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| {{Short description|Phyllosilicate mineral in the mica family}} | |||
| '''Annite''' is a ] mineral in the ] family. It has a chemical formula of KFe<sub>3</sub><sup>2+</sup></sup>AlSi<sub>3</sub>O<sub>10</sub>]. | |||
| <ref name=Mindat></ref> Annite is the ] end member of the ] mica group, the iron rich analogue of ] rich ].<ref>Deer, W. A., R. A. Howie and J. Zussman, ''An Introduction to the Rock Forming Minerals,'' Longman, 1966, p. 212 ISBN 0582442109</ref> | |||
| ⚫ | Annite was first described in 1868 for the first noted occurrence in ], ], ], |
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| {{FixBunching|beg}} | |||
| {{Infobox mineral | {{Infobox mineral | ||
| |name = Annite | | name = Annite | ||
| | category = ] <br />Mica group | |||
| |category = mica group, biotite-phlogopite series. The hydroxyll analogue of Flourannite. | |||
| | image = Annite-pas-130ab.jpg | |||
| ⚫ | |formula = KFe<sub>3</sub><sup>2+</sup> |
||
| | caption = Annite sample | |||
| ⚫ | |molecular weight = 512.88 g | ||
| ⚫ | | formula = KFe<sub>3</sub><sup>2+</sup>AlSi<sub>3</sub>O<sub>10</sub>(OH,F)<sub>2</sub> | ||
| ⚫ | |color = |
||
| |IMAsymbol=Ann<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | |||
| ⚫ | |habit = |
||
| ⚫ | <!--not a parameter | molecular weight = 512.88 g/mol --> | ||
| ⚫ | of one-layer phlogopite and annite. |
||
| | strunz = 9.EC.20 | |||
| |system = monoclinic, pseudohexagonal | |||
| | system = ] | |||
| ⚫ | |twinning = |
||
| | class = Prismatic (2/m) <br/><small>(same ])</small> | |||
| ⚫ | |cleavage = |
||
| | symmetry = ''C2/m'' | |||
| 55{84}. </ref> | |||
| | unit cell = a = 5.39, b = 9.33 <br/>c = 10.29 ; β = 100°; Z = 2 | |||
| ⚫ | |fracture = |
||
| ⚫ | | color = Brown to black | ||
| ⚫ | |tenacity = |
||
| ⚫ | | habit = Usually in "blocks" of thin sheets or as aggregations of foliated thin scales. Includes large, well formed pseudohexagonal prisms up to 12 cm across and 15 cm long.<ref>Hazen, R.M. and Burnham, C.W. (1973) The crystal structures | ||
| annite. J. Petrol., 3, 82{125.</ref> | |||
| ⚫ | of one-layer phlogopite and annite. American Mineralogist, 58, 889–900.</ref> | ||
| ⚫ | |mohs = 2. |
||
| ⚫ | | twinning = Contact twins with composition surface on {001} and twin axis {310} | ||
| ⚫ | |luster = |
||
| ⚫ | | cleavage = Perfect in one direction {001}<ref>Deer, W.A., Howie, R.A., and Zussman, J. (1963) Sheet Silicates. Rock-forming minerals Volume 3, 55–84.</ref> | ||
| |optical properties = translucent to transparent<ref>Kwak, T.A.P. and P.W. | |||
| ⚫ | | fracture = Uneven | ||
| ⚫ | Askins (1981) Geology and genesis of the F-Sn-W(-Be-Zn) skarn (wrigglite) at Moina, Tasmania. | ||
| ⚫ | | tenacity = Flexible<ref>Eugster, H.P. and Wones, D.R. (1962) Annite. Stability relations of the ferruginous biotite. 3, 82–125</ref> | ||
| Econ. Geol., 76, 439{467).</ref> | |||
| ⚫ | | mohs = 2.5–3 | ||
| ⚫ | |streak = |
||
| ⚫ | | luster = Submetallic to vitreous; pearly on cleavage surfaces<ref>Dana, E.S. (1892) Dana's system of mineralogy, (6th edition), 634.</ref> | ||
| |gravity = approximately 3.3 g/cm<sup>3</sup> | |||
| | opticalprop = Biaxial (−) | |||
| ⚫ | |density = |
||
| | refractive = n<sub>α</sub> = 1.625 – 1.631 n<sub>β</sub> = 1.690 n<sub>γ</sub> = 1.691 – 1.697 | |||
| ⚫ | |other = |
||
| | pleochroism = X = brown; Y = Z = dark brown | |||
| </references> | |||
| | 2V = Calculated: 12° to 36° | |||
| ⚫ | | streak = Brownish white | ||
| | gravity = Approximately 3.3 | |||
| ⚫ | | density = | ||
| ⚫ | | diaphaneity = Translucent to transparent<ref name=Kwak1981>Kwak, T.A.P. and Askins, P.W. (1981) Geology and genesis of the F-Sn-W(-Be-Zn) skarn (wrigglite) at Moina, Tasmania. Economical Geology, 76, 439–467</ref> | ||
| ⚫ | | other = Diagnostic: occurrence: in magnesium poor igneous and metamorphic rocks. | ||
| | references = <ref name=Mindat></ref><ref name=HBM></ref> | |||
| }} | }} | ||
| {{FixBunching|mid}} | |||
| {{FixBunching|end}} | |||
| '''Annite''' is a ] mineral in the ] family. It has a chemical formula of KFe<sub>3</sub><sup>2+</sup>AlSi<sub>3</sub>O<sub>10</sub>(OH)<sub>2</sub>.<ref name=HBM/> Annite is the ] end member of the ] mica group, the iron rich analogue of ] rich ].<ref>Deer, W. A., R. A. Howie and Zussman, J., ''An Introduction to the Rock Forming Minerals,'' Longman, 1966, p. 212 {{ISBN|0-582-44210-9}}</ref> Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines.<ref name=Kwak1981 /> There are contact ] with composition surface {001} and twin axis {310}.<ref>Anthony,J.W., Bideaux, R.A., Bladh, K.W., and Nichols, C.M. (1995), Handbook of Mineralogy, Volume II, Silica, Silicates Part 1, p. 31</ref> | |||
| ⚫ | Annite was first described in 1868 for the first noted occurrence in ], ], ], Massachusetts, US.<ref name=Mindat/> It also occurs on ], ], Colorado.<ref name=HBM/> It occurs in ] and ] that are deficient in magnesium and is associated with ] and ] in the ].<ref name=HBM/> | ||
| ==Properties== | |||
| The relief of a mineral refers to the way a mineral may stand out in plane polarized light. A mineral may be referred to as having a low or high relief. Minerals with a high relief, such as annite, have sharp grain boundaries and display good fracture and cleavage. When viewed under a microscope, this mineral may appear to stick out of the other minerals in the thin section. Relief primarily depends on the index of refraction of the mineral.<ref name=HBM/> The index of refraction of a mineral is a measure of the speed of light in the mineral. It is expressed as a ratio of the speed of light in vacuum relative to that in the given mineral. Annite has three indices of refraction known to be n<sub>α</sub> = 1.625 – 1.631 n<sub>β</sub> = 1.690 n<sub>γ</sub> = 1.691 – 1.697.<ref name=Mindat/> It is also an anisotropic mineral, meaning under the cross polars of a microscope the mineral will become extinct every 90°. However, in plane polarized light, annite appears as a brown or green platy form and is ], meaning the mineral changes colors under a microscope without the polars being crossed.<ref name=HBM/> | |||
| == Uses == | |||
| Annite is a member of the mica group and has very similar properties as other micas such as muscovite and biotite. More importantly, annite is interesting to geologists because it can be used for potassium-argon dating. Because annite contains large amounts of potassium, it can be used to find the absolute age of articles older than 1000 years. This type of dating also preserves a record of the direction and intensity of the local magnetic field, giving field geologists better knowledge of their surroundings.<ref>Eugster, H.P. and Wones, D.R.(1962) Stability relations of the ferruginous biotite, annite. 3, 82–125</ref> | |||
| ==References== | |||
| {{Reflist}}{{Phyllosilicates}} | |||
| ] | ] | ||
| ] | ] | ||
| ] | ] | ||
| ] | ] | ||
| ] | ] | ||
| ] | |||
| ] | |||
| {{silicate-mineral-stub}} | |||
Latest revision as of 03:19, 24 January 2024
Phyllosilicate mineral in the mica family| Annite | |
|---|---|
 Annite sample | |
| General | |
| Category | Phyllosilicates Mica group |
| Formula (repeating unit) | KFe3AlSi3O10(OH,F)2 |
| IMA symbol | Ann |
| Strunz classification | 9.EC.20 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | C2/m |
| Unit cell | a = 5.39, b = 9.33 c = 10.29 ; β = 100°; Z = 2 |
| Identification | |
| Color | Brown to black |
| Crystal habit | Usually in "blocks" of thin sheets or as aggregations of foliated thin scales. Includes large, well formed pseudohexagonal prisms up to 12 cm across and 15 cm long. |
