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Dimethyl carbate: Difference between revisions

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	'''Dimethyl carbate''' is an ].<ref>{{cite web \| url = http://www.alanwood.net/pesticides/dimethyl%20carbate.html \| title = Dimethyl carbate \| publisher = AlanWood.net}}</ref> It can be prepared by the ] of ] and ].<ref>{{cite journal \| title = Aluminum chloride catalyzed diene condensation. II. Stronger adherence to the Alder endo rule \| author = Inukai, Takashi; Kojima, Takeshi \| journal = Journal of Organic Chemistry \| year = 1966 \| volume = 31 \| pages = 2032–2033 \| issn = 6}}</ref>		'''Dimethyl carbate''' is an ].<ref>{{cite web \| url = http://www.alanwood.net/pesticides/dimethyl%20carbate.html \| title = Dimethyl carbate \| publisher = AlanWood.net}}</ref> It can be prepared by the ] of ] and ].<ref>{{cite journal \| title = Aluminum chloride catalyzed diene condensation. II. Stronger adherence to the Alder endo rule \| author = Inukai, Takashi; Kojima, Takeshi \| journal = Journal of Organic Chemistry \| year = 1966 \| volume = 31 \| pages = 2032–2033 \| issn = 0022-3263}}</ref>

	==References==		==References==

Revision as of 06:08, 17 November 2013

Not to be confused with Dimethyl carbonate.

Dimethyl carbate
Names

IUPAC name Dimethyl (1R,2S,3R,4S)-bicyclohept-5-ene-2,3-dicarboxylate
Other names Dimethyl cis-5-norbornene-2,3-dicarboxylate ; Dimalone
Identifiers
CAS Number	39589-98-5
3D model (JSmol)	Interactive image
ChemSpider	10430159
CompTox Dashboard (EPA)	DTXSID701032069
InChI InChI=1S/C11H14O4/c1-14-10(12)8-6-3-4-7(5-6)9(8)11(13)15-2/h3-4,6-9H,5H2,1-2H3/t6-,7+,8-,9+Key: VGQLNJWOULYVFV-SPJNRGJMSA-N InChI=1/C11H14O4/c1-14-10(12)8-6-3-4-7(5-6)9(8)11(13)15-2/h3-4,6-9H,5H2,1-2H3/t6-,7+,8-,9+Key: VGQLNJWOULYVFV-SPJNRGJMBT
SMILES O=C(OC)2(C(=O)OC)\1C2/C=C/1
Properties
Chemical formula	C₁₁H₁₄O₄
Molar mass	210.229 g·mol
Density	1.4852 g/cm
Melting point	38 °C (100 °F; 311 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Chemical compound

Dimethyl carbate is an insect repellent. It can be prepared by the Diels–Alder reaction of dimethyl maleate and cyclopentadiene.

References

^ Merck Index, 11th Edition, 3230
"Dimethyl carbate". AlanWood.net.
Inukai, Takashi; Kojima, Takeshi (1966). "Aluminum chloride catalyzed diene condensation. II. Stronger adherence to the Alder endo rule". Journal of Organic Chemistry. 31: 2032–2033. ISSN 0022-3263.{{cite journal}}: CS1 maint: multiple names: authors list (link)

External links

Dimethyl carbate, PAN Pesticides Database

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