Dimethenamid: Difference between revisions

Browse history interactively ← Previous edit Next edit →Content deleted Content addedVisual WikitextInline

Revision as of 21:16, 1 November 2015 editDePiep (talk \| contribs)Extended confirmed users294,285 editsm Chembox: unknown parameters: fix spelling, replace or remove. See also full parameter list (via AWB script)← Previous edit		Revision as of 15:05, 2 February 2016 edit undoEdgar181 (talk \| contribs)Extended confirmed users196,325 edits removed Category:Amides; added Category:Carboxamides using HotCat Next edit →
Line 55:		Line 55:
	]		]
	]		]
	]		]
	]		]
	]		]

Revision as of 15:05, 2 February 2016

Dimethenamid
Names

IUPAC name (RS)-2-Chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide
Other names Frontier Herbicide Dimethenamid-P ((S)-isomer)
Identifiers
CAS Number	87674-68-8
3D model (JSmol)	Interactive image Interactive image
ChEBI	CHEBI:81789
ChemSpider	82842
ECHA InfoCard	100.121.887
KEGG	C18499
PubChem CID	91744
RTECS number	AB5444200
CompTox Dashboard (EPA)	DTXSID4032376
InChI InChI=1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3Key: JLYFCTQDENRSOL-UHFFFAOYSA-N InChI=1/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3Key: JLYFCTQDENRSOL-UHFFFAOYAR
SMILES CC1=CSC(=C1N(C(C)COC)C(=O)CCl)C ClCC(=O)N(c1c(scc1C)C)C(COC)C
Properties
Chemical formula	C₁₂H₁₈ClNO₂S
Molar mass	275.79 g/mol
Appearance	Tan to brown liquid
Density	1.141 g/cm
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Xn (harmful)
Flash point	151 °C (304 °F; 424 K)
Safety data sheet (SDS)	MSDS from BASF
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). N verify (what is ?) Infobox references

Chemical compound

Dimethenamid is a widely used herbicide. In 2001, about 7 million pounds of dimethenamid were used in the United States. Dimethenamid is registered for control of annual grasses, certain annual broadleaf weeds and sedges in field corn, seed corn, popcorn and soybeans. Supplemental labeling also allows use on sweet corn, grain sorghum, dry beans and peanuts. In registering dimethinamide (SAN 582H/Frontier), EPA concluded that the primary means of dissipation of dimethenamid applied to the soil surface is photolysis, whereas below the surface loss was due largely to microbial metabolism. The herbicide was found to undergo anaerobic microbial degradation under denitrifying, iron-reducing, sulfate-reducing, or methanogenic conditions. In that study, more than half of the herbicide carbon (based on 14C-labeling) added was found to be incorporated irreversibly into soil-bound residue.

References

Dimethenamid at Sigma-Aldrich
Material Safety Data Sheet from BASF
Dimethenamid at AlanWood.net
2000-2001 Pesticide Market Estimates, U.S. Environmental Protection Agency
Crawford, J.J.; Sims, G. K.; Simmons, F. W.; Wax, L. M.; Freedman, D. L. (2002). "Dissipation of the herbicide (14C) Dimethenamid under anaerobic aquatic conditions in flooded soil microcosms". J. Agric. Food. Chem. 50 (6): 61483–1491. doi:10.1021/jf010612i. Retrieved 2015-01-18.

Pest control: herbicides

FOP herbicides	chlorazifop cyhalofop diclofop fenoxaprop fluazifop haloxyfop quizalofop
DIM herbicides	sethoxydim

Protox inhibitors

Nitrophenyl ethers	acifluorfen bifenox fluorodifen fomesafen lactofen nitrofen oxyfluorfen
Pyrimidinediones	butafenacil saflufenacil
Triazolinones	carfentrazone sulfentrazone

Pyridines

Quaternary

Photosystem I inhibitors	cyperquat diquat paraquat

Triazines

Photosystem II inhibitors	ametryn atrazine cyanazine hexazinone prometon prometryn propazine simazine simetryn terbuthylazine terbutryn metamitron

Ureas

Photosystem II inhibitors	chlortoluron DCMU difenoxuron isoproturon linuron monuron monolinuron tebuthiuron
ALS inhibitors	chlorsulfuron flazasulfuron metsulfuron-methyl sulfometuron methyl tribenuron

Others

This article about an organic compound is a stub. You can help Misplaced Pages by expanding it.

Categories: