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#REDIRECT ] |
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{{citations missing|physics|date=August 2009}} |
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{{infobox untriseptium}} |
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{{Redirect category shell|1= |
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'''Untriseptium''' ({{pron-en|ˌuːntraɪˈsɛptiəm}}) is a hypothetical ] which has not been observed to occur naturally, nor has it yet been synthesised. Due to ], it is not known if this element is physically possible. Its atomic number is 137 and symbol is Uts. |
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{{R with Wikidata item}} |
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{{R with possibilities}} |
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{{R from subtopic}} |
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{{R adr|Superactinides}} |
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{{R printworthy}} |
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}} |
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] |
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The name ''untriseptium'' is a temporary ] ]. |
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== Significance == |
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Untriseptium is sometimes called '''feynmanium''' (symbol Fy) because ] noted<ref> |
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{{cite web |
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|author=G. Elert |
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|date= |
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|title=Atomic Models |
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|url=http://physics.info/atomic-models/ |
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|work=The Physics Hypertextbook |
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|accessdate=2009-10-09 |
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}}</ref> that a simplistic interpretation of the ] ] runs into problems with electron orbitals at ''Z'' > 1/α = 137, suggesting that neutral atoms cannot exist beyond untriseptium, and that a periodic table of elements based on electron orbitals therefore breaks down at this point. However, a more rigorous analysis calculates the limit to be ''Z'' ≈ 173.<ref> See ].</ref> |
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=== Bohr model breakdown {{Anchor|Bohr model}} === |
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The ] exhibits difficulty for atoms with atomic number greater than 137, for the speed of an electron in a ], ''v'', is given by |
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:<math>v = Z \alpha c \approx \frac{Z c}{137.036}</math> |
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where ''Z'' is the ], and ''α'' is the ], a measure of the strength of electromagnetic interactions.<ref>See for example {{cite book |
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|author=R. Eisberg, R. Resnick |
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|Year=1985 |
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|title=Quantum Physics of Atoms, Molecules, Solids, Nuclei and Particles |
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|publisher=] |
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|isbn= |
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}}</ref> Under this approximation, any element with an atomic number of greater than 137 would require 1s electrons to be traveling faster than ''c'', the ]. Hence the non-relativistic Bohr model is clearly inaccurate when applied to such an element. |
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=== The Dirac equation === |
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The ] ] also has problems for ''Z'' > 137, for the ground state energy is |
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:<math>E=m c^2 \sqrt{1-Z^2 \alpha^2}</math> |
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where ''m'' is the rest mass of the electron. For ''Z'' > 137, the wave function of the Dirac ground state is oscillatory, rather than bound, and there is no gap between the positive and negative energy spectra, as in the ].<ref> |
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{{cite book |
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|author=J.D. Bjorken, S.D. Drell |
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|year=1964 |
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|title=Relativistic Quantum Mechanics |
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|publisher=] |
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|isbn= |
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}}</ref> |
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More accurate calculations including the effects of the finite size of the nucleus indicate that the binding energy first exceeds 2''mc''<sup>2</sup> for ''Z'' > ''Z''<sub>cr</sub> ≈ 173. For ''Z'' > ''Z''<sub>cr</sub>, if the innermost orbital is not filled, the electric field of the nucleus will pull an electron out of the vacuum, resulting in the spontaneous emission of a positron.<ref> |
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{{cite journal |
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|author=W. Greiner, S. Schramm |
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|year=2008 |
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|title=] |
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|volume=76 |pages=509 |
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|doi= |
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}}, and references therein.</ref> |
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More complete analysis involving relativity shows that the contradiction this particle poses may actually occur in the hypothetical element untriennium (''Z'' = 139; see ]). |
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==See also== |
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* ] |
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* ] – ] |
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* ], section ] |
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== References == |
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{{Reflist}} |
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