wired.com/science/discoveries/news/2007/08/cold_fusion| accessdate = 2008-05-25}} | ||
*{{citation|last=Arata|first=Yoshiaki|last2=Zhang|first2=Yue-Chang|title=Anomalous difference between reaction energies generated within D<sub>2</sub>0-cell and H<sub>2</sub>0 Cell|journal=Japanese Journal of Applied Physics|volume=37|issue=11A|year=1998|pages=L1274-L1276}}. | *{{citation|last=Arata|first=Yoshiaki|last2=Zhang|first2=Yue-Chang|title=Anomalous difference between reaction energies generated within D<sub>2</sub>0-cell and H<sub>2</sub>0 Cell|journal=Japanese Journal of Applied Physics|volume=37|issue=11A|year=1998|pages=L1274-L1276}}. | ||
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*{{citation|last=Beaudette|first=Charles G.|title=Excess Heat & Why Cold Fusion Research Prevailed|year=2002|location=New York|publisher=Oak Grove Press|isbn=9-9678548-2-2}} | *{{citation|last=Beaudette|first=Charles G.|title=Excess Heat & Why Cold Fusion Research Prevailed|year=2002|location=New York|publisher=Oak Grove Press|isbn=9-9678548-2-2}} | ||
*{{citation|last=Biberian|first=Jean-Paul|title=Condensed Matter Nuclear Science (Cold Fusion): An Update|journal=International Journal of Nuclear Energy Science and Technology|volume=3|issue=1|year=2007|pages= |
*{{citation|last=Biberian|first=Jean-Paul|title=Condensed Matter Nuclear Science (Cold Fusion): An Update|journal=International Journal of Nuclear Energy Science and Technology|volume=3|issue=1|year=2007|pages=31–43|doi=10.1504/IJNEST.2007.012439 |url=http://www.jeanpaulbiberian.net/Download/Paper%2056.pdf}}. | ||
*{{citation|last=Bowen|first=Jerry|title=Science: Nuclear Fusion|periodical=CBS Evening News|issue=April 10, 1989|year=1989|url=http://openweb.tvnews.vanderbilt.edu/1989-4/1989-04-10-CBS-7.html}}. | *{{citation|last=Bowen|first=Jerry|title=Science: Nuclear Fusion|periodical=CBS Evening News|issue=April 10, 1989|year=1989|url=http://openweb.tvnews.vanderbilt.edu/1989-4/1989-04-10-CBS-7.html| accessdate = 2008-05-25}}. | ||
*{{citation|last= |
*{{citation|last=Broad|first=William J.|title=Georgia Tech Team Reports Flaw In Critical Experiment on Fusion|journal=New York Times| date=April 14, 1989|year=1989| url=http://query.nytimes.com/gst/fullpage.html?res=950DE7DE1130F937A25757C0A96F948260| accessdate = 2008-05-25}}. | ||
*{{citation|last=Britz|first=Dieter|title=Book review:The Science of Low Energy Nuclear Reaction|journal=J. Sci. Exploration|year=2008| volume=21, #4| pages=801}}. | |||
* {{citation|last=Bush|first=Ben F.|last2=Lagowski|first2=J. J.|last2=Miles|first2=M. H.|last2=Ostrom|first2=Greg S.|year=1991|title=Helium Production During the Electrolysis of D<sub>2</sub>O in Cold Fusion|journal=Journal of Electroanalytical Chemistry|volume=304|pages=271-278|url=http://www.lenr-canr.org/acrobat/BushBFheliumprod.pdf}}. | |||
*{{citation|last=Browne|first=M.|title=Physicists Debunk Claim Of a New Kind of Fusion| journal=New York Times| date=May 3, 1989 |year=1989| url=http://partners.nytimes.com/library/national/science/050399sci-cold-fusion.html| accessdate = 2008-05-25}}. | |||
* {{citation|last=Bush|first=Ben F.|last2=Lagowski|first2=J. J.|last2=Miles|first2=M. H.|last2=Ostrom|first2=Greg S.|year=1991|title=Helium Production During the Electrolysis of D<sub>2</sub>O in Cold Fusion|journal=Journal of Electroanalytical Chemistry|volume=304|pages=271–278}}. | |||
*{{citation|last=Bush|first=R. T.|last2=Eagleton|first2=R.D.|title=Evidence of electrolytically induced transmutation and radioactivity correlated with excess heat in Electrolytic cells with light water rubidium salt electrolytes|journal=Transactions of Fusion Technology|year=1994|volume=26|issue=4T}}. | *{{citation|last=Bush|first=R. T.|last2=Eagleton|first2=R.D.|title=Evidence of electrolytically induced transmutation and radioactivity correlated with excess heat in Electrolytic cells with light water rubidium salt electrolytes|journal=Transactions of Fusion Technology|year=1994|volume=26|issue=4T}}. | ||
*{{citation|last=Cartwright|first=Jon |year=2008|title=Cold-fusion demonstration "a success" |publisher=PhysicsWorld.com|url=http://physicsworld.com/blog/2008/05/coldfusion_demonstration_a_suc.html| accessdate = 2008-05-25}} | |||
*{{citation|last=Chubb|first=Scott et al.|ref=APS2006|title=Session W41: Cold Fusion|series=Proceedings of the 2006 APS March Meeting, March 13–17, 2006 in Baltimore|location=College Park, MD|publisher=American Physical Society|year=2006|url=http://meetings.aps.org/Meeting/MAR06/SessionIndex2/?SessionEventID=45597}}. | |||
*{{citation|last=Cartwright|first=Jon |year=2008b|title=Cold-fusion demonstration: an update |publisher=PhysicsWorld.com|url=http://physicsworld.com/blog/2008/06/coldfusion_demonstration_an_up_1.html| accessdate = 2008-06-23}} | |||
*{{citation|last=Chubb|first=Scott et al.|ref=APS2006|title=Session W41: Cold Fusion|publisher=American Physical Society|year=2006|url=http://meetings.aps.org/Meeting/MAR06/SessionIndex2/?SessionEventID=45597| accessdate = 2008-05-25}}. | |||
*{{citation|last=Close|first=Frank E.|authorlink=Frank Close|title=Too Hot to Handle: The Race for Cold Fusion|location=Princeton, N.J.|publisher=Princeton University Press|year=1991|isbn=0-691-08591-9}}. | *{{citation|last=Close|first=Frank E.|authorlink=Frank Close|title=Too Hot to Handle: The Race for Cold Fusion|location=Princeton, N.J.|publisher=Princeton University Press|year=1991|isbn=0-691-08591-9}}. | ||
*{{citation|last=Crease|first=Robert|last2=Samios|first2=N. P.|title=Cold Fusion confusion |
*{{citation|last=Crease|first=Robert|last2=Samios|first2=N. P.|title=Cold Fusion confusion|journal=New York Times Magazine|page=34-38|year=1989|issue=September 24, 1989|accessdate=2008-02-02}} | ||
*{{citation|last=Feder|first=Toni|title=DOE Warms to Cold Fusion|journal=Physics Today|year=2004|volume=57|issue=4|pages=27–28|url=http://scitation.aip.org/journals/doc/PHTOAD-ft/vol_57/iss_4/27_1.shtml| accessdate = 2008-05-25}} | |||
*{{citation|last=Evans|first=Robley D.|title=The Atomic Nucleus|year=1982|location=New York|publisher=Krieger Publishing|isbn=0-89874-414-8}}. | |||
*{{citation|last=Feder|first=Toni|title=DOE Warms to Cold Fusion|journal=Physics Today|year=2004|volume=57|issue=4|pages=27-28|url=http://www.physicstoday.org/vol-57/iss-4/p27.html}} | |||
*{{citation|last=Feder|first=Toni|title= Cold Fusion Gets Chilly Encore|journal=Physics Today|year=2005 |
*{{citation|last=Feder|first=Toni|title= Cold Fusion Gets Chilly Encore|journal=Physics Today|year=2005|url=http://scitation.aip.org/journals/doc/PHTOAD-ft/vol_58/iss_1/31_1.shtml| accessdate = 2008-05-25}} | ||
*{{citation|last=Fleischmann|first=Martin|last2=Pons|first2=Stanley|title=Electrochemically induced nuclear fusion of deuterium|journal=Journal of Electroanalytical Chemistry|volume=261|issue=2A|pages= |
*{{citation|last=Fleischmann|first=Martin|authorlink=Martin Fleischmann|last2=Pons|first2=Stanley|title=Electrochemically induced nuclear fusion of deuterium|journal=Journal of Electroanalytical Chemistry|volume=261|issue=2A|pages=301–308|year=1989|url=http://dx.doi.org/10.1016/0022-0728(89)80006-3}}. | ||
*{{citation|ref=Fleischmann1990|last=Fleischmann|first=Martin|last2=Pons|first2=Stanley|last3=Anderson|first3=Mark W.|last4=Li|first4=Lian Jun|last5=Hawkins|first5=Marvin|title=Calorimetry of the palladium-deuterium-heavy water system|journal=Journal of Electroanalytical Chemistry|volume=287|year=1990|pages= |
*{{citation|ref=Fleischmann1990|last=Fleischmann|first=Martin|last2=Pons|first2=Stanley|last3=Anderson|first3=Mark W.|last4=Li|first4=Lian Jun|last5=Hawkins|first5=Marvin|title=Calorimetry of the palladium-deuterium-heavy water system|journal=Journal of Electroanalytical Chemistry|volume=287|year=1990|pages=293–348}} | ||
*{{citation|ref=Fleischmann1992|last=Fleischmann|first=Martin|last2=Pons|first2=Stanley|title=Some Comments on The Paper 'Analysis of Experiments on The Calorimetry of Liod-D2O Electrochemical Cells,' R.H. Wilson et al., Journal of Electroanalytical Chemistry, Vol. 332, (1992)",|journal=Journal of Electroanalytical Chemistry|volume=332|year=1992|pages=33}} | |||
*{{citation|last=Fleischmann|first=Martin|year=2003|chapter=Background to cold fusion: the genesis of a concept|title=Tenth International Conference on Cold Fusion|location=Cambridge, MA|publisher=LENR-CANR.org|url=http://www.lenr-canr.org/acrobat/Fleischmanbackground.pdf}} | |||
*{{citation|last=Fleischmann|first=Martin|year=2003|chapter=Background to cold fusion: the genesis of a concept|title=Tenth International Conference on Cold Fusion|location=Cambridge, MA|publisher=World Scientific Publishing|ISBN=978-9812565648}} | |||
*{{citation|ref=Gai1989|last=Gai|first=M.|first2=S. L.|last2=Rugari|first3=R. H.|last3=France|first4=B. J.|last4=Lund|first5=Z.|last5=Zhao|first6=A. J.|last6=Davenport|first7=H. S.|last7=Isaacs|first8=K. G.|last8=Lynn|title=Upper limits on neutron and big gamma-ray emission from cold fusion|journal=Nature|volume=340|pages=29-34|year=1989|doi=10.1038/340029a0}} | |||
*{{citation|ref=Gai1989|last=Gai|first=M.|first2=S. L.|last2=Rugari|first3=R. H.|last3=France|first4=B. J.|last4=Lund|first5=Z.|last5=Zhao|first6=A. J.|last6=Davenport|first7=H. S.|last7=Isaacs|first8=K. G.|last8=Lynn|title=Upper limits on neutron and big gamma-ray emission from cold fusion|journal=Nature|volume=340|pages=29–34|year=1989|doi=10.1038/340029a0}} | |||
*{{citation|last=Goodstein|first=David|title=Whatever happened to cold fusion?|journal=The American Scholar|volume=63|issue=4|year=1994|pages=527-541|url=http://www.its.caltech.edu/~dg/fusion_art.html}}. | |||
*{{citation|last=Goodstein|first=David|title=Whatever happened to cold fusion?|journal=The American Scholar|volume=63|issue=4|year=1994|pages=527-541|url=http://www.its.caltech.edu/~dg/fusion_art.html| accessdate = 2008-05-25}}. | |||
*{{citation|last=Hagelstein|first=Peter|last2=Michael|first2=McKubre|last3=Nagel|first3=David|last4=Chubb|first4=Talbot|last5=Hekman|first5=Randall|title=New Physical Effects in Metal Deuterides|location=Washington|publisher=USDOE|year=2004|url=http://www.science.doe.gov/Sub/Newsroom/News_Releases/DOE-SC/2004/low_energy/Appendix_1.pdf|ref=DOE2004}} | |||
*{{citation|last=Hagelstein|first=Peter|authorlink=Peter L. Hagelstein|last2=Michael|first2=McKubre | |||
*{{citation|last=Higashiyama|first=Taichi|last2=Sakano|first2=Mitsuru|last3=Miyamaru|first3=Hiroyuki|last4=Takahashi|first4=Akito|chapter=Replication of MHI Transmutation Experiment by D2 Gas Permeation Through Pd Complex|title=Tenth International Conference on Cold Fusion|year=2003|location=Cambridge, MA|publisher=LENR-CANR.org|url=http://www.lenr-canr.org/acrobat/Higashiyamreplicatio.pdf}} | |||
|last3=Nagel|first3=David|last4=Chubb|first4=Talbot|last5=Hekman|first5=Randall | |||
|title=New Physical Effects in Metal Deuterides|location=Washington|publisher=USDOE|year=2004 | |||
|url=http://web.archive.org/web/20070106185101/www.science.doe.gov/Sub/Newsroom/News_Releases/DOE-SC/2004/low_energy/Appendix_1.pdf | |||
|ref=DOE2004| accessdate = 2008-07-19}} | |||
*{{citation|last=Higashiyama|first=Taichi|last2=Sakano|first2=Mitsuru|last3=Miyamaru|first3=Hiroyuki|last4=Takahashi|first4=Akito|chapter=Replication of MHI Transmutation Experiment by D2 Gas Permeation Through Pd Complex|title=Tenth International Conference on Cold Fusion|year=2003|location=Cambridge, MA|publisher=publisher=World Scientific Publishing Company|ISBN=978-9812565648}} | |||
*{{citation|last=Hubler|first=G. K.|title=Anomalous Effects in Hydrogen-Charged Palladium - A Review|journal=Surface and Coatings Technology|volume=201|issue=19-20|year=2007|pages=8568-8573|doi=10.1016/j.surfcoat.2006.03.062}} | *{{citation|last=Hubler|first=G. K.|title=Anomalous Effects in Hydrogen-Charged Palladium - A Review|journal=Surface and Coatings Technology|volume=201|issue=19-20|year=2007|pages=8568-8573|doi=10.1016/j.surfcoat.2006.03.062}} | ||
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*{{citation|last=Huizenga|first=John R.|title=Cold Fusion: The Scientific Fiasco of the Century|location=Rochester, N.Y.|publisher=University of Rochester Press|year=1992|isbn=1-878822-07-1}}. | *{{citation|last=Huizenga|first=John R.|title=Cold Fusion: The Scientific Fiasco of the Century|location=Rochester, N.Y.|publisher=University of Rochester Press|year=1992|isbn=1-878822-07-1}}. | ||
*{{citation|last=Hutchinson|first=Alex|title=The Year in Science: Physics|journal=Discover Magazine|year=2006|url=http://discovermagazine.com/2006/jan/physics| accessdate = 2008-06-20}} | |||
*{{citation|last=Iwamura|first=Yasuhiro|first2=Mitsuru|last2=Sakano|first3=Takehiko|last3=Itoh|title=Elemental Analysis of Pd Complexes: Effects of D<sub>2</sub> Gas Permeation|journal=Japanese Journal of Applied Physics|year=2002|volume=41|issue=7A|pages=4642-4650|doi=10.1143/JJAP.41.4642}}. <!-- not needed: http://lenr-canr.org/acrobat/IwamuraYelementalaa.pdf --> | |||
*{{citation|last=Iwamura|first=Yasuhiro|first2=Mitsuru|last2=Sakano|first3=Takehiko|last3=Itoh|title=Elemental Analysis of Pd Complexes: Effects of D<sub>2</sub> Gas Permeation|journal=Japanese Journal of Applied Physics|year=2002|volume=41|issue=7A|pages=4642-4650|doi=10.1143/JJAP.41.4642}}. | |||
*{{citation|last=Iwamura|first=Yasuhiro|chapter=Observation of Nuclear Transmutation Reactions induced by D2 Gas Permeation through Pd Complexes|title=Eleventh International Conference on Condensed Matter Nuclear Science|year=2004|location=Marseille, France|publisher=World Scientific Publishing Company|isbn=978-9812566409}} | |||
*{{citation|last=Jayaraman|first=K. S.|title=Cold fusion hot again|url=http://www.nature.com/nindia/2008/080117/full/nindia.2008.77.html| accessdate = 2008-05-25|journal=Nature India|year=2008|date=Jan 17, 2008|doi=10.1038/nindia.2008.77}} | |||
*{{citation|last=Iwamura|first=Yasuhiro|chapter=Observation of Nuclear Transmutation Reactions induced by D2 Gas Permeation through Pd Complexes|title=Eleventh International Conference on Condensed Matter Nuclear Science|year=2004|location=Cambridge, MA|publisher=LENR-CANR.org|chapter-url=http://lenr-canr.org/acrobat/IwamuraYobservatiob.pdf}} | |||
*{{citation|ref=Jones1995|last=Jones|first=J. E.|last2=Hansen|first2=L. D.|last3=Jones|first3=S. E.|last4=Shelton|first4=D. S.|last5=Thorne|first5=J. M.|title=Faradaic efficiencies less than 100% during electrolysis of water can account for reports of excess heat in`cold fusion` cells|year=1995|journal=Journal of Physical Chemistry|volume=99|issue=18|pages=6973-6979}} | *{{citation|ref=Jones1995|last=Jones|first=J. E.|last2=Hansen|first2=L. D.|last3=Jones|first3=S. E.|last4=Shelton|first4=D. S.|last5=Thorne|first5=J. M.|title=Faradaic efficiencies less than 100% during electrolysis of water can account for reports of excess heat in`cold fusion` cells|year=1995|journal=Journal of Physical Chemistry|volume=99|issue=18|pages=6973-6979}} | ||
*{{citation|last=Josephson|first=Brian. D.|title=Pathological Disbelief|year=2004|series=Lecture given at the Nobel Laureates’ meeting Lindau, June 30th., 2004|year=2004|url=http://www. |
*{{citation|last=Josephson|first=Brian. D.|auhtorlink=Brian David Josephson|title=Pathological Disbelief|year=2004|series=Lecture given at the Nobel Laureates’ meeting Lindau, June 30th., 2004|year=2004|url=http://www.lenr-canr.org/acrobat/JosephsonBpathologic.pdf| accessdate = 2008-07-17}}. | ||
*{{citation|last=Kee|first=B|title=What is the current scientific thinking on cold fusion? Is there any possible validity to this phenomenon?|series=Ask the Experts|journal=Scientific American|year=1999|date=October 21, 1999|url=http://www.sciam.com/askexpert_question.cfm?articleID=0007CC4D-394F-1C71-84A9809EC588EF21&pageNumber=2&catID=3}}. | *{{citation|last=Kee|first=B|title=What is the current scientific thinking on cold fusion? Is there any possible validity to this phenomenon?|series=Ask the Experts|journal=Scientific American|year=1999|date=October 21, 1999|url=http://www.sciam.com/askexpert_question.cfm?articleID=0007CC4D-394F-1C71-84A9809EC588EF21&pageNumber=2&catID=3| accessdate = 2008-05-25}}. | ||
*{{citation|last=Kim|first=Y. E.|last2=Yoon|first2=J.-H.|last3=Rice|first3=R. A.|last4=Rabinowitz|first4=Mario|title=Cluster-Impact Fusion and Effective Deuteron Temperature|journal=Physical Review Letters|volume=68|issue=3|year=1992|pages=373-376}}. | *{{citation|last=Kim|first=Y. E.|last2=Yoon|first2=J.-H.|last3=Rice|first3=R. A.|last4=Rabinowitz|first4=Mario|title=Cluster-Impact Fusion and Effective Deuteron Temperature|journal=Physical Review Letters|volume=68|issue=3|year=1992|pages=373-376}}. | ||
Line 264: | Line 241: | ||
*{{citation|last=Kozima|first=Hideo|title=The Science of the Cold Fusion phenomenon|publisher=Elsevier Science|location=New York|year=2006|ISBN=0-08-045110-1}}. | *{{citation|last=Kozima|first=Hideo|title=The Science of the Cold Fusion phenomenon|publisher=Elsevier Science|location=New York|year=2006|ISBN=0-08-045110-1}}. | ||
*{{citation|last=Krivit|first=Steven B.|title=The Seminal Papers of Cold Fusion|journal=New Energy Times|year=2005|url=http://www.newenergytimes.com/PR/TheSeminalPapers.htm}}. | *{{citation|last=Krivit|first=Steven B.|title=The Seminal Papers of Cold Fusion|journal=New Energy Times|year=2005|url=http://www.newenergytimes.com/PR/TheSeminalPapers.htm| accessdate = 2008-05-25}}. | ||
*{{citation|last=Krivit|first=Steven B.|title=Extraordinary Courage: Report on Some LENR Presentations at the 2007 American Physical Society Meeting|journal=New Energy Times|issue= |
*{{citation|last=Krivit|first=Steven B.|title=Extraordinary Courage: Report on Some LENR Presentations at the 2007 American Physical Society Meeting|journal=New Energy Times|issue=21|year=2007|url=http://www.newenergytimes.com/news/2007/NET21.htm#apsreport| accessdate = 2008-05-25}}. | ||
*{{citation|last= |
*{{citation|last=Krivit|first=Steven B.|title=Low Energy Nuclear Reaction Research – Global Scenario|journal=Current Science|year=2008|volume=94|issue=7|pages=854-857|url=http://www.ias.ac.in/currsci/apr102008/854.pdf| accessdate = 2008-07-19}}. | ||
*{{citation|last= |
*{{citation|last=Kruglinksi|first=Susan|title=Whatever Happened To... Cold Fusion?|journal=Discover Magazine|year=2006|url=http://discovermagazine.com/2006/mar/cold-fusion| accessdate = 2008-06-20}} | ||
*{{citation|last= |
*{{citation|last=Kowalski|first=Ludwik|title=Jones’s manuscript on History of Cold Fusion at BYU|location=Upper Montclair, NJ|publisher=csam.montclair.edu|year=2004|url=http://pages.csam.montclair.edu/~kowalski/cf/131history.html| accessdate = 2008-05-25}} | ||
*{{citation|last=Leggett|first=A.J.|title=Exact upper bound on barrier penetration probabilities in many-body systems: Application to ‘‘cold fusion’’|year=1989|journal=Phys. Rev. Lett.|issue=63|year=1989|pages=191-194}}. | |||
*{{citation|last=Miles|first=Melvin H.|last2=Hollins|first2=R. A.|last3=Bush|first3=Ben F.|last4=Logowski|first4=J. J.|last5=Miles|first5=R. E.|ref=MilesEtAl1993<!-- ref= needed because double "Miles" -->|title=Correlation of excess power and helium production during D<sub>2</sub>O and H<sub>2</sub>0 electrolysis using Palladium cathodes|journal=Journal of Electroanalytical Chemistry|year=1993|volume=346|issue=1-2|pages=99-117|url=http://www.lenr-canr.org/acrobat/MilesMcorrelatio.pdf}}. | |||
*{{citation|last=Lewenstein|first=Bruce V.|title=Cornell cold fusion archive|year=1994|url=http://rmc.library.cornell.edu/EAD/pdf_guides/RMM04451.pdf| accessdate = 2008-05-25|location=collection n°4451, Division of Rare and Manuscript Collections, Cornell University Library}} | |||
*{{citation|last=Mallove|first=Eugene|authorlink=Eugene Mallove|title=Fire from Ice: Searching for the Truth Behind the Cold Fusion Furor|location=London|publisher=Wiley|year=1991|ISBN=0-471-53139-1}}. | |||
*{{citation|last=Mallove|first=Eugene|title=MIT and Cold Fusion: A Special Report|year=1999|journal=Infinite Energy Magazine|volume=24|url=http://www.infinite-energy.com/images/pdfs/mitcfreport.pdf| accessdate = 2008-05-25}} | |||
*{{citation|last=Miles|first=Melvin H.|last2=Hollins|first2=R. A.|last3=Bush|first3=Ben F.|last4=Logowski|first4=J. J.|last5=Miles|first5=R. E.|ref=MilesEtAl1993<!-- ref= needed because double "Miles" -->|title=Correlation of excess power and helium production during D<sub>2</sub>O and H<sub>2</sub>0 electrolysis using Palladium cathodes|journal=Journal of Electroanalytical Chemistry|year=1993|volume=346|issue=1-2|pages=99–117}}. | |||
*{{citation|last=Miley|first=George H.|last2=Shrestha|first2=P.|chapter=Review Of Transmutation Reactions In Solids|title=Proceedings of the Tenth International Conference on Cold Fusion|year=2003|location=Cambridge, MA|publisher=World Scientific Publishing Company|ISBN=978-9812565648}} | |||
*{{citation|last=Mizuno|first=Tadahiko|title=Analysis of Elements for Solid State Electrolyte in Deuterium Atmosphere during Applied Field|year=1996|journal=J. New Energy|issue=1(2)|pages=37}}. | |||
*{{citation|last=Miley|first=George H.|last2=Shrestha|first2=P.|chapter=Review Of Transmutation Reactions In Solids|title=Proceedings of the Tenth International Conference on Cold Fusion|year=2003|location=Cambridge, MA|publisher=LENR-CANR.org|chapter-url=http://www.lenr-canr.org/acrobat/MileyGHreviewoftr.pdf}} | |||
*{{citation|last=Mizuno|first=Tadahiko|title=Nuclear Transmutation: The Reality of Cold Fusion|year=1998|location=Concord, NH: Infinite Energy Press}}. | *{{citation|last=Mizuno|first=Tadahiko|title=Nuclear Transmutation: The Reality of Cold Fusion|year=1998|location=Concord, NH: Infinite Energy Press}}. | ||
*{{citation|last=Mizuno|first=Tadahiko|last2=Ohmori|first2=Tadayoshi|last3=Akimoto|first3=Tadashi|last4=Takahashi|first4=Akito | *{{citation|last=Mizuno|first=Tadahiko|last2=Ohmori|first2=Tadayoshi|last3=Akimoto|first3=Tadashi|last4=Takahashi|first4=Akito | ||
|title=Production of Heat During Plasma Electrolysis in Liquid|journal=Japanese Journal of Applied Physics|volume=39|issue=10|year=2000|pages=6055-6061 |
|title=Production of Heat During Plasma Electrolysis in Liquid|journal=Japanese Journal of Applied Physics|volume=39|issue=10|year=2000|pages=6055-6061}}. | ||
*{{citation|last=Mosier-Boss|first=Pamela A.|last2=Szpak|first2=Stanislaw|last3=Gordon|first3=Frank E.|title=Production of High Energy Particles Using the Pd/D Co-Deposition Process|journal=Proceedings of the 2007 APS March Meeting, March 5–9, 2007 in Denver|location=College Park, MD|publisher=American Physical Society|year=2007|url=http://meetings.aps.org/link/BAPS.2007.MAR.A31.2| accessdate = 2008-05-25}}. retrieved on ], 2008 | |||
*{{citation|last=Mizuno|first=Tadahiko|chapter=Experimental Confirmation of the Nuclear Reaction at Low Energy Caused by Electrolysis in the Electrolyte|title=Proceeding for the Symposium on Advanced Research in Technology, Hokkaido University, March 15-17, 2000|year=2000|pages=95-106|url=http://www.lenr-canr.org/acrobat/MizunoTexperiment.pdf}}. | |||
*{{citation|last=Mosier-Boss|first=Pamela A.|last2=Szpak|first2=Stanislaw|last3=Gordon|first3=Frank E.|title= |
*{{citation|last=Mosier-Boss|first=Pamela A.|last2=Szpak|first2=Stanislaw|last3=Gordon|first3=Frank E.|last4=Forsley|first4=L. P. G.|title=Use of CR-39 in Pd/D co-deposition experiments|journal=European Physical Journal Applied Physics|issue=40|pages=293–303|year=2007|doi=10.1051/epjap:2007152}} | ||
*{{citation|last= |
*{{citation|last=Oriani|first=Richard A.|first2=John C.|last2=Nelson|first3=Sung-Kyu|last3=Lee|first4=J. H.|last4=Broadhurst|title=Calorimetric Measurements of Excess Power Output During the Cathodic Charging of Deuterium into Palladium|title=Fusion Technology|volume=18|year=1990|pages=652-662}}. | ||
*{{citation|last=Oriani|first=Richard A.|first2=John C.|last2=Nelson|first3=Sung-Kyu|last3=Lee|first4=J. H.|last4=Broadhurst|title=Calorimetric Measurements of Excess Power Output During the Cathodic Charging of Deuterium into Palladium|title=Fusion Technology|volume=18|year=1990|pages=652-662|url=http://www.lenr-canr.org/acrobat/OrianiRAcalorimetr.pdf}}. | |||
*{{citation|last=Park|first=Robert|authorlink=Robert L. Park|title=Voodoo Science: The Road from Foolishness to Fraud|location=New York|publisher=Oxford University Press|year=2000|ISBN=0-19-513515-6}}. | *{{citation|last=Park|first=Robert|authorlink=Robert L. Park|title=Voodoo Science: The Road from Foolishness to Fraud|location=New York|publisher=Oxford University Press|year=2000|ISBN=0-19-513515-6}}. | ||
*{{citation|last=Platt|first=Charles|title=What If Cold Fusion Is Real?|journal=Wired Magazine|year=1989|issue=6.11|url=http://www.wired.com/wired/archive/6.11/coldfusion.html?pg= |
*{{citation|last=Platt|first=Charles|title=What If Cold Fusion Is Real?|journal=Wired Magazine|year=1989|issue=6.11|url=http://www.wired.com/wired/archive/6.11/coldfusion.html?pg=1&topic=&topic_set= | accessdate = 2008-05-25}} | ||
*{{citation|last=Pollack|first=A.|title=Japan, Long a Holdout, Is Ending Its Quest for Cold Fusion|periodical=New York Times|issue=August 26, 1997|year=1997|page=C4}}. | *{{citation|last=Pollack|first=A.|title=Japan, Long a Holdout, Is Ending Its Quest for Cold Fusion|periodical=New York Times|issue=August 26, 1997|year=1997|page=C4}}. | ||
*{{citation|last=Prow|first=Tina M.|title=George Miley: Harnessing fusion as an energy source|journal=Engineering Outlook|volume=41|issue=2|year=2001|url=http://www.engr.uiuc.edu/publications/outlook/Text,%2041-2/miley.htm}} | *{{citation|last=Prow|first=Tina M.|title=George Miley: Harnessing fusion as an energy source|journal=Engineering Outlook|volume=41|issue=2|year=2001|url=http://www.engr.uiuc.edu/publications/outlook/Text,%2041-2/miley.htm| accessdate = 2008-05-25}} | ||
*{{citation|editor-last=Rusbringer|editor-first=Alan|title=In from the cold|journal=The Guardian|year=2005|issue=March 24, 2005|url=http://education.guardian.co.uk/higher/research/story/0,9865,1444306,00.html}} | *{{citation|editor-last=Rusbringer|editor-first=Alan|title=In from the cold|journal=The Guardian|year=2005|issue=March 24, 2005|url=http://education.guardian.co.uk/higher/research/story/0,9865,1444306,00.html| accessdate = 2008-05-25}} | ||
*{{citation|last=Schwinger|first=Julian|authorlink=Julian Schwinger|chapter=Cold fusion—Does it have a future?|title=Evolutionary Trends in the Physical Sciences: Proceedings of the Yoshio Nishina Centennial Symposium, Tokyo, Japan, December 5-7, 1990|editor-last=Suzuki|editor-first=Masuo|editor2-last=Kubo|editor2-first=Ryogo|series=Springer Proceedings in Physics, vol. 57|location=Berlin|publisher=Springer Verlag|year=1991|pages= |
*{{citation|last=Schwinger|first=Julian|authorlink=Julian Schwinger|chapter=Cold fusion—Does it have a future?|title=Evolutionary Trends in the Physical Sciences: Proceedings of the Yoshio Nishina Centennial Symposium, Tokyo, Japan, December 5-7, 1990|editor-last=Suzuki|editor-first=Masuo|editor2-last=Kubo|editor2-first=Ryogo|series=Springer Proceedings in Physics, vol. 57|location=Berlin|publisher=Springer Verlag|year=1991|pages=171–175|isbn=3-540-54568-9}}. <!-- repr. (1994) ''Cold Fusion'' '''1''' (1): 14-17. --> | ||
*{{citation|last=Shanahan|first=Kirk|title=A systematic error in mass flow calorimetry demonstrated|journal=Thermochimica Acta|volume=382|issue=2|year=2002|pages=95-101}}. | |||
*{{citation|last=Shanahan|first=Kirk|title=Comments on "Thermal behavior of polarized Pd/D electrodes prepared by co-deposition"|journal=Thermochimica Acta|volume=428|year=2005|pages=207-212}}. | |||
