| Revision as of 14:17, 10 January 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 449118703 of page Trimethylsilyldiazomethane for the Chem/Drugbox validation project (updated: '').← Previous edit |
Latest revision as of 14:25, 29 January 2022 edit undo119.246.116.98 (talk)No edit summary |
| Line 1: |
Line 1: |
|
{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
|
{{ambox | text = This page contains a copy of the infobox ({{tl|drugbox}}) taken from revid of page ] with values updated to verified values.}} |
|
{{Chembox |
|
{{drugbox |
|
| verifiedrevid = 404978232 |
|
| verifiedrevid = 477001424 |
|
|
| IUPAC_name = 2-Oxo-<small>L</small>-threo-hexono-1,4-lactone-2,3-enediol<br />''or''<br />(''R'')-3,4-dihydroxy-5-((''S'')- 1,2-dihydroxyethyl)furan-2(5''H'')-one |
|
| ImageFile = Trimethylsilyldiazomethane.png |
|
|
|
| image = L-Ascorbic_acid.svg |
|
| ImageSize = 150 |
|
|
|
| width = 200px |
|
| IUPACName = (Diazomethyl)trimethylsilane |
|
|
|
| image2 = Ascorbic-acid-from-xtal-1997-3D-balls.png |
|
| OtherNames = Trimethylsilyldiazomethane<br />Diazo(trimethylsilyl)methane |
|
|
|
| width2 = 200px |
|
| Section1 = {{Chembox Identifiers |
|
|
|
|
|
| CASNo = 18107-18-1 |
|
|
|
<!--Clinical data--> |
| ⚫ |
| CASNo_Ref = {{cascite|correct|CAS}} |
|
|
|
| Drugs.com = {{drugs.com|MTM|vitamin_c}} |
| ⚫ |
| PubChem = 167693 |
|
|
|
| licence_EU = <!-- EMEA requires brand name --> |
|
| PubChem_Ref = {{Pubchemcite|correct|PubChem}} |
|
|
|
| licence_US = <!-- FDA may use generic name --> |
| ⚫ |
| ChemSpiderID = 146699 |
|
|
|
| pregnancy_AU = <!-- A / B1 / B2 / B3 / C / D / X --> |
| ⚫ |
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
|
|
| pregnancy_US = <!-- A / B / C / D / X --> |
|
| MeSHName = Trimethylsilyldiazomethane |
|
|
|
| pregnancy_category = A |
|
| SMILES = C(C)(C)#N |
|
|
|
| legal_AU = <!-- Unscheduled / S2 / S3 / S4 / S5 / S6 / S7 / S8 / S9 --> |
|
| SMILES1 = ==C(C)(C)C |
|
|
|
| legal_CA = <!-- / Schedule I, II, III, IV, V, VI, VII, VIII --> |
| ⚫ |
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
|
|
|
| legal_UK = <!-- GSL / P / POM / CD / Class A, B, C --> |
|
| StdInChI = 1S/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3 |
|
|
|
| legal_US = <!-- OTC / Rx-only / Schedule I, II, III, IV, V --> |
|
| InChI1 = 1/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3 |
|
|
|
| legal_status = general public availability |
| ⚫ |
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
|
|
|
| routes_of_administration = oral |
| ⚫ |
| StdInChIKey = ONDSBJMLAHVLMI-UHFFFAOYSA-N |
|
|
|
|
|
| InChIKey1 = ONDSBJMLAHVLMI-UHFFFAOYAN |
|
|
|
<!--Pharmacokinetic data--> |
|
| Beilstein = 1902903}} |
|
|
|
| bioavailability = rapid & complete |
|
| Section2 = {{Chembox Properties |
|
|
|
| protein_bound = negligible |
|
| C = 4 |
|
|
|
| elimination_half-life = varies according to plasma concentration <!-- can be 30 min to weeks, depending on body stores --> |
|
| H = 10 |
|
|
| N = 2 |
|
| excretion = renal |
|
|
|
|
| Si = 1 |
|
|
|
<!--Identifiers--> |
|
| ExactMass = 114.061324863 g mol<sup>-1</sup> |
|
|
⚫ |
| CASNo_Ref = {{cascite|correct|CAS}} |
|
| Appearance = greenish-yellow liquid<ref>{{ cite journal | doi = 10.1021/ja01006a055 | title = Trimethylsilyldiazomethane and trimethylsilylcarbene | year = 1968 | last1 = Seyferth | first1 = Dietmar. | last2 = Dow | first2 = Alan W. | last3 = Menzel | first3 = Horst. | last4 = Flood | first4 = Thomas C. | journal = ] | volume = 90 | issue = 4 | pages = 1080–1082 }}</ref><ref>{{cite journal | doi = 10.1016/S0022-328X(00)82916-2 | title = Trimethylsilyl-substituted diazoalkanes I. Trimethylsilyldiazomethane | year = 1972 | last1 = Seyferth | first1 = Dietmar | last2 = Menzel | first2 = Horst | last3 = Dow | first3 = Alan W. | last4 = Flood | first4 = Thomas C. | journal = ] | volume = 44 | issue = 2 | pages = 279–290 }}</ref> }} |
|
|
|
| CAS_number_Ref = {{cascite|correct|??}} |
|
|Section3={{Chembox Hazards |
|
|
|
| CAS_number = 50-81-7 |
|
| ExternalMSDS = |
|
|
|
| ATC_prefix = A |
|
| EUClass = {{Hazchem Xn}} {{Hazchem F}} {{Hazchem N}} |
|
|
|
| ATC_suffix = 11G |
|
| Autoignition= |
|
|
|
| ChEBI_Ref = {{ebicite|correct|EBI}} |
|
}} |
|
|
|
| ChEBI = 29073 |
|
⚫ |
| PubChem = 5785 |
|
|
| DrugBank_Ref = {{drugbankcite|correct|drugbank}} |
|
|
| DrugBank = DB00126 |
|
⚫ |
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
⚫ |
| ChemSpiderID = 10189562 |
|
|
| NIAID_ChemDB = 002072 |
|
|
| UNII_Ref = {{fdacite|correct|FDA}} |
|
|
| UNII = PQ6CK8PD0R |
|
|
| KEGG_Ref = {{keggcite|correct|kegg}} |
|
|
| KEGG = D00018 |
|
|
| ChEMBL_Ref = {{ebicite|correct|EBI}} |
|
|
| ChEMBL = 196 |
|
|
|
|
|
<!--Chemical data--> |
|
|
| chemical_formula = |
|
|
| C=6 | H=7 | O=6 |
|
|
| molecular_weight = 176.12 g/] |
|
|
| smiles = C((1C(=C(C(=O)O1)O)O)O)O |
|
|
| InChI = 1/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2,5,7-10H,1H2/t2-,5+/m0/s1 |
|
⚫ |
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
|
|
| StdInChI = 1S/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2,5,7-10H,1H2/t2-,5+/m0/s1 |
|
⚫ |
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
|
⚫ |
| StdInChIKey = CIWBSHSKHKDKBQ-JLAZNSOCSA-N |
|
|
| synonyms = <small>L</small>-ascorbic acid |
|
|
| density = 1.694 |
|
|
| melting_point = 190 |
|
|
| boiling_point = 553 |
|
}} |
|
}} |
