CataCXium F sulf: Difference between revisions

Browse history interactively ← Previous edit Next edit →Content deleted Content addedVisual WikitextInline

Revision as of 14:31, 30 August 2011 edit144.32.196.109 (talk) →References: Removed the reference to the Pschierer/Plenio paper as it has been retracted← Previous edit		Revision as of 14:42, 30 August 2011 edit undoCheMoBot (talk \| contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'ChemSpiderID_Ref', 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEBI_Ref') per [[WP:CHEMVALID\|Chem/Drugbox validationNext edit →
Line 2:		Line 2:

	{{chembox		{{chembox
	\| verifiedrevid = ~~409101109~~		\| verifiedrevid = 428759792
	\| ImageFile = CatFsulf.png		\| ImageFile = CatFsulf.png
	\| ImageSize = 200px		\| ImageSize = 200px

Revision as of 14:42, 30 August 2011

This article is an orphan, as no other articles link to it. Please introduce links to this page from related articles; try the Find link tool for suggestions. (August 2009)

{{chembox | verifiedrevid = 428759792 | ImageFile = CatFsulf.png | ImageSize = 200px | IUPACName = Dicyclohexyl-{9--2-sulfonylfluoren-9-yl}phosphonium hydrogensulfate | OtherNames = CataCXium F sulf | Section1 = ! colspan=2 style="background: #f8eaba; text-align: center;" |Identifiers

| ECHA InfoCard | 100.221.684 |-

CompTox Dashboard (EPA)

DTXSID30647780

| Section2 = ! colspan=2 style="background: #f8eaba; text-align: center;" |Properties

Chemical formula

| C₃₄H₄₃O₁₀PS₃

|- | Molar mass

| 738.87 g/mol

|- | Appearance | pale yellow solid |-

| Solubility | soluble in water |- | Section3 = }}

CataCXium F sulf is a water-soluble organophosphorus compound derived from fluorene. The palladium complexes of the respective phosphine show an excellent activity in various palladium catalyzed cross coupling reactions, including Suzuki reactions, Sonogashira couplings and Buchwald-Hartwig reactions.

References

C.A. Fleckenstein; H. Plenio, Highly efficient Suzuki-Miyaura coupling of heterocyclic substrates through rational reaction design. Chemistry-A European Journal 2008, 14(14), 4267-4279.

C.A. Fleckenstein; H. Plenio, Aqueous/organic cross coupling: Sustainable protocol for Sonogashira reactions of heterocycles. Green Chemistry 2008, 10, 563-570.

C.A. Fleckenstein; H. Plenio, Efficient Suzuki-Miyaura Coupling of (Hetero)aryl Chlorides with Thiophene- and Furanboronic Acids in Aqueous n-Butanol. Journal of Organic Chemistry 2008, 73, 3236-3244.

C.A Fleckenstein; R. Kadyrov; H. Plenio, Efficient Large-Scale Synthesis of 9-Alkylfluorenyl Phosphines for Pd-Catalyzed Cross-Coupling Reactions. Organic Process Research & Development 2008, 12, 475-479.

C.A. Fleckenstein; H. Plenio, Aqueous cross-coupling. Highly efficient Suzuki-Miyaura coupling of N-heteroaryl halides and N-heteroarylboronic acids. Green Chemistry 2007, 9, 1287-1291.

External links

Categories: