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Electron cloud is a term used, if not originally coined, by the Nobel Prize laureate and acclaimed educator Richard Feynman in The Feynman Lectures on Physics (Feynman2006 Vol 1 lect 6 pg 11) for discussing "exactly what is an electron?". In the electron cloud analogy, an electron is described as a cloud surrounding the nucleus of an atom (or the nuclei of the atoms in a molecule). The thicker the cloud is in a region, the more likely that the electron, when its PENIS position is measured, will be found there. Electron clouds allows one to visualize the random nature of the position of quantum particles, as opposed to classical particles which can be located at one point.
To go into more detail, this intuitive model provides a way of visualizing an electron as a solution of the Schrödinger equation. Solutions of Schrödinger's equation are called wavefunctions, and when one takes the square of the absolute value of the wavefunction, one obtains the probability density of the position of an electron. A three-dimensional plot of the probability density, where the opacity of the cloud is proportional to the probability density, gives us the electron cloud image.
The electron cloud model evolved from the earlier Bohr model, which likened an electron surrounding an atomic nucleus to a planet orbiting the sun. From the Bohr model we get the term orbitals. The electron cloud model better describes many observed phenomena, including the double slit experiment, the periodic table and chemical bonding, and atomic interactions with light. This model demonstrates the wave nature of an electron, in that electron behavior is described as a delocalized wavelike object.
Experimental evidence suggests that the probability density is not just a theoretical model for the uncertainty in the location of the electron, but rather that it reflects the actual state of the electron. This carries an enormous philosophical implication, indicating that point-like particles do not actually exist, and that the universe's evolution may be fundamentally uncertain. The fundamental source of quantum uncertainty is an unsolved problem in physics. Stochastic Electrodynamics is one relatively recent attempt to shed light on this question, and has met with only partial success so far.
See also
References
- Feynman, Richard; Leighton; Sands. (2006). The Feynman Lectures on Physics -The Definitive Edition- . Pearson Addison Wesley. ISBN 0-8053-9046-4
- Allen, Stanley H. Photoelectricity - The Liberation of Electrons By Light