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Revision as of 14:43, 10 January 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 458928850 of page Uranium_borohydride for the Chem/Drugbox validation project (updated: '').← Previous edit Revision as of 14:44, 10 January 2012 edit undoBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 468245454 of page Uranium_hexafluoride for the Chem/Drugbox validation project (updated: '').Next edit →
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} {{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}}
{{chembox {{chembox
| verifiedrevid = 444638249 | verifiedrevid = 450441052
| Name = Uranium borohydride | Name = Uranium Hexafluoride

| ImageFile =
| ImageFile = Uranium-hexafluoride-2D-V2.svg
<!-- | ImageSize = 200px --> | ImageSize = 125px
| ImageName = Uranium borohydride
| IUPACName = Uranium hexafluoride<br/>Uranium(VI) fluoride
| OtherNames =
| Section1 = {{Chembox Identifiers | Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 15385433 | ChemSpiderID = 22966
| PubChem = 24560
| InChI = 1/2BH5.U/h2*1H5;/q2*-1;+2
| InChI = 1/6FH.U/h6*1H;/q;;;;;;+6/p-6/rF6U/c1-7(2,3,4,5)6
| InChIKey = KUMAXXHQRVBPEC-UHFFFAOYAW
| InChIKey = SANRKQGLYCLAFE-IIYYNVFAAT
| SMILES = ..
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 30235
| SMILES = F(F)(F)(F)(F)F
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2BH5.U/h2*1H5;/q2*-1;+2 | StdInChI = 1S/6FH.U/h6*1H;/q;;;;;;+6/p-6
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = KUMAXXHQRVBPEC-UHFFFAOYSA-N | StdInChIKey = SANRKQGLYCLAFE-UHFFFAOYSA-H
| CASNo = 7783-81-5
| CASNo_Ref = {{cascite|correct|??}}
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo =
| RTECS = YR4720000
| UNNumber = 2978 (<1% <sup>235</sup>U)<br/>2977 (>1% <sup>235</sup>U)
}} }}
| Section2 = {{Chembox Properties | Section2 = {{Chembox Properties
| Formula = U(BH<sub>4</sub>)<sub>4</sub> | Formula = UF<sub>6</sub>
| MolarMass = 297.27 g/mol | MolarMass = 352.02 g/mol
| Density = | Appearance = colorless solid
| Density = 5.09 g/cm<sup>3</sup>, solid
| Solvent = other solvents
| SolubleOther = Decomposes | Solubility = reacts
| SolubleOther = soluble in ], ], liquid ] and ] <br> dissolves in ]
| MeltingPt =
| MeltingPt = 64.05 °C (triple point)
| BoilingPt = }} | BoilingPt = 56.5 °C (sublimes)
}}
| Section3 = {{Chembox Structure
| CrystalStruct = ], ]
| SpaceGroup = Pnma, No. 62
| Coordination = octahedral (''O<sub>h</sub>'')
| Dipole = 0
}}
| Section4 = {{Chembox Thermochemistry
| DeltaHf = – solid: −(2197,7&nbsp;±&nbsp;1,8)&nbsp;]·mol<sup>−1</sup><ref name="Enthalpie">Gerald K. Johnson: "The Enthalpy of Formation of Uranium Hexafluoride", '']'', '''1979''', ''11&nbsp;(5)'', p.&nbsp;483–490; {{DOI|10.1016/0021-9614(79)90126-5}}.</ref>
– gaseous: −(2148,1&nbsp;±&nbsp;1,8)&nbsp;kJ·mol<sup>−1</sup><ref name="Enthalpie"/>
| Entropy = – solid: −430,4&nbsp;±&nbsp;1,5&nbsp;J·K<sup>−1</sup>·mol<sup>−1</sup><ref name="Enthalpie"/>
– gaseous: −280,4&nbsp;±&nbsp;1,5&nbsp;J·K<sup>−1</sup>·mol<sup>−1</sup><ref name="Enthalpie"/>
}}
| Section7 = {{Chembox Hazards
| ExternalMSDS =
| EUIndex = 092-002-00-3
| EUClass = Very toxic ('''T+''')<br/>Dangerous for the environment ('''N''')
| RPhrases = {{R26/28}}, {{R33}}, {{R51/53}}
| SPhrases = {{S1/2}}, {{S20/21}}, {{S45}}, {{S61}}
| FlashPt = Non-flammable
}}
| Section8 = {{Chembox Related
| OtherAnions = ]
| OtherCations = ]<br/>]
| OtherFunctn = ]<br/>]<br/>]
| Function = uranium fluorides
}}
}} }}

Revision as of 14:44, 10 January 2012

This page contains a copy of the infobox ({{chembox}}) taken from revid 468245454 of page Uranium_hexafluoride with values updated to verified values.
Uranium Hexafluoride
Names
IUPAC names Uranium hexafluoride
Uranium(VI) fluoride
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
RTECS number
  • YR4720000
UN number 2978 (<1% U)
2977 (>1% U)
InChI
  • InChI=1S/6FH.U/h6*1H;/q;;;;;;+6/p-6Key: SANRKQGLYCLAFE-UHFFFAOYSA-H
  • InChI=1/6FH.U/h6*1H;/q;;;;;;+6/p-6/rF6U/c1-7(2,3,4,5)6Key: SANRKQGLYCLAFE-IIYYNVFAAT
SMILES
  • F(F)(F)(F)(F)F
Properties
Chemical formula UF6
Molar mass 352.02 g/mol
Appearance colorless solid
Density 5.09 g/cm, solid
Melting point 64.05 °C (triple point)
Boiling point 56.5 °C (sublimes)
Solubility in water reacts
Solubility soluble in chloroform, CCl4, liquid chlorine and bromine
dissolves in nitrobenzene
Structure
Crystal structure Orthorhombic, oP28
Space group Pnma, No. 62
Coordination geometry octahedral (Oh)
Dipole moment 0
Thermochemistry
Std molar
entropy
(S298)
– solid: −430,4 ± 1,5 J·K·mol

– gaseous: −280,4 ± 1,5 J·K·mol

Std enthalpy of
formation
fH298)
– solid: −(2197,7 ± 1,8) kJ·mol

– gaseous: −(2148,1 ± 1,8) kJ·mol

Hazards
Flash point Non-flammable
Related compounds
Other anions Uranium hexachloride
Other cations Neptunium hexafluoride
Plutonium hexafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Tracking categories (test):
Chemical compound
  1. ^ Gerald K. Johnson: "The Enthalpy of Formation of Uranium Hexafluoride", The Journal of Chemical Thermodynamics, 1979, 11 (5), p. 483–490; doi:10.1016/0021-9614(79)90126-5.