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| Section2 = {{Chembox Properties | Section2 = {{Chembox Properties
| H=8|N=2|S=1 | H=8|N=2|S=5
| MolarMass = | MolarMass =
| Appearance = Yellow powder | Appearance = Yellow powder

Revision as of 11:00, 14 January 2025

Ammonium pentasulfide
Names
IUPAC name diazanium;sulfide
Other names Diammonium pentasulfide
Identifiers
CAS Number
3D model (JSmol)
EC Number
  • 235-223-4
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2H3N.5S/h2*1H3;;;;;/q;;5*-2/p+2Key: BTMGSTQWMJHDHO-UHFFFAOYSA-P
SMILES
  • ......
Properties
Chemical formula H8N2S5
Molar mass 196.38 g·mol
Appearance Yellow powder
Density 3.024 g/cm
Solubility in water reacts with water
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Precautionary statements P264, P270, P301, P312, P330, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Ammonium pentasulfide is a chemical compound with the chemical formula (NH4)2S5.

Synthesis

Passing hydrogen sulfide through a suspension of powdered sulfur in a concentrated ammonia solution:

2NH3 + H2 + 5S → (NH4)2S5

Physical properties

Ammonium tellurate forms yellow crystals, decomposing in water, of monoclinic system, spatial group P 21/C, cell parameters a = 0.5427 nm, B = 1.6226 Nm, c = 0.9430 Nm, β = 105.31°, Z = 4.

Chemical properties

The compound decomposes when stored in air or slightly heated:

(NH4)2S5 → 2NH3 + H2S + S

References

  1. "Crystal structure of diammoniumpentasulfide (NH4)2S5". Zeitschrift für Kristallographie. 172 (1–2): 153–158. 1 January 1985. doi:10.1524/zkri.1985.172.1-2.153. ISSN 0044-2968. Retrieved 14 January 2025.
Ammonium salts
Inorganic salts
monatomic anions
oxyanions
other anions
Organic salts
Categories: