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'''Dimethenamid''' is a widely used ]. In 2001, about 7 million pounds of dimethenamid were used in the United States.<ref>, ]</ref> '''Dimethenamid''' is a widely used ]. In 2001, about 7 million pounds of dimethenamid were used in the United States.<ref>, ]</ref> Dimethenamid is registered for control of annual grasses, certain annual broadleaf weeds and sedges in field corn, seed corn, popcorn and soybeans. Supplemental labeling also allows use on sweet corn,
grain sorghum, dry beans and peanuts. In registering dimethinamide (SAN 582H/Frontier), EPA concluded that the primary means of dissipation of dimethinamide applied to the soil surface is photolysis, whereas below the surface loss was due largely to microbial metabolism. The herbicide was found to undergo anaerobic microbial degradation under denitrifying, iron-reducing, sulfate-reducing, or methanogenic conditions. In that study, more than half of the herbicide carbon (based on 14C-labeling) added was found to be incorporated irreversibly into soil-bound residue.




==References== ==References==

Revision as of 20:35, 28 May 2013

Dimethenamid
Names
IUPAC name (RS)-2-Chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide
Other names Frontier Herbicide
Dimethenamid-P ((S)-isomer)
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.121.887 Edit this at Wikidata
KEGG
PubChem CID
RTECS number
  • AB5444200
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3Key: JLYFCTQDENRSOL-UHFFFAOYSA-N
  • InChI=1/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3Key: JLYFCTQDENRSOL-UHFFFAOYAR
SMILES
  • CC1=CSC(=C1N(C(C)COC)C(=O)CCl)C
  • ClCC(=O)N(c1c(scc1C)C)C(COC)C
Properties
Chemical formula C12H18ClNO2S
Molar mass 275.79 g/mol
Appearance Tan to brown liquid
Density 1.141 g/cm
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Xn (harmful)
Flash point 151 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Dimethenamid is a widely used herbicide. In 2001, about 7 million pounds of dimethenamid were used in the United States. Dimethenamid is registered for control of annual grasses, certain annual broadleaf weeds and sedges in field corn, seed corn, popcorn and soybeans. Supplemental labeling also allows use on sweet corn, grain sorghum, dry beans and peanuts. In registering dimethinamide (SAN 582H/Frontier), EPA concluded that the primary means of dissipation of dimethinamide applied to the soil surface is photolysis, whereas below the surface loss was due largely to microbial metabolism. The herbicide was found to undergo anaerobic microbial degradation under denitrifying, iron-reducing, sulfate-reducing, or methanogenic conditions. In that study, more than half of the herbicide carbon (based on 14C-labeling) added was found to be incorporated irreversibly into soil-bound residue.


References

  1. Dimethenamid at Sigma-Aldrich
  2. Material Safety Data Sheet from BASF
  3. Dimethenamid at AlanWood.net
  4. 2000-2001 Pesticide Market Estimates, U.S. Environmental Protection Agency
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