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Diamond
A scattering of round-brilliant cut diamonds shows off the many reflecting facets.
General
Category	Native Minerals
Formula (repeating unit)	C
Crystal system	Isometric-Hexoctahedral (Cubic)
Identification
Formula mass	12.01 u
Color	Typically yellow, brown or gray to colorless. Less often blue, green, black, translucent white, pink, violet, orange, purple and red.
Crystal habit	Octahedral
Cleavage	111 (perfect in four directions)
Fracture	Conchoidal (shell-like)
Mohs scale hardness	10
Luster	Adamantine
Streak	White
Specific gravity	3.52±0.01
Density	3.5–3.53 g/cm
Polish luster	Adamantine
Optical properties	Singly Refractive
Refractive index	2.4175–2.4178
Birefringence	None
Pleochroism	None
Dispersion	0.044

In mineralogy, diamond (from the ancient Greek adámas, meaning "proper" or "unalterable") is the allotrope of carbon, where the carbon atoms are arranged in a variation of the face centered cubic crystal structure called diamond lattice. Diamond is the second most stable form of carbon after graphite; however, the conversion rate from diamond to graphite is negligible at ambient conditions. Diamond is specifically renowned as a material with superlative physical qualities, most of which originate from the strong covalent bonding between its atoms. In particular, diamond has the highest hardness and thermal conductivity of any bulk material synthesized so far. Those properties determine the major industrial application of diamond in cutting and polishing tools.

Diamond has remarkable optical characteristics. Because of its extremely rigid lattice, it can be contaminated by only few types of impurities, such as boron and nitrogen. Combined with the wide transparency (corresponding to the wide band gap of 5.5 eV), this results in clear, colorless appearance of most natural diamonds. Small amounts of defects or impurities (about one part per million) color diamond blue (boron), yellow (nitrogen), brown (lattice defects), green, purple, pink, orange or red. Diamond also has relatively high optical dispersion, that is ability to disperse light of different colors, which results in its characteristic luster. Excellent optical and mechanical properties, combined with efficient marketing, make diamond the most popular gemstone.

Most natural diamonds are formed at high-pressure high-temperature conditions existing at depths of 140 km to 190 km in the Earth mantle. Carbon-containing minerals provide the carbon source, and the growth occurs over periods from 1 billion to 3.3 billion years, which respectively corresponds to roughly 25% and 75% of the age of the Earth. Diamonds are brought close to the Earth surface through deep volcanic eruptions by a magma, which cools into igneous rocks known as kimberlites and lamproites. Diamonds can also be produced synthetically in a high-pressure high-temperature process which approximately simulates the conditions in the Earth mantle. An alternative, and completely different growth technique is chemical vapor deposition. Several non-diamond materials, which include cubic zirconia and silicon carbide and are often called diamond simulants, resemble diamond in appearance and many properties. Special gemological techniques have been specially developed to distinguish natural and synthetic diamonds and diamond simulants.

History

The name diamond is derived from the ancient Greek ἀδάμας (adámas), "proper", "unalterable", "unbreakable, untamed", from ἀ- (a-), "un-" + δαμάω (damáō), "I overpower, I tame". However, diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could then be found many centuries ago along the rivers Penner, Krishna and Godavari. Diamonds have been known in India for at least 3000 years but most likely 6000 years.

Diamonds have been treasured as gemstones since their use as religious icons in ancient India. Their usage in engraving tools also dates to early human history. Popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.

In 1813, Humphry Davy used a lens to concentrate the rays of the sun on a diamond in an atmosphere of oxygen, and showed that the only product of the combustion was carbon dioxide, proving that diamond is composed of carbon. Later, he showed that in an atmosphere devoid of oxygen, diamond is converted to graphite.

The most familiar usage of diamonds today is as gemstones used for adornment, a usage which dates back into antiquity. The dispersion of white light into spectral colors is the primary gemological characteristic of gem diamonds. In the twentieth century, experts in the field of gemology have developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem. Four characteristics, known informally as the four Cs, are now commonly used as the basic descriptors of diamonds: these are carat, cut, color, and clarity.

Material properties

A diamond is a transparent crystal of tetrahedrally bonded carbon atoms (sp) that crystallizes into the diamond lattice which is a variation of the face centered cubic structure. Diamonds have been adapted for many uses because of the material's exceptional physical characteristics. Most notable are its extreme hardness and thermal conductivity (900 – 2320 W/m K), as well as wide bandgap and high optical dispersion. Above 1700 °C (1973 K / 3583 °F) in vacuum or oxygen-free atmosphere, diamond converts to graphite; in air, transformation starts at ~800 °C. Naturally occurring diamonds have a density ranging from 3.15 to 3.53 g/cm³, with very pure diamond typically extremely close to 3.52 g/cm³.

Hardness

Diamond is the hardest natural material known, where hardness is defined as resistance to scratching. Diamond has a hardness of 10 (hardest) on Mohs scale of mineral hardness. Diamond's hardness has been known since antiquity, and is the source of its name.

The hardest natural diamonds in the world are from the Copeton and Bingara fields located in the New England area in New South Wales, Australia. They were called can-ni-faire ("cannot be processed"—a combination of English "can", Italian "ni" = not and French "faire" = do) by the cutters in Antwerp when they started to arrive in quantity from Australia in the 1870s. These diamonds are generally small, perfect to semiperfect octahedra, and are used to polish other diamonds. Their hardness is associated with the crystal growth form, which is single-stage crystal growth. Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness. It is possible to treat regular diamonds under a combination of high pressure and high temperature to produce diamonds that are harder than the diamonds used in hardness gauges.

The hardness of diamonds contributes to its suitability as a gemstone. Because it can only be scratched by other diamonds, it maintains its polish extremely well. Unlike many other gems, it is well-suited to daily wear because of its resistance to scratching—perhaps contributing to its popularity as the preferred gem in engagement or wedding rings, which are often worn every day.

Industrial use of diamonds has historically been associated with their hardness; this property makes diamond the ideal material for cutting and grinding tools. As the hardest known naturally occurring material, diamond can be used to polish, cut, or wear away any material, including other diamonds. Common industrial adaptations of this ability include diamond-tipped drill bits and saws, and the use of diamond powder as an abrasive. Less expensive industrial-grade diamonds, known as bort, with more flaws and poorer color than gems, are used for such purposes.

Diamond is not suitable for machining ferrous alloys at high speeds as carbon is soluble in iron at the high temperatures created by high-speed machining, leading to greatly increased wear on diamond tools when compared to alternatives.

These substances can scratch diamond:

• Some diamonds are harder than others.
• Nanocrystalline diamond aggregates produced by high-pressure high-temperature treatment of graphite or fullerite (C₆₀).
• Cubic Boron nitride (Borazon)
• A hexagonal form of diamond called lonsdaleite, which is theoretically predicted to be 58% stronger than diamond.

Electrical conductivity

Other specialized applications also exist or are being developed, including use as semiconductors: some blue diamonds are natural semiconductors, in contrast to most other diamonds, which are excellent electrical insulators. The conductivity and blue color originate from the boron impurity. Boron substitutes for carbon atoms in the diamond lattice, donating a hole into the valence band.

Substantial conductivity is commonly observed in nominally undoped diamond grown by chemical vapor deposition. This conductivity is associated with hydrogen-related species adsorbed at the surface, and it can be removed by annealing or other surface treatments.

Toughness

Toughness relates to a material's ability to resist breakage from forceful impact. The toughness of natural diamond has been measured as 2.0 MPa m, and the critical stress intensity factor is 3.4 MN m. Those values are good compared to other gemstones, but poor compared to most engineering materials. As with any material, the macroscopic geometry of a diamond contributes to its resistance to breakage. Diamond has a cleavage plane and is therefore more fragile in some orientations than others. Diamond cutters use this attribute to cleave some stones, prior to faceting.

Color

Diamond has a wide bandgap of 5.5 eV (or 225 nm) meaning that pure diamond should transmit visible light and appear as a clear colorless crystal. Colors in diamond originate from lattice defects and impurities. The diamond crystal lattice is exceptionally strong and only atoms of nitrogen, boron and hydrogen can be introduced into diamond during the growth at significant concentrations (up to atomic percents). Transition metals Ni and Co, which are commonly used for growth of synthetic diamond by the high-pressure high-temperature techniques, have been detected in diamond as individual atoms, however the maximum concentration is 0.01% for Ni and even much less for Co. Note however, that virtually any element can be introduced in diamond by ion implantation.

Nitrogen is by far the most common impurity found in gem diamonds. Nitrogen is responsible for the yellow and brown in diamonds. Boron is responsible for the gray blue colors. Color in diamond has two additional sources: irradiation (usually by alpha particles), that causes the color in green diamonds; and physical deformation of the diamond crystal known as plastic deformation. Plastic deformation is the cause of color in some brown and perhaps pink and red diamonds. In order of rarity, colorless diamond, by far the most common, is followed by yellow and brown, by far the most common colors, then by blue, green, black, translucent white, pink, violet, orange, purple, and the rarest, red. "Black," or Carbonado, diamonds are not truly black, but rather contain numerous dark inclusions that give the gems their dark appearance. Colored diamonds contain impurities or structural defects that cause the coloration, while pure or nearly pure diamonds are transparent and colorless. Most diamond impurities replace a carbon atom in the crystal lattice, known as a carbon flaw. The most common impurity, nitrogen, causes a slight to intense yellow coloration depending upon the type and concentration of nitrogen present. The Gemological Institute of America (GIA) classifies low saturation yellow and brown diamonds as diamonds in the normal color range, and applies a grading scale from 'D' (colorless) to 'Z' (light yellow). Diamonds of a different color, such as blue, are called fancy colored diamonds, and fall under a different grading scale.

In 2008, the Wittelsbach Diamond, a 35.56 carats (7.112 g) blue diamond once belonging to the King of Spain, fetched over US$24 million at a Christie's auction. In 2009 a 7.03 carats (1.406 g) blue diamond fetched the highest price per-carat ever paid for a diamond when it was sold at auction for 10.5 million Swiss francs (6.97 million Euro or US$9.5 million at the time) which is in excess of US$1.3 million per carat.

Identification

Diamonds can be identified by their high thermal conductivity. Their high refractive index is also indicative, but other materials have similar refractivity. Diamonds do cut glass, but this does not positively identify a diamond because other materials, such as quartz, also lie above glass on the Mohs scale and can also cut glass. Diamonds easily scratch other diamonds, but this damages both diamonds.

Natural history

The formation of natural diamond requires very specific conditions—exposure of carbon-bearing materials to high pressure, ranging approximately between 45 and 60 kilobars, but at a comparatively low temperature range between approximately 1650–2370 °F (900–1300 °C). These conditions are met in two places on Earth; in the lithospheric mantle below relatively stable continental plates, and at the site of a meteorite strike.

Formation in cratons

The conditions for diamond formation to happen in the lithospheric mantle occur at considerable depth corresponding to the aforementioned requirements of temperature and pressure. These depths are estimated between 140 and 190 km though occasionally diamonds have crystallized at depths of 300-400 km as well. The rate at which temperature changes with increasing depth into the Earth varies greatly in different parts of the Earth. In particular, under oceanic plates the temperature rises more quickly with depth, beyond the range required for diamond formation at the depth required. The correct combination of temperature and pressure is only found in the thick, ancient, and stable parts of continental plates where regions of lithosphere known as cratons exist. Long residence in the cratonic lithosphere allows diamond crystals to grow larger.

Through studies of carbon isotope ratios (similar to the methodology used in carbon dating, except with the stable isotopes C-12 and C-13), it has been shown that the carbon found in diamonds comes from both inorganic and organic sources. Some diamonds, known as harzburgitic, are formed from inorganic carbon originally found deep in the Earth's mantle. In contrast, eclogitic diamonds contain organic carbon from organic detritus that has been pushed down from the surface of the Earth's crust through subduction (see plate tectonics) before transforming into diamond. These two different source of carbons have measurably different C:C ratios. Diamonds that have come to the Earth's surface are generally quite old, ranging from under 1 billion to 3.3 billion years old. This is 22% to 73% of the age of the Earth.

Diamonds occur most often as euhedral or rounded octahedra and twinned octahedra known as macles or maccles. As diamond's crystal structure has a cubic arrangement of the atoms, they have many facets that belong to a cube, octahedron, rhombicosidodecahedron, tetrakis hexahedron or disdyakis dodecahedron. The crystals can have rounded off and unexpressive edges and can be elongated. Sometimes they are found grown together or form double "twinned" crystals at the surfaces of the octahedron. These different shapes and habits of the diamonds result from differing external circumstances. Diamonds (especially those with rounded crystal faces) are commonly found coated in nyf, an opaque gum-like skin.

Formation in meteorite impact craters

Diamonds can also form in other natural high-pressure events. Very small diamonds, known as microdiamonds or nanodiamonds, have been found in meteorite impact craters. Such impact events create shock zones of high pressure and temperature suitable for diamond formation. Impact-type microdiamonds can be used as an indicator of ancient impact craters.

Extraterrestrial formation

Not all diamonds found on Earth originated here. A type of diamond called carbonado diamond that is found in South America and Africa may have been deposited there via an asteroid impact (not formed from the impact) about 3 billion years ago. These diamonds may have formed in the intrastellar environment, but as of 2008, there was no scientific consensus on how carbonado diamonds originated.

Presolar grains in many meteorites found on Earth contain nanodiamonds of extraterrestrial origin, probably formed in supernovas. Scientific evidence indicates that white dwarf stars have a core of crystallized carbon and oxygen nuclei. The largest of these found in the universe so far, BPM 37093, is located 50 light years away in the constellation Centaurus. A news release from the Harvard-Smithsonian Center for Astrophysics described the 2,500 mile-wide stellar core as a diamond. It was referred to as Lucy, after the Beatles song "Lucy in the Sky With Diamonds".

Surfacing

Diamond-bearing rock is brought close to the surface through deep-origin volcanic eruptions. The magma for such a volcano must originate at a depth where diamonds can be formed—150 km (93 mi) or more (three times or more the depth of source magma for most volcanoes). This is a relatively rare occurrence. These typically small surface volcanic craters extend downward in formations known as volcanic pipes. The pipes contain material that was transported toward the surface by volcanic action, but was not ejected before the volcanic activity ceased. During eruption these pipes are open to the surface, resulting in open circulation; many xenoliths of surface rock and even wood and/or fossils are found in volcanic pipes. Diamond-bearing volcanic pipes are closely related to the oldest, coolest regions of continental crust (cratons). This is because cratons are very thick, and their lithospheric mantle extends to great enough depth that diamonds are stable. Not all pipes contain diamonds, and even fewer contain enough diamonds to make mining economically viable.

The magma in volcanic pipes is usually one of two characteristic types, which cool into igneous rock known as either kimberlite or lamproite. The magma itself does not contain diamond; instead, it acts as an elevator that carries deep-formed rocks (xenoliths), minerals (xenocrysts), and fluids upward. These rocks are characteristically rich in magnesium-bearing olivine, pyroxene, and amphibole minerals which are often altered to serpentine by heat and fluids during and after eruption. Certain indicator minerals typically occur within diamantiferous kimberlites and are used as mineralogical tracers by prospectors, who follow the indicator trail back to the volcanic pipe which may contain diamonds. These minerals are rich in chromium (Cr) or titanium (Ti), elements which impart bright colors to the minerals. The most common indicator minerals are chromian garnets (usually bright red Cr-pyrope, and occasionally green ugrandite-series garnets), eclogitic garnets, orange Ti-pyrope, red high-Cr spinels, dark chromite, bright green Cr-diopside, glassy green olivine, black picroilmenite, and magnetite. Kimberlite deposits are known as blue ground for the deeper serpentinized part of the deposits, or as yellow ground for the near surface smectite clay and carbonate weathered and oxidized portion.

Once diamonds have been transported to the surface by magma in a volcanic pipe, they may erode out and be distributed over a large area. A volcanic pipe containing diamonds is known as a primary source of diamonds. Secondary sources of diamonds include all areas where a significant number of diamonds, eroded out of their kimberlite or lamproite matrix, and accumulated because of water or wind action. These include alluvial deposits and deposits along existing and ancient shorelines, where loose diamonds tend to accumulate because of their approximate size and density. Diamonds have also rarely been found in deposits left behind by glaciers (notably in Wisconsin and Indiana); however, in contrast to alluvial deposits, glacial deposits are minor and are therefore not viable commercial sources of diamond.

Commercial markets

The diamond industry can be broadly separated into two basically distinct categories: one dealing with gem-grade diamonds and another for industrial-grade diamonds. While a large trade in both types of diamonds exists, the two markets act in dramatically different ways.

Gemstones

A large trade in gem-grade diamonds exists. Unlike precious metals such as gold or platinum, gem diamonds do not trade as a commodity: there is a substantial mark-up in the retail sale of diamonds. Contrary to popular belief, there is a well-established market for resale of polished diamonds (e.g. pawnbroking, auctions, second-hand jewelry stores, diamantaires, bourses, etc.). One hallmark of the trade in gem-quality diamonds is its remarkable concentration: wholesale trade and diamond cutting is limited to just a few locations. 92% of diamond pieces cut in 2003 were in Surat, Gujarat, India. Other important centers of diamond cutting and trading are Antwerp, where the International Gemological Institute is based, London, New York, Tel Aviv, and Amsterdam. A single company—De Beers—controls a significant proportion of the trade in diamonds. They are based in Johannesburg, South Africa and London, England. One contributory factor is the geological nature of diamond deposits: several large primary kimberlite-pipe mines each account for significant portions of market share (such as the Jwaneng mine in Botswana, which is a single large pit operated by De Beers that can produce between 12.5 to 15 million carats of diamonds per year), whereas secondary alluvial diamond deposits tend to be fragmented amongst many different operators because they can be dispersed over many hundreds of square kilometers (e.g., alluvial deposits in Brazil).

The production and distribution of diamonds is largely consolidated in the hands of a few key players, and concentrated in traditional diamond trading centers. The most important being Antwerp, where 80% of all rough diamonds, 50% of all cut diamonds and more than 50% of all rough, cut and industrial diamonds combined are handled. This makes Antwerp the de facto 'world diamond capital'. New York, however, along with the rest of the United States, is where almost 80% of the world's diamonds are sold, including auction sales. Also, the largest and most unusually shaped rough diamonds end up in New York. The De Beers company, as the world's largest diamond miner holds a clearly dominant position in the industry, and has done so since soon after its founding in 1888 by the British imperialist Cecil Rhodes. De Beers owns or controls a significant portion of the world's rough diamond production facilities (mines) and distribution channels for gem-quality diamonds. The company and its subsidiaries own mines that produce some 40 percent of annual world diamond production. At one time it was thought over 80 percent of the world's rough diamonds passed through the Diamond Trading Company (DTC, a subsidiary of De Beers) in London, but presently the figure is estimated at around 40 percent. De Beers sold off the vast majority its diamond stockpile in the late 1990s - early 2000s and the remainder largely represents working stock (diamonds that are being sorted before sale). This was well documented in the press but remains little known to the general public.

The De Beers diamond advertising campaign is acknowledged as one of the most successful and innovative campaigns in history. N. W. Ayer & Son, the advertising firm retained by De Beers in the mid-20th century, succeeded in reviving the American diamond market and opened up new markets, even in countries where no diamond tradition had existed before. N.W. Ayer's multifaceted marketing campaign included product placement, advertising the diamond itself rather than the De Beers brand, and building associations with celebrities and royalty. This coordinated campaign has lasted decades and continues today; it is perhaps best captured by the slogan "a diamond is forever".

Further down the supply chain, members of The World Federation of Diamond Bourses (WFDB) act as a medium for wholesale diamond exchange, trading both polished and rough diamonds. The WFDB consists of independent diamond bourses in major cutting centers such as Tel Aviv, Antwerp, Johannesburg and other cities across the USA, Europe and Asia.

In 2000, the WFDB and The International Diamond Manufacturers Association established the World Diamond Council to prevent the trading of diamonds used to fund war and inhumane acts. WFDB's additional activities also include sponsoring the World Diamond Congress every two years, as well as the establishment of the International Diamond Council (IDC) to oversee diamond grading.

Industrial grade

The market for industrial-grade diamonds operates much differently from its gem-grade counterpart. Industrial diamonds are valued mostly for their hardness and heat conductivity, making many of the gemological characteristics of diamonds, such as clarity and color, irrelevant for most applications. This helps explain why 80% of mined diamonds (equal to about 100 million carats or 20,000 kg annually), unsuitable for use as gemstones, are destined for industrial use. In addition to mined diamonds, synthetic diamonds found industrial applications almost immediately after their invention in the 1950s; another 3 billion carats (600 metric tons) of synthetic diamond is produced annually for industrial use. Approximately 90% of diamond grinding grit is currently of synthetic origin.

The dominant industrial use of diamond is in cutting, drilling, grinding, and polishing. Most uses of diamonds in these technologies do not require large diamonds; in fact, most diamonds that are gem-quality except for their small size, can find an industrial use. Diamonds are embedded in drill tips or saw blades, or ground into a powder for use in grinding and polishing applications. Specialized applications include use in laboratories as containment for high pressure experiments (see diamond anvil cell), high-performance bearings, and limited use in specialized windows.

With the continuing advances being made in the production of synthetic diamonds, future applications are becoming feasible. Garnering much excitement is the possible use of diamond as a semiconductor suitable to build microchips from, or the use of diamond as a heat sink in electronics.

The boundary between gem-quality diamonds and industrial diamonds is poorly defined and partly depends on market conditions (for example, if demand for polished diamonds is high, some suitable stones will be polished into low-quality or small gemstones rather than being sold for industrial use). Within the category of industrial diamonds, there is a sub-category comprising the lowest-quality, mostly opaque stones, which are known as bort or 'boart'.

Supply chain

Approximately 130 million carats (26,000 kg (57,000 lb)) are mined annually, with a total value of nearly USD $9 billion, and about 100,000 kg (220,000 lb) are synthesized annually.

Roughly 49% of diamonds originate from central and southern Africa, although significant sources of the mineral have been discovered in Canada, India, Russia, Brazil, and Australia. They are mined from kimberlite and lamproite volcanic pipes, which can bring diamond crystals, originating from deep within the Earth where high pressures and temperatures enable them to form, to the surface. The mining and distribution of natural diamonds are subjects of frequent controversy such as with concerns over the sale of conflict diamonds or blood diamonds by African paramilitary groups. The diamond supply chain is controlled by a limited number of powerful businesses, and is also highly concentrated in a small number of locations around the world (see figure).

Mining, sources and production

Only a very small fraction of the diamond ore consists of actual diamonds. The ore is crushed, during which care is required not to destroy larger diamonds , and then sorted by density. Today, diamonds are located in the diamond-rich density fraction with the help of X-ray fluorescence, after which the final sorting steps are done by hand. Before the use of X-rays became commonplace, the separation was done with grease belts; diamonds have a stronger tendency to stick to grease than the other minerals in the ore.

Historically diamonds were found only in alluvial deposits in southern India. India led the world in diamond production from the time of their discovery in approximately the 9th century BC to the mid-18th century AD, but the commercial potential of these sources had been exhausted by the late 18th century and at that time India was eclipsed by Brazil where the first non-Indian diamonds were found in 1725.

Diamond production of primary deposits (kimberlites and lamproites) only started in the 1870s after the discovery of the Diamond fields in South Africa. Production has increased over time and now an accumulated total of 4.5 billion carats have been mined since that date. Interestingly 20% of that amount has been mined in the last 5 years alone and during the last ten years 9 new mines have started production while 4 more are waiting to be opened soon. Most of these mines are located in Canada, Zimbabwe, Angola, and one in Russia.

In the U.S., diamonds have been found in Arkansas, Colorado, and Montana. In 2004, a startling discovery of a microscopic diamond in the U.S. led to the January 2008 bulk-sampling of kimberlite pipes in a remote part of Montana.

Today, most commercially viable diamond deposits are in Russia (mostly in Yakutia, for example Mir pipe and Udachnaya pipe), Botswana, Australia (Northern and Western Australia) and the Democratic Republic of Congo.

In 2005, Russia produced almost one-fifth of the global diamond output, reports the British Geological Survey. Australia boasts the richest diamantiferous pipe with production reaching peak levels of 42 metric tons (41 long tons; 46 short tons) per year in the 1990s.

There are also commercial deposits being actively mined in the Northwest Territories of Canada and Brazil. Diamond prospectors continue to search the globe for diamond-bearing kimberlite and lamproite pipes.

Controversial sources

In some of the more politically unstable central African and west African countries, revolutionary groups have taken control of diamond mines, using proceeds from diamond sales to finance their operations. Diamonds sold through this process are known as conflict diamonds or blood diamonds. Major diamond trading corporations continue to fund and fuel these conflicts by doing business with armed groups. In response to public concerns that their diamond purchases were contributing to war and human rights abuses in central and western Africa, the United Nations, the diamond industry and diamond-trading nations introduced the Kimberley Process in 2002. The Kimberley Process aims to ensure that conflict diamonds do not become intermixed with the diamonds not controlled by such rebel groups. This is done by requiring diamond-producing countries to provide proof that the money they make from selling the diamonds is not used to fund criminal or revolutionary activities. Although the Kimberley Process has been moderately successful in limiting the number of conflict diamonds entering the market, some still find their way in. 2–3% of all diamonds traded today are potentially conflict diamonds. Two major flaws still hinder the effectiveness of the Kimberley Process: (1) the relative ease of smuggling diamonds across African borders, and (2) the violent nature of diamond mining in nations that are not in a technical state of war and whose diamonds are therefore considered "clean."

The Canadian Government has set up a body known as Canadian Diamond Code of Conduct to help authenticate Canadian diamonds. This is a very stringent tracking system of diamonds and helps protect the 'conflict free' label of Canadian diamonds.

Distribution

The Diamond Trading Company (DTC) is a subsidiary of De Beers and markets rough diamonds from De Beers-operated mines (it withdrew from purchasing diamonds on the open market in 1999 and ceased purchasing Russian diamonds mined by Russian company Alrosa, at the end of 2008. Alrosa has successfully appealed against a European court ruling and will resume is sales in May 2009.).

Once purchased by Sightholders (which is a trademark term referring to the companies that have a three-year supply contract with DTC), diamonds are cut and polished in preparation for sale as gemstones. The cutting and polishing of rough diamonds is a specialized skill that is concentrated in a limited number of locations worldwide. Traditional diamond cutting centers are Antwerp, Amsterdam, Johannesburg, New York, and Tel Aviv. Recently, diamond cutting centers have been established in China, India, Thailand, Namibia and Botswana. Cutting centers with lower cost of labor, notably Surat in Gujarat, India, handle a larger number of smaller carat diamonds, while smaller quantities of larger or more valuable diamonds are more likely to be handled in Europe or North America. The recent expansion of this industry in India, employing low cost labor, has allowed smaller diamonds to be prepared as gems in greater quantities than was previously economically feasible.

Diamonds which have been prepared as gemstones are sold on diamond exchanges called bourses. There are 26 registered diamond bourses in the world. Bourses are the final tightly controlled step in the diamond supply chain; wholesalers and even retailers are able to buy relatively small lots of diamonds at the bourses, after which they are prepared for final sale to the consumer. Diamonds can be sold already set in jewelry, or sold unset ("loose"). According to the Rio Tinto Group, in 2002 the diamonds produced and released to the market were valued at US$9 billion as rough diamonds, US$14 billion after being cut and polished, US$28 billion in wholesale diamond jewelry, and US$57 billion in retail sales.

Synthetics, simulants, and enhancements

Synthetics

Synthetic diamonds are diamond crystals that are manufactured in a laboratory, as opposed to natural diamonds which form naturally within the Earth. The gemological and industrial uses of diamond have created a large demand for rough stones. This demand has long been satisfied in large part by synthetic diamonds, which have been manufactured by various processes for more than half a century. However, in recent years it has become possible to produce gem-quality synthetic diamonds of significant size.

The majority of commercially available synthetic diamonds are yellow in color and produced by so called High Pressure High Temperature (HPHT) processes. The yellow color is caused by nitrogen impurities. Other colors may also be reproduced such as blue, green or pink, which are a result of the addition of boron or from irradiation after synthesis.

Another popular method of growing synthetic diamond is chemical vapor deposition (CVD). The growth occurs under low pressure (below atmospheric pressure). It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them to chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch or laser. This method is mostly used for coatings, but can also produce single crystals several millimeters in size (see picture).

At present, the annual production of gem quality synthetic diamonds is only a few thousand carats, whereas the total production of natural diamonds is around 120 million carats. Despite this fact, a purchaser is more likely to encounter a synthetic when looking for a fancy-colored diamond because nearly all synthetic diamonds are fancy-colored, while only 0.01% of natural diamonds are fancy-colored. Producing large synthetic diamonds threatens the business model of the diamond industry. The ultimate effect of the ready availability of gem-quality diamonds at low cost in the future is hard to predict.

Simulants

A diamond simulant is defined as a non-diamond material that is used to simulate the appearance of a diamond. Diamond-simulant gems are often referred to as diamante. The most familiar diamond simulant to most consumers is cubic zirconia. The popular gemstone moissanite (silicon carbide) is often treated as a diamond simulant, although it is a gemstone in its own right. While moissanite does look similar to diamond, its main disadvantage as a diamond simulant is that cubic zirconia is far cheaper and arguably equally convincing. Both cubic zirconia and moissanite are produced synthetically.

Enhancements

Diamond enhancements are specific treatments performed on natural or synthetic diamonds (usually those already cut and polished into a gem), which are designed to better the gemological characteristics of the stone in one or more ways. These include laser drilling to remove inclusions, application of sealants to fill cracks, treatments to improve a white diamond's color grade, and treatments to give fancy color to a white diamond.

Coatings are increasingly used to give a diamond simulant such as cubic zirconia a more "diamond-like" appearance. One such substance is diamond-like carbon—an amorphous carbonaceous material that has some physical properties similar to those of the diamond. Advertising suggests that such a coating would transfer some of these diamond-like properties to the coated stone, hence enhancing the diamond simulant. However, modern techniques such as Raman Spectroscopy should easily identify such as treatment.

Identification

It was stated that annealing can convert typically brown synthetically made (CVD) diamonds into colorless diamonds, and that after having sent these diamonds for diamond jewelry identification, they were not identified as different from natural diamonds. Such claims are often made for new synthetics, simulants, and treated stones, so it is important to validate how the stones were submitted for identification.

Properly trained and equipped gemologists can distinguish between natural diamonds and synthetic diamonds. They can also identify the vast majority of treated natural diamonds, two exceptions being a small minority of HPHT-treated Type II diamonds and some artificially irradiated green diamonds. "Perfect" crystals (at the atomic lattice level) have never been found, so both natural and synthetic diamonds always possess characteristic imperfections, arising from the circumstances of their crystal growth, that allow them to be distinguished from each other.

Laboratories use techniques such as spectroscopy, microscopy and luminescence under shortwave ultraviolet light to determine a diamond's origin. They also use specially made machines to aid them in the identification process. Two screening machines are the DiamondSure and the DiamondView, both produced by the DTC and marketed by the GIA.

Several methods for identifying synthetic diamonds can be performed, depending on the method of production and the color of the diamond. CVD diamonds can usually be identified by an orange fluorescence. D-J colored diamonds can be screened through the Swiss Gemmological Institute's Diamond Spotter. Stones in the D-Z color range can be examined through the DiamondSure UV/visible spectrometer, a tool developed by De Beers. Similarly, natural diamonds usually have minor imperfections and flaws, such as inclusions of foreign material, that are not seen in synthetic diamonds.

See also

• Chemical vapor deposition of diamond
• Diamond cubic
• Diamond drilling
• Emerald
• List of famous diamonds
• List of minerals
• Material properties of diamond
• Ruby
• Sapphire
• Synthetic diamond

References

1. ^ Gemological Institute of America (1995). GIA Gem Reference Guide. ISBN 0-87311-019-6.
2. H. G. Liddell and R. Scott. "Adamas". A Greek-English Lexicon. Perseus.
3. ^ Hershey, W. (1940). The Book of Diamonds. Hearthside Press New York.
4. Pliny the Elder (2004). Natural History: A Selection. Penguin Classics. p. 371. ISBN 0140444130.
5. "Chinese made first use of diamond". BBC News. 2005-05-17. Retrieved 2007-03-21.
6. ^ "Have You Ever Tried To Sell a Diamond?". Retrieved 2009-05-05. {{cite web}}: Text "publisher : The Atlantic Monthly" ignored (help)
7. Thomas, J. M. Lloyd (1991). Michael Faraday and the Royal Institution (the genius of man and place). Bristol: A. Hilger. ISBN 0-7503-0145-7.
8. Wei, L. (1993). "Thermal conductivity of isotopically modified single crystal diamond". Physical Review Letters. 70: 3764. doi:10.1103/PhysRevLett.70.3764. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
9. ^ Zaitsev, A. M. (2001). Optical Properties of Diamond : A Data Handbook. Springer. ISBN 9783540665823.
10. Radovic, L. R. (1965). Chemistry and physics of carbon: a series of advances. New York, N.Y.: Marcel Dekker. ISBN 0-8247-0987-X. {{cite book}}: More than one of |author= and |last= specified (help)
11. ^ O'Donoghue, M. (2006). Gems. Elsevier. ISBN 0-75-065856-8.
12. ^ Cordua, W. S. (1998). "The Hardness of Minerals and Rocks". Lapidary Digest. gemcutters at International Lapidary Association]. Retrieved 2007-08-19.
13. ^ E. I. Erlich and W. Dan Hausel (2002). Diamond deposits. SME. ISBN 0873352785. Retrieved 2009-06-06.
14. "Ariadne thread" (in Russian). Retrieved 2009-05-05.
15. Taylor, W. R. (1990). "Nitrogen defect aggregation of some Australasian diamonds: Time-temperature constraints on the source regions of pipe and alluvial diamonds" (PDF). American Mineralogist. 75: 1290–1310. {{cite journal}}: Unknown parameter |coauthor= ignored (|author= suggested) (help)
16. ^ Boser, U. (2008). "Diamonds on Demand". Smithsonian. 39 (3): 52–59. {{cite journal}}: Unknown parameter |month= ignored (help)
17. Holtzapffel, Ch. (1856). Turning And Mechanical Manipulation. Charles Holtzapffel.
18. Coelho, R. T. (1995). "The application of polycrystalline diamond (PCD) tool materials when drilling and reaming aluminum-based alloys including MMC". International Journal of Machine Tools & Manufacture. 35: 761–774. doi:10.1016/0890-6955(95)93044-7. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
19. Blank, V. (1998). "Ultrahard and superhard phases of fullerite C60: comparison with diamond on hardness and wear" (PDF). Diamond and Related Materials. 7: 427–431. doi:10.1016/S0925-9635(97)00232-X. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
20. Pan, Zicheng (2009). "Harder than Diamond: Superior Indentation Strength of Wurtzite BN and Lonsdaleite". Physical Review Letters. 102 (102): 055503. doi:10.1103/PhysRevLett.102.055503. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help); Unknown parameter |laydate= ignored (help); Unknown parameter |laysource= ignored (help); Unknown parameter |laysummary= ignored (help)
21. Collins, A. T. (1993). "The Optical and Electronic Properties of Semiconducting Diamond". Philosophical Transactions: Physical Sciences and Engineering. 342: 233–244. doi:10.1098/rsta.1993.0017.
22. Landstrass, M. I. (1989). "Resistivity of chemical vapor deposited diamond films". Applied Physics Letters. 55: 975–977. doi:10.1063/1.101694. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
23. Zhang, W. (2008). "Hydrogen-terminated diamond electrodes. II. Redox activity". Physical Review E. 78: 041603. doi:10.1103/PhysRevE.78.041603. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
24. Weber, M. J. (2002). Handbook of optical materials. CRC Press. p. 119. ISBN 0849335124.
25. Field, J. E. (1981). "Strength and Fracture Properties of Diamond". Philosophical Magazine A. 43 (3). Taylor and Francis Ltd: 595–618. doi:10.1080/01418618108240397.
26. Collins, A. T. (1998). "Correlation between optical absorption and EPR in high-pressure diamond grown from a nickel solvent catalyst". Diamond and Related Materials. 7: 333–338. doi:10.1016/S0925-9635(97)00270-7. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
27. Walker, J. (1979). "Optical absorption and luminescence in diamond". Reports on Progress in Physics. 42: 1605–1659. doi:10.1088/0034-4885/42/10/001.
28. Hounsome, L. S. (2006). "Origin of brown coloration in diamond". Physical Review B. 73: 125203–125211. doi:10.1103/PhysRevB.73.125203. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
29. Wise, R. W. (2001). Secrets Of The Gem Trade, The Connoisseur's Guide To Precious Gemstones. Brunswick House Press. pp. 223–224. ISBN 9780972822381.
30. Khan, U. "Blue-grey diamond belonging to King of Spain has sold for record 16.3 GBP". The Telegraph.
31. Nebehay, S. (12 May 2009). "Rare blue diamond sells for record $9.5 million". Reuters. Retrieved 13 May 2009.
32. ^ Diamonds and Diamond Grading: Lesson 4 How Diamonds Form. Gemological Institute of America,, Carlsbad, California., 2002 Cite error: The named reference "GIAGrading4" was defined multiple times with different content (see the help page).
33. M. Sevdermish and A. Mashiah (1995). The Dealer's Book of Gems and Diamonds. Kal Printing House, Israel.
34. Webster, R. (2000). Gems: Their sources, descriptions and identification (5th ed.). Great Britain: Butterworth-Heinemann. p. 17. ISBN 0-7506-1674-1. {{cite book}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
35. Garai, J. (2006). "Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado Diamonds". The Astrophysical Journal. 653 (2): L153 – L156. doi:10.1086/510451. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)
36. "Diamonds from Outer Space: Geologists Discover Origin of Earth's Mysterious Black Diamonds". National Science Foundation. 2007-01-08. Retrieved 2007-10-28.
37. "CfA Press release". Center for Astrophysics. Retrieved 2009-05-05.
38. S. Cauchi (2004-02-18). "Biggest Diamond Out of This World". Retrieved November 11. {{cite web}}: Check date values in: |accessdate= (help); Unknown parameter |accessyear= ignored (|access-date= suggested) (help); Unknown parameter |month= ignored (help)CS1 maint: date and year (link)
39. "Astronomers Discovered Lucy, the Largest Diamond, in Space". The XO Directory. Retrieved 2009-05-05.
40. Aravind Adiga (April 12, 2004). "Uncommon Brilliance - TIME". Time.com. Retrieved 2008-11-03. {{cite news}}: Text "Surat Monday, April 12, 2004" ignored (help)
41. "Jwaneng". De Beers group. Retrieved 2009-04-26.
42. ^ Tichotsky, J. (2000). Russia's diamond colony: the republic of Sakha. Routledge. p. 254. Retrieved 2009-06-06.
43. "declaring a concentration to be compatible with the common market and the EEA Agreement".
44. "Business: Changing facets; Diamonds" (PDF). The Economist. 382 (8517): 68. 2007.
45. "The elusive Sparcle". Retrieved 2009-04-26.
46. Even-Zohar, C. (2008-11-06). "Crisis Mitigation at De Beers" (PDF). DIP online. Retrieved 2009-04-26.
47. Even-Zohar, C. (1999-11-03). "De Beers to Halve Diamond Stockpile". National Jeweler. Retrieved 2009-04-26.
48. "Industrial Diamonds Statistics and Information". United States Geological Survey. Retrieved 2009-05-05.
49. ^ Karl E. Spear, John P. Dismukes (1994). Synthetic diamond: emerging CVD science and technology. Wiley-IEEE. p. 628. ISBN 0471535893.
50. M. Sakamoto; et al. (1992). "120 W CW output power from monolithic AlGaAs (800 nm) laser diode array mounted on diamond heatsink". Electronics Letters. 28 (2): 197–199. doi:10.1049/el:19920123. {{cite journal}}: Explicit use of et al. in: |author= (help)
51. ^ Yarnell, A. (2004). "The Many Facets of Man-Made Diamonds". Chemical and Engineering News. 82 (5). American Chemical Society: 26–31. ISSN 0009-2347. Retrieved 2006-10-03.
52. ^ "Conflict Diamonds". United Nations Department of Public Information. March 21, 2001. Retrieved 2009-05-05.
53. G. E. Harlow (1998). The nature of diamonds. Cambridge University Press. p. 223. ISBN 0521629357.
54. W.R. Catelle (1911). The Diamond. John Lane Company. Page 159 discussion on Alluvial diamonds in India and elsewhere as well as earliest finds
55. V. Ball (1881). Diamonds, Gold and Coal of India. London, Truebner & Co. Ball was a Geologist in British service. Chapter I, Page 1
56. Williams, Gardner (1905). The Diamond Mines of South Africa. New York: B.F. Buck & Co.
57. ^ A. J. A. Janse (2007). "Global Rough Diamond Production Since 1870". Gems and Gemology. XLIII (Summer 2007). GIA: 98–119.
58. ^ V. Lorenz (2007). "Argyle in Western Australia: The world's richest diamantiferous pipe; its past and future". Gemmologie, Zeitschrift der Deutschen Gemmologischen Gesellschaft. 56 (1/2). DGemG: 35–40.
59. "Microscopic diamond found in Montana". The Montana Standard. Retrieved 2009-05-05.
60. "Microscopic Diamond Found in Montana | LiveScience". Livescience.com. Retrieved 2008-11-03.
61. "Delta: News / Press Releases / Publications". Deltamine.com. Retrieved 2008-11-03.
62. S. Marshall and J. Shore (2004). "The Diamond Life". Retrieved 2007-03-21.
63. "Joint Resolution - World Federation of Diamond Bourses (WFDB) and International Diamond Manufacturers Association". World Diamond Council. 2000-07-19. Retrieved 2006-11-05.
64. T. Zoellner (2006). The Heartless Stone: A Journey Through the World of Diamonds, Deceit, and Desire. St. Martin's Press. ISBN 0312339690.
65. "Voluntary Code of Conduct For Authenticating Canadian Diamond Claims" (PDF). The Canadian Diamond Code Committee. 2006. Retrieved 2007-10-30.
66. B.A. Kjarsgaard and A. A. Levinson (2002). "Diamonds in Canada". Gems & Gemology. 38 (3): 208–238.
67. "Judgment of the Court of First Instance of 11 July 2007 — Alrosa v Commission". Retrieved 2009-04-26.
68. "Diamond producer Alrosa to resume market diamond sales in May". RiaNovosti. Retrieved 2009-05-25.
69. "Bourse listing". World Federation of Diamond Bourses. Retrieved 2007-04-04.
70. "North America Diamond Sales Show No Sign of Slowing". A&W diamonds. Retrieved 2009-05-05.
71. J. E. Shigley; et al. (2002). "Gemesis Laboratory Created Diamonds". Gems and Gemology. 38 (4). GIA: 301–309. {{cite journal}}: Explicit use of et al. in: |author= (help)
72. J. E. Shigley; et al. (2004). "Lab Grown Colored Diamonds from Chatham Created Gems". Gems and Gemology. 40 (2). GIA: 128–145. {{cite journal}}: Explicit use of et al. in: |author= (help)
73. M Werner; et al. (1998). "Growth and application of undoped and doped diamond films". Rep. Prog. Phys. 61: 1665. doi:10.1088/0034-4885/61/12/002. {{cite journal}}: Explicit use of et al. in: |author= (help)
74. M. O'Donoghue and L. Joyner (2003). Identification of gemstones. Great Britain: Butterworth-Heinemann. pp. 12–19. ISBN 0-7506-5512-7.
75. J. E. Shigley (2007). "Observations on new coated gemstones". Gemmologie: Zeitschrift der Deutschen Gemmologischen Gesellschaft. 56 (1/2). DGemG: 53–56. {{cite journal}}: Unknown parameter |month= ignored (help)
76. "New Process Promises Bigger, Better Diamond Crystals". Carnegie Institution for Science. Retrieved 2009-05-11.
77. ^ C. Welbourn (2006). "Identification of Synthetic Diamonds: Present Status and Future Developments/Proceedings of the 4th International Gemological Symposium". Gems and Gemology. 42 (3). GIA: 34–35.
78. "DTC Appoints GIA Distributor of DiamondSure and DiamondView". BOND Communications. Retrieved 2009-03-02.
79. "SSEF diamond spotter™ and SSEF illuminator™". Lilach diamond equipment. Retrieved 2009-05-05.

