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'''Tetracyclopropylmethane''' is an ], a ] ] with formula C<sub>13</sub>H<sub>20</sub>, or (C<sub>3</sub>H<sub>5</sub>-)<sub>4</sub>C. The ] skeleton of its molecule consists of four ] rings attached to a central carbon atom. | '''Tetracyclopropylmethane''' is an ], a ] ] with formula C<sub>13</sub>H<sub>20</sub>, or (C<sub>3</sub>H<sub>5</sub>-)<sub>4</sub>C. The ] skeleton of its molecule consists of four ] rings attached to a central carbon atom. | ||
This compound was synthesized in 2001 by ] and others, with ] as an intermediate step.<ref>{{cite journal | doi = 10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K | |
This compound was synthesized in 2001 by ] and others, with ] as an intermediate step.<ref>{{cite journal | doi = 10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K |author1=Kozhushkov, Sergei I. |author2=Kostikov, Rafael R. |author3=Molchanov, Alexander P. |author4=Boese, Roland |author5=Benet-Buchholz, Jordi |author6=Schreiner, Peter R. |author7=Rinderspacher, Christopher |author8=Ghiviriga, Ion |author9=De Meijere, Armin. | title = Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry | journal = Angewandte Chemie International Edition | year = 2001 | volume = 40 | issue = 1 | pages = 180–183}}</ref> In the solid state, the molecules have a propeller shape with S4 symmetry. | ||
==References== | ==References== |
Revision as of 03:22, 6 June 2016
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Names | |
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IUPAC name Tetracyclopropylmethane | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
CompTox Dashboard (EPA) | |
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Properties | |
Chemical formula | C13H20 |
Molar mass | 176.303 g·mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Y verify (what is ?) Infobox references |
Tetracyclopropylmethane is an organic compound, a polycyclic hydrocarbon with formula C13H20, or (C3H5-)4C. The carbon skeleton of its molecule consists of four cyclopropane rings attached to a central carbon atom.
This compound was synthesized in 2001 by Armin de Meijere and others, with dicyclopropyldiethenylmethane as an intermediate step. In the solid state, the molecules have a propeller shape with S4 symmetry.
References
- Kozhushkov, Sergei I.; Kostikov, Rafael R.; Molchanov, Alexander P.; Boese, Roland; Benet-Buchholz, Jordi; Schreiner, Peter R.; Rinderspacher, Christopher; Ghiviriga, Ion; De Meijere, Armin. (2001). "Tetracyclopropylmethane: a unique hydrocarbon with S4 symmetry". Angewandte Chemie International Edition. 40 (1): 180–183. doi:10.1002/1521-3773(20010105)40:1<180::AID-ANIE180>3.0.CO;2-K.
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