| Twinning | Contact twins with composition surface on {001} and twin axis {310} |
| Cleavage | Perfect in one direction {001} |
| Fracture | Uneven |
| Tenacity | Flexible |
| Mohs scale hardness | 2.5–3 |
| Luster | Submetallic to vitreous; pearly on cleavage surfaces |
| Streak | Brownish white |
| Diaphaneity | Translucent to transparent |
| Specific gravity | Approximately 3.3 |
| Optical properties | Biaxial (−) |
| Refractive index | nα = 1.625 – 1.631 nβ = 1.690 nγ = 1.691 – 1.697 |
| Pleochroism | X = brown; Y = Z = dark brown |
| 2V angle | Calculated: 12° to 36° |
| Other characteristics | Diagnostic: occurrence: in magnesium poor igneous and metamorphic rocks. |
| References | |
Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe3AlSi3O10(OH)2. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines. There are contact twins with composition surface {001} and twin axis {310}.
Annite was first described in 1868 for the first noted occurrence in Cape Ann, Rockport, Essex County, Massachusetts, US. It also occurs on Pikes Peak, El Paso County, Colorado. It occurs in igneous and metamorphic rocks that are deficient in magnesium and is associated with fluorite and zircon in the type locality.
Properties
The relief of a mineral refers to the way a mineral may stand out in plane polarized light. A mineral may be referred to as having a low or high relief. Minerals with a high relief, such as annite, have sharp grain boundaries and display good fracture and cleavage. When viewed under a microscope, this mineral may appear to stick out of the other minerals in the thin section. Relief primarily depends on the index of refraction of the mineral. The index of refraction of a mineral is a measure of the speed of light in the mineral. It is expressed as a ratio of the speed of light in vacuum relative to that in the given mineral. Annite has three indices of refraction known to be nα = 1.625 – 1.631 nβ = 1.690 nγ = 1.691 – 1.697. It is also an anisotropic mineral, meaning under the cross polars of a microscope the mineral will become extinct every 90°. However, in plane polarized light, annite appears as a brown or green platy form and is pleochroic, meaning the mineral changes colors under a microscope without the polars being crossed.
Uses
Annite is a member of the mica group and has very similar properties as other micas such as muscovite and biotite. More importantly, annite is interesting to geologists because it can be used for potassium-argon dating. Because annite contains large amounts of potassium, it can be used to find the absolute age of articles older than 1000 years. This type of dating also preserves a record of the direction and intensity of the local magnetic field, giving field geologists better knowledge of their surroundings.
References
- Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- Hazen, R.M. and Burnham, C.W. (1973) The crystal structures of one-layer phlogopite and annite. American Mineralogist, 58, 889–900.
- Deer, W.A., Howie, R.A., and Zussman, J. (1963) Sheet Silicates. Rock-forming minerals Volume 3, 55–84.
- Eugster, H.P. and Wones, D.R. (1962) Annite. Stability relations of the ferruginous biotite. 3, 82–125
- Dana, E.S. (1892) Dana's system of mineralogy, (6th edition), 634.
- ^ Kwak, T.A.P. and Askins, P.W. (1981) Geology and genesis of the F-Sn-W(-Be-Zn) skarn (wrigglite) at Moina, Tasmania. Economical Geology, 76, 439–467
- ^ Mindat.org
- ^ Handbook of Mineralogy
- Deer, W. A., R. A. Howie and Zussman, J., An Introduction to the Rock Forming Minerals, Longman, 1966, p. 212 ISBN 0-582-44210-9
- Anthony,J.W., Bideaux, R.A., Bladh, K.W., and Nichols, C.M. (1995), Handbook of Mineralogy, Volume II, Silica, Silicates Part 1, p. 31
- Eugster, H.P. and Wones, D.R.(1962) Stability relations of the ferruginous biotite, annite. 3, 82–125
