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Titanium tetraazide

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Titanium tetraazide
Names
IUPAC name Titanium(IV) tetraazide
Other names Titanium tetraazide
Identifiers
3D model (JSmol)
PubChem CID
InChI
  • InChI=1S/4N3.Ti/c4*1-3-2;/q4*-1;+4Key: UBKFNPJMWUJHGB-UHFFFAOYSA-N
SMILES
  • ==.==.==.==.
Properties
Chemical formula Ti(N3)4
Molar mass 215.95 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Titanium tetraazide is an inorganic chemical compound with the formula Ti(N3)4. It is a highly sensitive explosive, and has been prepared via titanium tetrafluoride and trimethylsilyl azide, and the corresponding fluoride-azide exchange.

Properties

Titanium tetraazide has been characterized by vibrational spectroscopy and single-crystal X-ray diffraction. The compound was predicted to be vibrationally stable, and was expected to have a tetrahedral structures containing linear bond angles, contrasting other metal azides which generally feature bent bond angles. After synthesis though, the resulting titanium tetraazide did not linear bond angles, as the coordination numbers exceeded 4.

References

  1. Saal, Thomas; Deokar, Piyush; Christe, Karl O.; Haiges, Ralf (4 April 2019). "The Binary Group 4 Azide Adducts [(bpy)Ti(N3)4], [(phen)Ti(N3)4], [(bpy)2Zr(N3)4]2·bpy, and [(bpy)2Hf(N3)4]2·bpy". Eur. J. Inorg. Chem.: 2388–2391. doi:10.1002/ejic.201900334. Retrieved 5 January 2025.
  2. Haiges, Ralf; Boatz, Jerry A.; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. (12 March 2004). "reparation and Characterization of the First Binary Titanium Azides, Ti(N3 )4 , [P(C6H5 )4 ][Ti(N3 )5 ] and [P(C6H5 )4 ]2 [Ti(N3 )6 ] and on Linear Ti-N-NN Coordination" (PDF). Defense Technical Information Center. Retrieved 5 January 2025.
Titanium compounds
Titanium(II)
Organotitanium(II) compounds
Titanium(III)
Organotitanium(III) compounds2
Titanium(IV)
Titanate compounds
Organotitanium(IV) compounds
Salts and covalent derivatives of the azide ion
HN3 He
LiN3 Be(N3)2 B(N3)3 CH3N3
C(N3)4
CO(N3)2 		NH4N3
N3NO
N(N3)3
H2N–N3 		O FN3 Ne
NaN3 Mg(N3)2 Al(N3)3 Si(N3)4 P SO2(N3)2 ClN3 Ar
KN3 Ca(N3)2 Sc(N3)3 Ti(N3)4 VO(N3)3 Cr(N3)3
CrO2(N3)2 		Mn(N3)2 Fe(N3)2
Fe(N3)3 		Co(N3)2
Co(N3)3 		Ni(N3)2 CuN3
Cu(N3)2 		Zn(N3)2 Ga(N3)3 Ge As(N3)5 Se(N3)4 BrN3 Kr
RbN3 Sr(N3)2 Y(N3)3 Zr(N3)4 Nb Mo Tc Ru(N3)6 Rh(N3)6 Pd(N3)2 AgN3 Cd(N3)2 In Sn Sb(N3)5 Te(N3)4 IN3 Xe(N3)2
CsN3 Ba(N3)2 * Lu(N3)3 Hf Ta W Re Os Ir(N3)6 Pt(N3)6 Au(N3)4 Hg2(N3)2
Hg(N3)2 		TlN3 Pb(N3)2 Bi(N3)3 Po At Rn
Fr Ra(N3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(N3)3 Ce(N3)3
Ce(N3)4 		Pr Nd Pm Sm(N3)3 Eu(N3)2
Eu(N3)3 		Gd(N3)3 Tb Dy(N3)3 Ho(N3)3 Er Tm Yb(N3)3
** Ac(N3)3 Th(N3)4 Pa UO2(N3)2 Np Pu Am Cm Bk Cf Es Fm Md No
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