*{{citation|last=Shanahan|first=Kirk|title=Reply to “Comment on papers by K. Shanahan that propose to explain anomalous heat generated by cold fusion”, E. Storms, Thermochim. Acta, 2006|journal=Thermochimica Acta|volume=441|issue=2|year=2006|pages=210-214}}. | |||
*{{citation|ref=Shkedi1995|last=Shkedi|first=Zvi|first2=R.C.|last2=McDonald|first3=J.J.|last3=Breen|first4=S.J.|last4=Maguire|first5=J.|last5=Veranth | *{{citation|ref=Shkedi1995|last=Shkedi|first=Zvi|first2=R.C.|last2=McDonald|first3=J.J.|last3=Breen|first4=S.J.|last4=Maguire|first5=J.|last5=Veranth | ||
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*{{citation|ref=Shkedi1996|last=Shkedi|first=Zvi|title=Response to Comments on 'Calorimetry, Excess Heat, and Faraday Efficiency in Ni-H<sub>2</sub>O Electrolytic Cells'|journal=Fusion Technology|volume=30|issue=???|year=1996|page=133}}. <!-- only one page? --> | *{{citation|ref=Shkedi1996|last=Shkedi|first=Zvi|title=Response to Comments on 'Calorimetry, Excess Heat, and Faraday Efficiency in Ni-H<sub>2</sub>O Electrolytic Cells'|journal=Fusion Technology|volume=30|issue=???|year=1996|page=133}}. <!-- only one page? --> | ||
*{{citation|last=Srinivasan|first=M.|title=Energy concepts for the 21st century|url=http://www.ias.ac.in/currsci/apr102008/842.pdf| accessdate = 2008-07-19|journal=Current Science|volume=94|issue=7|year=2008|pages=842-843}} | |||
*{{citation|last=Storms|first=Edmund|title=Comment on papers by K. Shanahan that propose to explain anomalous heat generated by cold fusion|journal=Thermochimica Acta|volume=441|issue=2|year=2006|pages=207}}. | |||
*{{citation|last=Storms|first=Edmund|title=Science of Low Energy Nuclear Reaction: A Comprehensive Compilation of Evidence and Explanations|location=Singapore|publisher=World Scientific|year=2007|ISBN=9-8127062-0-8}}. | *{{citation|last=Storms|first=Edmund|title=Science of Low Energy Nuclear Reaction: A Comprehensive Compilation of Evidence and Explanations|location=Singapore|publisher=World Scientific|year=2007|ISBN=9-8127062-0-8}}. | ||
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*{{citation|last=Szpak|first=Stanislaw|last2=Mosier-Boss|first2=Pamela A.|last3=Young|first3=Charles|last4=Gordon|first4=Frank E.|title= Evidence of nuclear reactions in the Pd lattice|journal=Naturwissenschaften|volume=92|issue=8|year=2005|pages=394-397|doi=10.1007/s00114-005-0008-7}}. | *{{citation|last=Szpak|first=Stanislaw|last2=Mosier-Boss|first2=Pamela A.|last3=Young|first3=Charles|last4=Gordon|first4=Frank E.|title= Evidence of nuclear reactions in the Pd lattice|journal=Naturwissenschaften|volume=92|issue=8|year=2005|pages=394-397|doi=10.1007/s00114-005-0008-7}}. | ||
*{{citation|editor-last=Szpak|editor-first=Stanislaw|editor2-last=Mosier-Boss|editor2-first=Pamela A.|title= Thermal and nuclear aspects of the Pd/D2O system - Volume 1:A decade of research at Navy laboratories|series=Technical report 1862|year=2002a|url=http://www.spawar.navy.mil/sti/publications/pubs/tr/1862/tr1862-vol1.pdf|location=San Diego|publisher=Office of Naval Research/Space and Naval Warfare Systems Center}}. | *{{citation|editor-last=Szpak|editor-first=Stanislaw|editor2-last=Mosier-Boss|editor2-first=Pamela A.|title= Thermal and nuclear aspects of the Pd/D2O system - Volume 1:A decade of research at Navy laboratories|series=Technical report 1862|year=2002a|url=http://www.spawar.navy.mil/sti/publications/pubs/tr/1862/tr1862-vol1.pdf| accessdate = 2008-05-25|location=San Diego|publisher=Office of Naval Research/Space and Naval Warfare Systems Center}}. | ||
*{{citation|editor-last=Szpak|editor-first=Stanislaw|editor2-last=Mosier-Boss|editor2-first=Pamela A.|title= Thermal and nuclear aspects of the Pd/D2O system - Volume 2:Simulation of the electrochemical cell (ICARUS) calorimetry||series=Technical report 1862|year=2002b|url=http://www.spawar.navy.mil/sti/publications/pubs/tr/1862/tr1862-vol2.pdf|location=San Diego|publisher=Office of Naval Research/Space and Naval Warfare Systems Center}}. | *{{citation|editor-last=Szpak|editor-first=Stanislaw|editor2-last=Mosier-Boss|editor2-first=Pamela A.|title= Thermal and nuclear aspects of the Pd/D2O system - Volume 2:Simulation of the electrochemical cell (ICARUS) calorimetry||series=Technical report 1862|year=2002b|url=http://www.spawar.navy.mil/sti/publications/pubs/tr/1862/tr1862-vol2.pdf| accessdate = 2008-05-25|location=San Diego|publisher=Office of Naval Research/Space and Naval Warfare Systems Center}}. | ||
*{{citation|last=Tate|first=N.|title=MIT bombshell knocks fusion ‘breakthrough’ cold|periodical=Boston Herald|issue=May 1, 1989|year=1989|page=1}}. | *{{citation|last=Tate|first=N.|title=MIT bombshell knocks fusion ‘breakthrough’ cold|periodical=Boston Herald|issue=May 1, 1989|year=1989|page=1|url= }}. | ||
*{{citation|last=Taubes|first=Gary|authorlink=Gary Taubes|title=Bad Science: The Short Life and Weird Times of Cold Fusion|location=New York|publisher=Random House|year=1993|ISBN=0-394-58456-2}}. | *{{citation|last=Taubes|first=Gary|authorlink=Gary Taubes|title=Bad Science: The Short Life and Weird Times of Cold Fusion|location=New York|publisher=Random House|year=1993|ISBN=0-394-58456-2}}. | ||
*{{citation|author=U.S. Department of Energy|ref=DOE1989|title=A Report of the Energy Research Advisory Board to the United States Department of Energy|year=1989|publisher=US DOE|location=Washington|url=http://www.ncas.org/erab/}}. | *{{citation|author=U.S. Department of Energy|ref=DOE1989|title=A Report of the Energy Research Advisory Board to the United States Department of Energy|year=1989|publisher=US DOE|location=Washington|url=http://www.ncas.org/erab/| accessdate = 2008-05-25}}. | ||
*{{citation|author=U.S. Department of Energy|ref=DOE2004r|title=Report of the Review of Low Energy Nuclear Reactions |
*{{citation|author=U.S. Department of Energy|ref=DOE2004r|year=2004 | ||
|title=Report of the Review of Low Energy Nuclear Reactions | |||
|url=http://web.archive.org/web/20070114122346/http://www.science.doe.gov/Sub/Newsroom/News_Releases/DOE-SC/2004/low_energy/CF_Final_120104.pdf | |||
| accessdate = 2008-07-19|year=2004|location=Washington, DC|publisher=doe.gov}}. | |||
<!-- linked from http://www.science.doe.gov/Sub/Newsroom/News_Releases/DOE-SC/2004/low_energy/index.htm --> | |||
*{{citation|last=Van Noorden|first= R.|title=Cold fusion back on the menu|journal=Chemistry World|year=2007|issue=April 2007|url=http://www.rsc.org/chemistryworld/News/2007/March/22030701.asp}}. | *{{citation|last=Van Noorden|first= R.|title=Cold fusion back on the menu|journal=Chemistry World|year=2007|issue=April 2007|url=http://www.rsc.org/chemistryworld/News/2007/March/22030701.asp| accessdate = 2008-05-25}}. | ||
*{{citation|last= |
*{{citation|last=Voss|first=David|title=What Ever Happened to Cold Fusion|journal=Physics World|issue=March 1|year=1999|url=http://physicsworld.com/cws/article/print/1258| accessdate=2008-05-01}}. | ||
*{{citation|last=Will|first=F. G.|title=Hydrogen + oxygen recombination and related heat generation in undivided electrolysis cells|journal=Journal of Electroanalytical Chemistry|volume=426|issue=1|year=1997|pages=177–184}}. | |||
*{{citation|ref=Williams1989|last=Williams|first=D. E.|first2=D. J. S.|last2=Findlay|first3=D. H.|last3=Craston|first4=M. R.|last4=Sené|first5=M.|last5=Bailey|first6=S.|last6=Croft|first7=B. W.|last7=Hooton | *{{citation|ref=Williams1989|last=Williams|first=D. E.|first2=D. J. S.|last2=Findlay|first3=D. H.|last3=Craston|first4=M. R.|last4=Sené|first5=M.|last5=Bailey|first6=S.|last6=Croft|first7=B. W.|last7=Hooton | ||
|first8=C. P.|last8=Jones|first9=A. R. J.|last9=Kucernak|first10=J. A.|last10=Mason|first11=R. I.|last11=Taylor|title=Upper bounds on 'cold fusion' in electrolytic cells|journal=Nature|volume=342|pages=375-384|year=1989|doi=10.1038/342375a0}}. | |first8=C. P.|last8=Jones|first9=A. R. J.|last9=Kucernak|first10=J. A.|last10=Mason|first11=R. I.|last11=Taylor|title=Upper bounds on 'cold fusion' in electrolytic cells|journal=Nature|volume=342|pages=375-384|year=1989|doi=10.1038/342375a0}}. | ||
*{{citation|last=Wilson|first=R. H.|title=Analysis of experiments on the calorimetry of LiOD-D2O electrochemical cells|journal=Journal of Electroanalytical Chemistry|year=1992|volume=332|pages= |
*{{citation|last=Wilson|first=R. H.|title=Analysis of experiments on the calorimetry of LiOD-D2O electrochemical cells|journal=Journal of Electroanalytical Chemistry|year=1992|volume=332|pages=1–31}}. | ||
{{refend}} | {{refend}} | ||
==Further reading== | |||
{{refbegin}} | |||
* listed on <!-- New Energy Times is linked to from this wired article, giving it both reliability and notability: --> | |||
* <!-- this page is linked to from this wired article, giving it both reliability and notability: --> | |||
* : An extensive overview and review of almost all available publications on the subject of cold nuclear fusion. | |||
* LENR-CANR.org and | |||
{{refend}} | {{refend}} | ||
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Revision as of 12:45, 24 July 2008
Cold fusion, sometimes called low energy nuclear reactions (LENR) or condensed matter nuclear science, is a set of effects reported in controversial laboratory experiments at ordinary temperatures and pressures, which some researchers say is caused by nuclear reactions.