Books

• Chaim Evevn-Zohar (2007). "From Mine to Mistress - Corporate Strategies and Government Policies in the International Diamond Industry" (Second edition of the book on the world diamond industry) Mining Journal Press.
• M. O'Donoghue (2006). Gems. Elsevier. ISBN 0-75-065856-8.
• G. Davies (1994). Properties and growth of diamond. INSPEC.
• O'Donoghue, Michael, and Joyner, Louise (2003). Identification of gemstones. Great Britain: Butterworth-Heinemann. pp. 12–19. ISBN 0-7506-5512-7.{{cite book}}: CS1 maint: multiple names: authors list (link)
• A. Feldman and L. H. Robins (1991). Applications of Diamond Films and Related Materials. Elsevier Sci.
• J.E. Field (1979). The Properties of Diamond. London: Academic Press.
• J.E. Field (1992). The Properties of Natural and Synthetic Diamond. London: Academic Press.
• W. Hershey (1940). The Book of Diamonds. Hearthside Press New York.
• S. Koizumi, C. E. Nebel and M. Nesladek (2008). Physics and Applications of CVD Diamond. Wiley VCH. ISBN 3527408010.
• L.S. Pan and D.R. Kania (1995). Diamond: Electronic Properties and Applications. Kluwer Academic Publishers.
• Pagel - Theisen, Verena. Diamond Grading ABC: the Manual Rubin & Son, Antwerp, Belgium, 2001. ISBN 3-9800434-6-0
• Radovic, Ljubisa R.; Walker, Philip M.; Thrower, Peter A. (1965). Chemistry and physics of carbon: a series of advances. New York, N.Y.: Marcel Dekker. ISBN 0-8247-0987-X.{{cite book}}: CS1 maint: multiple names: authors list (link)
• Tolkowsky, Marcel (1919). Diamond Design: A Study of the Reflection and Refraction of Light in a Diamond. London: E. & F.N. Spon, Ltd. (Web edition as edited by Jasper Paulsen, Seattle, 2001)
• Wise, Richard W. "Secrets Of The Gem Trade, The Connoisseur's Guide To Precious Gemstones". (2003) Brunswick House Press. Website of book: Secrets of the Gem Trade
• A. M. Zaitsev (2001). Optical Properties of Diamond : A Data Handbook. Springer.

External links

• Properties of diamond: Ioffe database
• Interactive structure of bulk diamond (Java applet)
• PBS Nature: Diamonds
• Smithsonian's Splendour of Diamonds exhibit
• Epstein, Edward Jay (1982). The diamond invention (Complete book, includes "Chapter 20: Have you ever tried to sell a diamond?" )
• GIA "A Contribution to the Understanding of Blue Fluorescence on the Appearance of Diamonds". (2007) GIA
• Tyson, Peter (November 2000). "Diamonds in the Sky". Retrieved March 10, 2005.

Template:Jewellery Materials

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• Diamond
• Native element minerals
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