In 1989, Martin Fleischmann and Stanley Pons reported producing a tabletop nuclear fusion reaction at the University of Utah. In their press conferences and papers, they reported the observation of anomalous heating ("excess heat") of an electrolytic cell during electrolysis of heavy water using palladium (Pd) electrodes. Lacking an explanation for the source of such heat, they proposed the hypothesis that the heat came from nuclear fusion of deuterium (D). The report of their results raised hopes of a cheap and abundant source of energy.
Cold fusion gained a reputation as pathological science after other scientists failed to replicate the results. A review panel organized by the US Department of Energy (DOE) in 1989 did not find the evidence persuasive. Since then, other reports of anomalous heat production and anomalous Helium-4 production have been reported in peer-reviewed journals and have been discussed at scientific conferences. Most scientists have met these reports with skepticism. In 2004 the US DOE organized another review panel (US DOE 2004) which—like the one in 1989—did not recommend a focused federally-funded program for low energy nuclear reactions. The 2004 panel identified basic research areas that could be helpful in resolving some of the controversies in the field. It stated that the field would benefit from the peer-review processes associated with proposal submission to agencies and paper submission to archival academic journals.
Since 2004, two peer-reviewed literature reviews have concluded that cold fusion has been demonstrated by experiments that result in excess heat production and nuclear reaction products such as helium-4. The reviews stated that although many explanations have been proposed, several of which do not use new physics, none is yet satisfactory.
History
Early work
The special ability of palladium to absorb hydrogen was recognized as early as the nineteenth century by Thomas Graham. In the late nineteen-twenties, two German scientists, Friedrich Paneth and K. Peters, reported the transformation of hydrogen into helium by spontaneous nuclear catalysis when hydrogen was absorbed by finely divided palladium at room temperature. These authors later acknowledged that the helium they measured was due to background from the air.
In 1927, Swedish scientist J. Tandberg stated that he had fused hydrogen into helium in an electrolytic cell with palladium electrodes. On the basis of his work, he applied for a Swedish patent for "a method to produce helium and useful reaction energy". After deuterium was discovered in 1932, Tandberg continued his experiments with heavy water. Due to Paneth and Peters' retraction, Tandberg's patent application was eventually denied.
The term "cold fusion" was coined by Dr. Paul Palmer of Brigham Young University in 1986 in an investigation of "geo-fusion", or the possible existence of fusion in a planetary core.
Fleischmann-Pons announcement
Fleischmann said that he began investigating the possibility that chemical means could influence nuclear processes in the 1960s. He said that he explored whether collective effects, that would require quantum electrodynamics to calculate, might be more significant than the effects predicted by quantum mechanical calculations. He said that, by 1983, he had experimental evidence leading him to believe that condensed phase systems developed coherent structures up to 10m in size. In 1984, Fleischmann and Pons began cold fusion experiments.
In their original set-up, Fleischmann and Pons used a Dewar flask (a double-walled vacuum flask) for the electrolysis, so that heat conduction would be minimal on the side and the bottom of the cell (only 5 % of the heat loss in this experiment). The cell flask was then submerged in a bath maintained at constant temperature to eliminate the effect of external heat sources. They used an open cell, thus allowing the gaseous deuterium and oxygen resulting from the electrolysis reaction to leave the cell, along with some heat. It was necessary to replenish the cell with heavy water at regular intervals. The authors said that, since the cell was tall and narrow, the bubbling action of the gas kept the electrolyte well mixed and of a uniform temperature. Special attention was paid to the purity of the palladium cathode and electrolyte to prevent the build-up of material on its surface, especially after long periods of operation.
The cell was also instrumented with a thermistor to measure the temperature of the electrolyte, and an electrical heater to generate pulses of heat and calibrate the heat loss due to the gas outlet. After calibration, it was possible to compute the heat generated by the reaction.
A constant current was applied to the cell continuously for many weeks, and heavy water was added as necessary. For most of the time, the power input to the cell was equal to the power that went out of the cell within measuring accuracy, and the cell temperature was stable at around 30 °C. But then, at some point (and in some of the experiments), the temperature rose suddenly to about 50 °C without changes in the input power, for durations of 2 days or more. The generated power was calculated to be about 20 times the input power during the power bursts. Eventually the power bursts in any one cell would no longer occur and the cell was turned off.
In 1988, Fleischmann and Pons applied to the United States Department of Energy for funding towards a larger series of experiments. Up to this point they had been funding their experiments using a small device built with $100,000 out-of-pocket. The grant proposal was turned over for peer review, and one of the reviewers was Steven E. Jones of Brigham Young University. Jones had worked on muon-catalyzed fusion for some time, and had written an article on the topic entitled "Cold nuclear fusion" that had been published in Scientific American in July 1987. Fleischmann and Pons and co-workers met with Jones and co-workers on occasion in Utah to share research and techniques. During this time, Fleischmann and Pons described their experiments as generating considerable "excess energy", in the sense that it could not be explained by chemical reactions alone. They felt that such a discovery could bear significant commercial value and would be entitled to patent protection. Jones, however, was measuring neutron flux, which was not of commercial interest. In order to avoid problems in the future, the teams appeared to agree to simultaneously publish their results, although their accounts of their March 6 meeting differ.
In mid-March, both research teams were ready to publish their findings, and Fleischmann and Jones had agreed to meet at an airport on March 24 to send their papers to Nature via FedEx. Fleischmann and Pons, however, broke their apparent agreement, submitting their paper to the Journal of Electroanalytical Chemistry on March 11, and disclosing their work via a press conference on March 23. Jones, upset, faxed in his paper to Nature after the press conference.
Reaction to the announcement
The press initially reported on the experiments widely, and due to the surmised beneficial commercial applications of the Utah experiments, "scores of laboratories in the United States and abroad" attempted to repeat the experiments. The announcement raised hopes of a cheap and abundant source of energy.
On April 10, 1989, Fleischmann and Pons, who later suggested pressure from patent attorneys, published a rushed "preliminary note" in the Journal of Electroanalytical Chemistry. This paper notably contained a gamma peak without its corresponding Compton edge, a discrepancy that triggered accusations of fraud. Their "preliminary note" was followed up a year later in July 1990, when a much longer paper, going into details of calorimetry but without any nuclear measurements, was published in the same journal.
Also occurring on April 10, a team at Texas A&M University published their results of excess heat, followed up by a team at the Georgia Institute of Technology who observed production of neutrons. Both results were widely reported on in the press, although both Texas A&M and the Georgia Institute of Technology withdrew their results for lack of evidence. For the next six weeks, additional competing claims, counterclaims and suggested explanations kept what was referred to as "cold fusion" or "fusion confusion" in the news.
On April 12, Pons received a standing ovation from about 7,000 chemists at the semi-annual meeting of the American Chemical Society. The University of Utah asked Congress to provide $25 million to pursue the research, and Pons was scheduled to meet with representatives of President Bush in early May.
Then on May 1, the American Physical Society held a session on cold fusion, which included several reports of experiments that failed to produce evidence of cold fusion. A second session began the next day with other negative reports, and eight of the nine leading speakers stated that they considered the initial Utah claim dead. Dr. Steven E. Koonin of Caltech described the Utah report as a result of "the incompetence and delusion of Pons and Fleischmann." Dr. Douglas R. O. Morrison, a physicist representing CERN, called the entire episode an example of pathological science.Nature published papers critical of cold fusion in July and November.
1989 DOE panel
In November, a special panel formed by the Energy Research Advisory Board, under a charge of the United States Department of Energy, said that it was not possible to state categorically that cold fusion has been convincingly either proved or disproved. The experimental results of excess heat from calorimetric cells reported to them did not present convincing evidence that useful sources of energy will result from the phenomena attributed to cold fusion. These experiments did not present convincing evidence to associate the reported anomalous heat with a nuclear process. Current understanding of hydrogen in solids gives no support for the occurrence of cold fusion in solids. Nuclear fusion at room temperature, of the type discussed in this report, would be contrary to all understanding gained of nuclear reactions in the last half century; it would require the invention of an entirely new nuclear process.
The panel "recommended against the establishment of special programs or research centers to develop cold fusion", but was "sympathetic toward modest support for carefully focused and cooperative experiments within the present funding system." The Panel recommended that "the cold fusion research efforts in the area of heat production focus primarily on confirming or disproving reports of excess heat" and stated that "investigations designed to check the reported observations of excess tritium in electrolytic cells are desirable.".
Further developments (1989-2004)
The first published replication of excess heat was reported by Richard Oriani while he was professor of physical chemistry at the University of Minnesota, in December 1990. The results were published in his paper, "Calorimetric Measurements of Excess Power Output During the Cathodic Charging of Deuterium Into Palladium", in Fusion Technology.
In 1991, Dr. Eugene Mallove stated that the negative report issued by the MIT Plasma Fusion Center in 1989, which was highly influential in the controversy, was fraudulent because data was shifted without explanation, obscuring a possible positive excess heat result at MIT. In protest of MIT's failure to discuss and acknowledge the significance of this data shift, Mallove resigned from his post as chief science author at the MIT news office on June 7, 1991. He maintained that the data shift was biased to support the conventional belief in the non-existence of the cold fusion effect as well as to protect the financial interests of the plasma fusion center's research in hot fusion.
The late Nobel Laureate Julian Schwinger (1918 - 1994) also stated in 1991 that he had experienced "the pressure for conformity in editor's rejection of submitted papers, based on venomous criticism of anonymous reviewers," and that "the replacement of impartial reviewing by censorship will be the death of science." He resigned as Member and Fellow of the American Physical Society in protest of its peer review practice on cold fusion.
In 1992, workers at General Electric challenged the Fleischmann-Pons 1990 report in the Journal of Electroanalytical Chemistry, stating that the claims of excess heat had been overstated. The challenge concluded that the Fleischmann and Pons cell generated 40% excess heat, more than ten times larger than the initial error estimate. Despite the apparent confirmation, Fleischmann and Pons replied to General Electric and published a rebuttal in the same journal.
Fleischmann and Pons relocated their laboratory to France under a grant from the Toyota Motor Corporation. The laboratory, IMRA, was closed in 1998 after spending £12 million on cold fusion work. By comparison, research on the proven hot fusion reaction has run into the billions.
Eugene Mallove, a cold fusion proponent, contends that by 1991, 92 groups of researchers from 10 different countries had reported excess heat, tritium, helium4, neutrons or other nuclear effects. Proponents estimate that 3,000 cold fusion papers have been published, including over 1,000 journal papers and books, where the latter number includes both pro and con articles.
The generation of excess heat has been reported by (among others):
- Yoshiaki Arata, while he was professor at Osaka University, Japan,
- Robert A. Huggins, while he was professor at Stanford University (in March 1990),
- Michael McKubre, of SRI International,
- T. Mizuno (Hokkaido University, Japan),
- T. Ohmori (Japan),
- Richard A. Oriani, while he was professor at University of Minnesota (in December 1990),
- the late Giuliano Preparata, while he was at ENEA (Italy), and
- Edmund Storms, while he was at Los Alamos National Laboratory.
Many of these researchers continued their research in the phenomena after retirement.
Researchers share their results at the International Conference on Cold Fusion, recently renamed the International Conference on Condensed Matter Nuclear Science. The conference is held every 12 to 18 months in various countries around the world, and is hosted by The International Society for Condensed Matter Nuclear Science, a scientific organization that was founded as a professional society to support research efforts and to communicate experimental results. A few periodicals emerged in the 1990s that covered developments in cold fusion and related new energy sciences (Fusion Facts, Cold Fusion Magazine, Infinite Energy Magazine, and New Energy Times).
Between 1992 and 1997, Japan's Ministry of International Trade and Industry sponsored a "New Hydrogen Energy Program" of US$20 million to research cold fusion. Announcing the end of the program, Dr. Hideo Ikegami stated in 1997 "We couldn't achieve what was first claimed in terms of cold fusion." He added, "We can't find any reason to propose more money for the coming year or for the future."
In 1994, Dr. David Goodstein described cold fusion as "a pariah field, cast out by the scientific establishment. Between and respectable science there is virtually no communication at all. Cold fusion papers are almost never published in refereed scientific journals, with the result that those works don't receive the normal critical scrutiny that science requires. On the other hand, because the Cold-Fusioners see themselves as a community under siege, there is little internal criticism. Experiments and theories tend to be accepted at face value, for fear of providing even more fuel for external critics, if anyone outside the group was bothering to listen. In these circumstances, crackpots flourish, making matters worse for those who believe that there is serious science going on here."
Cold fusion researchers said that cold fusion was being suppressed, and that skeptics suffered from "pathological disbelief". They said that there was virtually no possibility for funding in cold fusion in the United States, and no possibility of getting published. They said that people in universities refused to work on it because they would be ridiculed by their colleagues.
In February 2002, a laboratory within the United States Navy released a report that came to the conclusion that the cold fusion phenomenon was in fact real and deserved an official funding source for research. Navy researchers say that, since 1990, they have published roughly 10 papers on cold fusion in respected peer-review journals.
2004 DOE panel
In 2004, the DOE organized another panel to take a look at cold fusion developments since 1989 to determine if their policies towards cold fusion should be altered.
It concluded: "While significant progress has been made in the sophistication of calorimeters since the review of this subject in 1989, the conclusions reached by the reviewers today are similar to those found in the 1989 review." "The nearly unanimous opinion of the reviewers in the 2004 review was that funding agencies should entertain individual, well-designed proposals for experiments that address specific scientific issues relevant to the question of whether or not there is anomalous energy production in Pd/D systems, or whether or not D-D fusion reactions occur at energies on the order of a few electron volts (eV). These proposals should meet accepted scientific standards and undergo the rigors of peer review. No reviewer recommended a focused federally funded program for low energy nuclear reactions." "The reviewers believed that this field would benefit from the peer-review processes associated with proposal submission to agencies and paper submission to archival journals."
Recent developments
The reports of excess heat and anomalous tritium production have met by most scientists with skepticism, although discussion in professional settings still continues. The American Chemical Society's (ACS) 2007 conference in Chicago held an "invited symposium" on cold fusion and low-energy nuclear reactions, and thirteen papers were presented at the "Cold Fusion" session of the 2006 American Physical Society (APS) March Meeting in Baltimore. Articles supporting cold fusion have been published in peer reviewed journals such as Naturwissenschaften, European Physical Journal A, European Physical Journal C, Journal of Solid State Phenomena, Journal of Electroanalytical Chemistry, Japanese Journal of Applied Physics, and Journal of Fusion Energy.
In 2008, the government of India reviewed the field. Dr. M. R. Srinivasan, former chairman of the Atomic Energy Commission of India said: "There is some science here that needs to be understood. We should set some people to investigate these experiments. There is much to be commended for the progress in the work. The neglect should come to an end". On May 22, 2008, Arata and Zhang publicly demonstrated what they say is a cold fusion reactor at Osaka University.
Summary of evidence for cold fusion
Cold fusion experiments have been conducted with many types of apparatus. The main constituents are:
- a metal, such as Palladium or Nickel, in bulk, thin films or powder;
- heavy or light water, hydrogen or deuterium gas or plasma;
- an excitation in the form of electricity or magnetism, of temperature or pressure cycle, of laser beam, or of acoustic waves.
Cold fusion has remained controversial, but several experimenters have reported excess heat, helium-4, low-level neutron production, X-ray emission, and/or transmutation of elements.
Excess heat
The excess power observed in some experiments is reported to be beyond that attributable to ordinary chemical or solid state sources; proponents attribute this excess power to nuclear fusion reactions.
The cold fusion researchers who presented their review document to the 2004 DOE panel said that "the hypothesis that the excess heat effect arises only as a consequence of errors in calorimetry was considered, studied, tested, and ultimately rejected". They said that numerous experiments conducted by SRI International showed excess power well above the accuracy of measurement. The researchers also said that the amount of energy reported in some of the experiments appeared to be too great compared to the small mass of the material in the cell for it to be stored by any chemical process. They said that their control experiments using light water did not show excess heat.
In 2007, a cold fusion proponent wrote a review by of experiments with a solid palladium cathode and an electrolyte with deuterium, or with D2 gas loaded in palladium powders. The author said that more than 10 groups worldwide have reported the measurement of excess heat in 1/3 of their experiments and that most of the research groups have reported occasionally seeing 50-200% excess heat for hours to days.
Nuclear products
The cold fusion researchers who presented their review document to the 2004 DOE panel on cold fusion said that there are insufficient chemical reaction products to account for the excess heat by several orders of magnitude. They said that several independent studies have shown that the rate of helium production measured in the gas stream varies linearly with excess power. Bursts of excess energy were time-correlated with bursts of He in the gas stream. Extensive precautions were taken to ensure that the samples were not contaminated by helium from the earth's atmosphere (5.2 ppm). They say that "numerous investigators" have reported that He was produced at levels above that of the concentration in air. However, the amount of helium in the gas stream was about half of what would be expected for a heat source of the type D + D -> He. Searches for neutrons and other energetic emissions commensurate with excess heat have uniformly produced null results.
In 2007, the Space and Naval Warfare Systems Center San Diego reported their observation of pits in CR-39 detectors during D/Pd codeposition experiments in the European Physical Journal. They said that those pits have features consistent with those observed for nuclear-generated tracks, that the Pd cathode is the source of those pits, and that they are not due to contamination or chemical reactions. They attributed some pits to knock-ons due to neutrons, and said that other pits are consistent with those obtained for alpha particles.
Nuclear transmutations
In nuclear reactions, a chemical element may be transmuted into another. There are numerous reports of nuclear transmutations and isotope anomalies in cold fusion experiments. Cold fusion proponents say that it is generally accepted that these anomalies are not the ash associated with the primary excess heat effect.
Tadahiko Mizuno was among the first to contribute a paper and a book on the subject. Dr. Miley, who also developed a process for making small inertial electrostatic confinement devices to serve as portable fusion neutron sources, wrote a review of these experiments. Some report the creation of only a few elements, while others report a wide variety of elements from the periodic table. Calcium, copper, zinc, and iron were the most commonly reported elements, often with non-natural isotopic ratios.
Iwamura and associates published what they say to be further evidence of transmutations in the Japanese Journal of Applied Physics in 2002. Instead of using electrolysis, they forced deuterium gas to permeate through a thin layer of caesium or strontium deposited on calcium oxide and palladium, while periodically analyzing the nature of the surface through X-ray photoelectron spectroscopy. They said that as the deuterium gas permeated over a period of a week, cesium appeared to be progressively transmuted into praseodymium while strontium appeared to be transmuted into molybdenum with anomalous isotopic composition representing an addition of four deuterium nuclei to the original nuclide. When the deuterium gas was replaced by hydrogen in control experiments, no transmutation was reported to be observed. The authors said that they analyzed, and then rejected, the possibility of explaining these various observations by contaminations or migration of impurities from the palladium interior.
Criticism
The skepticism towards cold fusion results from four issues: the precision of calorimetry, the lack of consistently reproducible results, the absence of nuclear products in quantities consistent with the excess heat, and the lack of a mainstream theoretical mechanism.
Precision of calorimetry
Main article: Calorimetry in cold fusion experimentsThe efficacy of the stirring method in the Fleischmann-Pons experiment, and thus the validity of the temperature measurements has been disputed by Browne. The experiment has also been criticized by Wilson. Other experiments using open cells have been criticized by Shkedi and Jones. Other experiments using mass flow calorimetry have been criticized by Shanahan.
Cold fusion researchers find these critique unconvincing, and not applicable to other experimental design.
The 2004 DOE panel noted that significant progress has been made in the sophistication of calorimeters since 1989. Evaluations by the reviewers ranged from: 1) evidence for excess power is compelling, to 2) there is no convincing evidence that excess power is produced when integrated over the life of an experiment. The reviewers were split approximately evenly on this topic.
Many of the reviewers noted that poor experiment design, documentation, background control and other similar issues hampered the understanding and interpretation of the results presented to the DOE panel. The reviewers who did not find the production of excess power convincing said that excess power in the short term is not the same as net energy production over the entire time of an experiment, that such short-term excess power is only a few percent of the total external power applied and hence calibration and systematic effects could account for the purported effect, that all possible chemical and solid state causes of excess heat had not been investigated and eliminated as an explanation, that the magnitude of the effect had not increased after over a decade of work.
Lack of reproducibility of excess heat
The cold fusion researchers who presented their review document to the 2004 DOE panel on cold fusion said that the observation of excess heat has been reproduced, that it can be reproduced at will under the proper conditions, and that many of the reasons for failure to reproduce it have been discovered. Contrary to these assertions, most reviewers stated that the effects are not repeatable, the magnitude of the effect has not increased in over a decade of work, and that many of the reported experiments were not well documented.
In 1989, the DOE panel noted that "Even a single short but valid cold fusion period would be revolutionary. As a result, it is difficult convincingly to resolve all cold fusion claims since, for example, any good experiment that fails to find cold fusion can be discounted as merely not working for unknown reasons."
Missing nuclear products
The fusion of two deuterium nuclei usually produces either a tritium nucleus and a proton, or a helium-3 (He) nucleus and a neutron. The level of neutrons, tritium and He actually observed in the Fleischmann-Pons experiments have been well below the level expected in view of the heat generated, implying that these fusion reactions cannot explain it. If the excess heat were generated by the fusion of two deuterium nuclei into helium (He), a reaction which is normally extremely rare, gamma rays and helium (alpha particles) would be expected. In 1989, insufficient levels of helium (alpha particles) and gamma rays were observed to explain the excess heat.
When asked about evidence of low energy nuclear reactions, twelve of the eighteen members of the 2004 DOE panel did not feel that there was any conclusive evidence, five found the evidence "somewhat convincing", and one was entirely convinced. The evidence of D+D fusion was taken as convincing or somewhat convincing by some reviewers; for others the lack of consistency was an indication that the overall hypothesis was not justified. Contamination of apparatus or samples by air containing He was cited as one possible cause for false positive results in some measurements.
Lack of theoretical explanations
Temperatures and pressures similar to those in stars are required for conventional nuclear fusion. The 1989 DOE panel said that such "nuclear fusion at room temperature would be contrary to all understanding gained of nuclear reactions in the last half century" and "it would require the invention of an entirely new nuclear process." but it also recognized that "the failure of a theory to account for cold fusion can be discounted on the grounds that the correct explanation and theory has not been provided", that is, the lack of a satisfactory explanation could not be used to dismiss experimental evidence.
Cold fusion observations are contrary to the conventional physics of nuclear fusion in several ways :
- The average density of deuterium atoms in the palladium rod seems vastly insufficient to force pairs of nuclei close enough for fusion to occur according to mechanisms known to mainstream theories. The average distance is approximately 0.17 nanometers, a distance at which the attractive strong nuclear force cannot overcome the Coulomb repulsion. Deuterium atoms are closer together in D2 gas molecules, which do not exhibit fusion.
- There is no known mechanism that would release fusion energy as heat instead of radiation within the relatively small metal lattice. The direct conversion of fusion energy into heat is not possible because of energy and momentum conservation and the laws of special relativity.
- Transmutations introduce additional discrepancies between observations and conventional theory because of the increased Coulomb barrier.
Cold fusion researchers acknowledge these issues and have proposed various speculative theories (for a full review, see Storms 2007) to explain the reported observations, but none has received mainstream acceptance.
Notes
- α. References to publications are listed in Storms 2007, pp. 52–61, 79–81 and in Hagelstein et al. 2004, pp. 25–29, to include Arata & Zhang 1998, Iwamura, Sakano & Itoh 2002, Mizuno et al. 2000, Miles et al. 1993 and Bush et al. 1991 harvnb error: no target: CITEREFBushLangowskiMilesOstrom1991 (help). Electrochemist Dr. Dieter Britz, who has remained neutral on the question of whether cold fusion exists, has compiled a list of 1385 papers published in scientific journals which includes numerous published scientific journal articles marked "res+", indicating positive research results or supportive theoretical calculations.
References
- ^ Fleischmann & Pons 1989, p. 301.
- ^ Browne 1989, para. 1.
- ^ Browne 1989, para. 29.
- Van Noorden 2007, para. 2.
- Chubb et al. 2006.
- Feder 2005,Hutchinson 2006,Kruglinksi 2006
- ^ Hubler 2007.
- ^ Biberian 2007.
- ^ US DOE 1989, p. 7.
- Kowalski 2004, II.A2.
- Fleischmann 2003, p. 1.
- ^ Fleischmann 2003, p. 3.
- Leggett 1989.
- Lewenstein 1994 p. 21.
- ^ Crease & Samios 1989, p. V1.
- ^ Fleischmann et al. 1990, p. 293
- ^ Lewenstein 1994, p. 8
- Browne 1989, para. 13.
- Tate 1989, p. 1.
- Platt 1989.
- ^ Broad 1989.
- Bowen 1989.
- Browne 1989, para. 8.
- ^ Browne 1989
- Gai et al. 1989, pp. 29–34.
- Williams et a. 1989, pp. 375–384.
- ^ US DOE 1989, p. 36 Cite error: The named reference "DOE_1989_36" was defined multiple times with different content (see the help page).
- ^ US DOE 1989, p. 37.
- Oriani et al. 1990, pp. 652–662, cited by Krivit 2005..
- Mallove 1999.
- Schwinger 1991.
- Wilson 1992, p. 1, cited by Krivit 2005.
- Beaudette 2002, pp. 188, 357–360.
- Voss 1999.
- Mallove 1991, p. 246-248.
- Anderson 2007
- Pollack 1997, p. C4.
- Goodstein 1994.
- Josephson 2004.
- Feder 2004, p. 27.
- Rusbringer 2005
- Szpak & Mosier-Boss 2002a
- Szpak & Mosier-Boss 2002b
- Szpak & Mosier-Boss 2002a, p. iv-v
- Szpak & Mosier-Boss 2002a, p. 113
- ^ US DOE 2004, p. 3.
- US DOE 2004, p. 5.
- Feder 2005
- Van Noorden 2007, para. 2.
- Chubb et al. 2006.
- cited by Krivit, Steven, "Selected Papers - Low Energy Nuclear Reactions,"
- Jayaraman 2008
- Srinivasan 2008
- Cartwright 2008
- Cartwright 2008b
- Storms 2007, p. 144-150
- Hagelstein et al. 2004, p. 1.
- Hagelstein et al. 2004, p. 22.
- Mosier-Boss, Szpak & Gordon 2007, slide 7
reported in Krivit 2007, p. 2. - ^ Hagelstein et al. 2004, p. 7.
- Hagelstein et al. 2004, p. 10.
- Mosier-Boss et al. 2007.
- Storms 2007, p. 93-95.
- Mizuno 1996
- Mizuno 1998, cited by Britz 2008
- Prow 2001.
- Miley & Shrestha 2003
- Miley & Shrestha 2003.
- Iwamura, Sakano & Itoh 2002, pp. 4642–4650.
- Iwamura, Sakano & Itoh 2002, p. 4648-4649.
- US DOE 1989, pp. 6–8.
- Browne 1989, para. 16.
- Wilson 1992
- Shkedi et al. 1995.
- Jones et al. 1995, p. 1.
- Shanahan 2002
- Shanahan 2005.
- Shanahan 2006
- Fleischmann 1992
- Will 1997, p. 177.
- Storms 2007, p. 195.
- Storms 2006.
- Hagelstein et al. 2004, p. 14.
- US DOE 2004, p. 3.
- US DOE 1989, pp. 5–6.
- US DOE 2004, p. 3-4.
- US DOE 1989, pp. 6–7.
- Goodstein 1994, p. 528.
- Kee 1999, p. 5.
Bibliography
- Anderson, Mark (2007), "Cold-Fusion Graybeards Keep the Research Coming", Wired Magazine, 2007 (8), retrieved 2008-05-25
- Arata, Yoshiaki; Zhang, Yue-Chang (1998), "Anomalous difference between reaction energies generated within D20-cell and H20 Cell", Japanese Journal of Applied Physics, 37 (11A): L1274 – L1276.
- Beaudette, Charles G. (2002), Excess Heat & Why Cold Fusion Research Prevailed, New York: Oak Grove Press, ISBN 9-9678548-2-2
{{citation}}
: Check|isbn=
value: checksum (help)
- Biberian, Jean-Paul (2007), "Condensed Matter Nuclear Science (Cold Fusion): An Update" (PDF), International Journal of Nuclear Energy Science and Technology, 3 (1): 31–43, doi:10.1504/IJNEST.2007.012439.
- Bowen, Jerry (1989), "Science: Nuclear Fusion", CBS Evening News, no. April 10, 1989, retrieved 2008-05-25.
- Broad, William J. (April 14, 1989), "Georgia Tech Team Reports Flaw In Critical Experiment on Fusion", New York Times, retrieved 2008-05-25
{{citation}}
: CS1 maint: date and year (link).
- Britz, Dieter (2008), "Book review:The Science of Low Energy Nuclear Reaction", J. Sci. Exploration, 21, #4: 801.
- Browne, M. (May 3, 1989), "Physicists Debunk Claim Of a New Kind of Fusion", New York Times, retrieved 2008-05-25
{{citation}}
: CS1 maint: date and year (link).
- Bush, Ben F.; Ostrom, Greg S. (1991), "Helium Production During the Electrolysis of D2O in Cold Fusion", Journal of Electroanalytical Chemistry, 304: 271–278.
- Bush, R. T.; Eagleton, R.D. (1994), "Evidence of electrolytically induced transmutation and radioactivity correlated with excess heat in Electrolytic cells with light water rubidium salt electrolytes", Transactions of Fusion Technology, 26 (4T).
- Cartwright, Jon (2008), Cold-fusion demonstration "a success", PhysicsWorld.com, retrieved 2008-05-25
- Cartwright, Jon (2008b), Cold-fusion demonstration: an update, PhysicsWorld.com, retrieved 2008-06-23
- Chubb, Scott; et al. (2006), Session W41: Cold Fusion, American Physical Society, retrieved 2008-05-25
{{citation}}
: Explicit use of et al. in:|first=
(help).
- Close, Frank E. (1991), Too Hot to Handle: The Race for Cold Fusion, Princeton, N.J.: Princeton University Press, ISBN 0-691-08591-9.
- Crease, Robert; Samios, N. P. (1989), "Cold Fusion confusion", New York Times Magazine (September 24, 1989): 34-38
{{citation}}
:|access-date=
requires|url=
(help)
- Feder, Toni (2004), "DOE Warms to Cold Fusion", Physics Today, 57 (4): 27–28, retrieved 2008-05-25
- Feder, Toni (2005), "Cold Fusion Gets Chilly Encore", Physics Today, retrieved 2008-05-25
- Fleischmann, Martin; Pons, Stanley (1989), "Electrochemically induced nuclear fusion of deuterium", Journal of Electroanalytical Chemistry, 261 (2A): 301–308.
- Fleischmann, Martin; Pons, Stanley; Anderson, Mark W.; Li, Lian Jun; Hawkins, Marvin (1990), "Calorimetry of the palladium-deuterium-heavy water system", Journal of Electroanalytical Chemistry, 287: 293–348
- Fleischmann, Martin; Pons, Stanley (1992), "Some Comments on The Paper 'Analysis of Experiments on The Calorimetry of Liod-D2O Electrochemical Cells,' R.H. Wilson et al., Journal of Electroanalytical Chemistry, Vol. 332, (1992)"", Journal of Electroanalytical Chemistry, 332: 33
- Fleischmann, Martin (2003), "Background to cold fusion: the genesis of a concept", Tenth International Conference on Cold Fusion, Cambridge, MA: World Scientific Publishing, ISBN 978-9812565648
- Gai, M.; Rugari, S. L.; France, R. H.; Lund, B. J.; Zhao, Z.; Davenport, A. J.; Isaacs, H. S.; Lynn, K. G. (1989), "Upper limits on neutron and big gamma-ray emission from cold fusion", Nature, 340: 29–34, doi:10.1038/340029a0
- Goodstein, David (1994), "Whatever happened to cold fusion?", The American Scholar, 63 (4): 527–541, retrieved 2008-05-25.
- Hagelstein, Peter; Michael, McKubre; Nagel, David; Chubb, Talbot; Hekman, Randall (2004), New Physical Effects in Metal Deuterides (PDF), Washington: USDOE, retrieved 2008-07-19
- Higashiyama, Taichi; Sakano, Mitsuru; Miyamaru, Hiroyuki; Takahashi, Akito (2003), "Replication of MHI Transmutation Experiment by D2 Gas Permeation Through Pd Complex", Tenth International Conference on Cold Fusion, Cambridge, MA: publisher=World Scientific Publishing Company, ISBN 978-9812565648
{{citation}}
: Missing pipe in:|publisher=
(help)
- Hubler, G. K. (2007), "Anomalous Effects in Hydrogen-Charged Palladium - A Review", Surface and Coatings Technology, 201 (19–20): 8568–8573, doi:10.1016/j.surfcoat.2006.03.062
- Huizenga, John R. (1992), Cold Fusion: The Scientific Fiasco of the Century, Rochester, N.Y.: University of Rochester Press, ISBN 1-878822-07-1.
- Hutchinson, Alex (2006), "The Year in Science: Physics", Discover Magazine, retrieved 2008-06-20
- Iwamura, Yasuhiro; Sakano, Mitsuru; Itoh, Takehiko (2002), "Elemental Analysis of Pd Complexes: Effects of D2 Gas Permeation", Japanese Journal of Applied Physics, 41 (7A): 4642–4650, doi:10.1143/JJAP.41.4642.
- Iwamura, Yasuhiro (2004), "Observation of Nuclear Transmutation Reactions induced by D2 Gas Permeation through Pd Complexes", Eleventh International Conference on Condensed Matter Nuclear Science, Marseille, France: World Scientific Publishing Company, ISBN 978-9812566409
- Jayaraman, K. S. (Jan 17, 2008), "Cold fusion hot again", Nature India, doi:10.1038/nindia.2008.77, retrieved 2008-05-25
{{citation}}
: CS1 maint: date and year (link)
- Jones, J. E.; Hansen, L. D.; Jones, S. E.; Shelton, D. S.; Thorne, J. M. (1995), "Faradaic efficiencies less than 100% during electrolysis of water can account for reports of excess heat in`cold fusion` cells", Journal of Physical Chemistry, 99 (18): 6973–6979
- Josephson, Brian. D. (2004), Pathological Disbelief (PDF), Lecture given at the Nobel Laureates’ meeting Lindau, June 30th., 2004, retrieved 2008-07-17
{{citation}}
: Unknown parameter|auhtorlink=
ignored (help).
- Kee, B (October 21, 1999), "What is the current scientific thinking on cold fusion? Is there any possible validity to this phenomenon?", Scientific American, Ask the Experts, retrieved 2008-05-25
{{citation}}
: CS1 maint: date and year (link).
- Kim, Y. E.; Yoon, J.-H.; Rice, R. A.; Rabinowitz, Mario (1992), "Cluster-Impact Fusion and Effective Deuteron Temperature", Physical Review Letters, 68 (3): 373–376.
- Kozima, Hideo (2006), The Science of the Cold Fusion phenomenon, New York: Elsevier Science, ISBN 0-08-045110-1.
- Krivit, Steven B. (2005), "The Seminal Papers of Cold Fusion", New Energy Times, retrieved 2008-05-25.
- Krivit, Steven B. (2007), "Extraordinary Courage: Report on Some LENR Presentations at the 2007 American Physical Society Meeting", New Energy Times (21), retrieved 2008-05-25.
- Krivit, Steven B. (2008), "Low Energy Nuclear Reaction Research – Global Scenario" (PDF), Current Science, 94 (7): 854–857, retrieved 2008-07-19.
- Kruglinksi, Susan (2006), "Whatever Happened To... Cold Fusion?", Discover Magazine, retrieved 2008-06-20
- Kowalski, Ludwik (2004), Jones’s manuscript on History of Cold Fusion at BYU, Upper Montclair, NJ: csam.montclair.edu, retrieved 2008-05-25
- Leggett, A.J. (1989), "Exact upper bound on barrier penetration probabilities in many-body systems: Application to cold fusion", Phys. Rev. Lett. (63): 191–194.
- Lewenstein, Bruce V. (1994), Cornell cold fusion archive (PDF), collection n°4451, Division of Rare and Manuscript Collections, Cornell University Library, retrieved 2008-05-25
{{citation}}
: CS1 maint: location (link) CS1 maint: location missing publisher (link)
- Mallove, Eugene (1991), Fire from Ice: Searching for the Truth Behind the Cold Fusion Furor, London: Wiley, ISBN 0-471-53139-1.
- Mallove, Eugene (1999), "MIT and Cold Fusion: A Special Report" (PDF), Infinite Energy Magazine, 24, retrieved 2008-05-25
- Miles, Melvin H.; Hollins, R. A.; Bush, Ben F.; Logowski, J. J.; Miles, R. E. (1993), "Correlation of excess power and helium production during D2O and H20 electrolysis using Palladium cathodes", Journal of Electroanalytical Chemistry, 346 (1–2): 99–117.
- Miley, George H.; Shrestha, P. (2003), "Review Of Transmutation Reactions In Solids", Proceedings of the Tenth International Conference on Cold Fusion, Cambridge, MA: World Scientific Publishing Company, ISBN 978-9812565648
- Mizuno, Tadahiko (1996), "Analysis of Elements for Solid State Electrolyte in Deuterium Atmosphere during Applied Field", J. New Energy (1(2)): 37.
- Mizuno, Tadahiko (1998), Nuclear Transmutation: The Reality of Cold Fusion, Concord, NH: Infinite Energy Press
{{citation}}
: CS1 maint: location missing publisher (link).
- Mizuno, Tadahiko; Ohmori, Tadayoshi; Akimoto, Tadashi; Takahashi, Akito (2000), "Production of Heat During Plasma Electrolysis in Liquid", Japanese Journal of Applied Physics, 39 (10): 6055–6061.
- Mosier-Boss, Pamela A.; Szpak, Stanislaw; Gordon, Frank E. (2007), "Production of High Energy Particles Using the Pd/D Co-Deposition Process", Proceedings of the 2007 APS March Meeting, March 5–9, 2007 in Denver, College Park, MD: American Physical Society, retrieved 2008-05-25. *slides* retrieved on May 25, 2008
- Mosier-Boss, Pamela A.; Szpak, Stanislaw; Gordon, Frank E.; Forsley, L. P. G. (2007), "Use of CR-39 in Pd/D co-deposition experiments", European Physical Journal Applied Physics (40): 293–303, doi:10.1051/epjap:2007152
- Oriani, Richard A.; Nelson, John C.; Lee, Sung-Kyu; Broadhurst, J. H. (1990), Fusion Technology, vol. 18, pp. 652–662.
- Park, Robert (2000), Voodoo Science: The Road from Foolishness to Fraud, New York: Oxford University Press, ISBN 0-19-513515-6.
- Platt, Charles (1989), "What If Cold Fusion Is Real?", Wired Magazine (6.11), retrieved 2008-05-25
- Pollack, A. (1997), "Japan, Long a Holdout, Is Ending Its Quest for Cold Fusion", New York Times, no. August 26, 1997, p. C4.
- Prow, Tina M. (2001), "George Miley: Harnessing fusion as an energy source", Engineering Outlook, 41 (2), retrieved 2008-05-25
- Rusbringer, Alan, ed. (2005), "In from the cold", The Guardian (March 24, 2005), retrieved 2008-05-25
- Schwinger, Julian (1991), "Cold fusion—Does it have a future?", in Suzuki, Masuo; Kubo, Ryogo (eds.), Evolutionary Trends in the Physical Sciences: Proceedings of the Yoshio Nishina Centennial Symposium, Tokyo, Japan, December 5-7, 1990, Springer Proceedings in Physics, vol. 57, Berlin: Springer Verlag, pp. 171–175, ISBN 3-540-54568-9.
- Shanahan, Kirk (2002), "A systematic error in mass flow calorimetry demonstrated", Thermochimica Acta, 382 (2): 95–101.
- Shanahan, Kirk (2005), "Comments on "Thermal behavior of polarized Pd/D electrodes prepared by co-deposition"", Thermochimica Acta, 428: 207–212.
- Shanahan, Kirk (2006), "Reply to "Comment on papers by K. Shanahan that propose to explain anomalous heat generated by cold fusion", E. Storms, Thermochim. Acta, 2006", Thermochimica Acta, 441 (2): 210–214.
- Shkedi, Zvi; McDonald, R.C.; Breen, J.J.; Maguire, S.J.; Veranth, J. (1995), "Calorimetry, Excess Heat, and Faraday Efficiency in Ni-H2O Electrolytic Cells.", Fusion Technology, 28 (4): 1720–1731.
- Shkedi, Zvi (1996), "Response to Comments on 'Calorimetry, Excess Heat, and Faraday Efficiency in Ni-H2O Electrolytic Cells'", Fusion Technology, 30 (???): 133.
- Srinivasan, M. (2008), "Energy concepts for the 21st century" (PDF), Current Science, 94 (7): 842–843, retrieved 2008-07-19
- Storms, Edmund (2006), "Comment on papers by K. Shanahan that propose to explain anomalous heat generated by cold fusion", Thermochimica Acta, 441 (2): 207.
- Storms, Edmund (2007), Science of Low Energy Nuclear Reaction: A Comprehensive Compilation of Evidence and Explanations, Singapore: World Scientific, ISBN 9-8127062-0-8.
- Szpak, Stanislaw; Mosier-Boss, Pamela A.; Young, Charles; Gordon, Frank E. (2005), "Evidence of nuclear reactions in the Pd lattice", Naturwissenschaften, 92 (8): 394–397, doi:10.1007/s00114-005-0008-7.
- Szpak, Stanislaw; Mosier-Boss, Pamela A., eds. (2002a), Thermal and nuclear aspects of the Pd/D2O system - Volume 1:A decade of research at Navy laboratories (PDF), Technical report 1862, San Diego: Office of Naval Research/Space and Naval Warfare Systems Center, retrieved 2008-05-25.
- Szpak, Stanislaw; Mosier-Boss, Pamela A., eds. (2002b), Thermal and nuclear aspects of the Pd/D2O system - Volume 2:Simulation of the electrochemical cell (ICARUS) calorimetry (PDF), Technical report 1862, San Diego: Office of Naval Research/Space and Naval Warfare Systems Center, retrieved 2008-05-25
{{citation}}
: Cite has empty unknown parameter:|1=
(help).
- Tate, N. (1989), "MIT bombshell knocks fusion 'breakthrough' cold", Boston Herald, no. May 1, 1989, p. 1.
- Taubes, Gary (1993), Bad Science: The Short Life and Weird Times of Cold Fusion, New York: Random House, ISBN 0-394-58456-2.
- U.S. Department of Energy (1989), A Report of the Energy Research Advisory Board to the United States Department of Energy, Washington: US DOE, retrieved 2008-05-25.
- U.S. Department of Energy (2004), Report of the Review of Low Energy Nuclear Reactions (PDF), Washington, DC: doe.gov, retrieved 2008-07-19.
- Van Noorden, R. (2007), "Cold fusion back on the menu", Chemistry World (April 2007), retrieved 2008-05-25.
- Voss, David (1999), "What Ever Happened to Cold Fusion", Physics World (March 1), retrieved 2008-05-01.
- Will, F. G. (1997), "Hydrogen + oxygen recombination and related heat generation in undivided electrolysis cells", Journal of Electroanalytical Chemistry, 426 (1): 177–184.
- Williams, D. E.; Findlay, D. J. S.; Craston, D. H.; Sené, M. R.; Bailey, M.; Croft, S.; Hooton, B. W.; Jones, C. P.; Kucernak, A. R. J.; Mason, J. A.; Taylor, R. I. (1989), "Upper bounds on 'cold fusion' in electrolytic cells", Nature, 342: 375–384, doi:10.1038/342375a0.
- Wilson, R. H. (1992), "Analysis of experiments on the calorimetry of LiOD-D2O electrochemical cells", Journal of Electroanalytical Chemistry, 332: 1–31.