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Thorium(IV) fluoride

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Thorium(IV) fluoride
Thorium(IV) fluoride Thorium tetrafluoride
Identifiers
CAS Number
ECHA InfoCard 100.033.857 Edit this at Wikidata
CompTox Dashboard (EPA)
Properties
Chemical formula ThF4
Molar mass 308.03 g/mol
Appearance hygroscopic white crystals
Density 6.3 g/cm
Melting point 1110 °C
Boiling point 1680 °C
Refractive index (nD) 1.45
Structure
Crystal structure Monoclinic, mS60
Space group C12/c1, No. 15
Hazards
Flash point Non-flammable
Related compounds
Other anions Thorium(IV) chloride
Thorium(IV) bromide
Thorium(IV) iodide
Other cations Protactinium(IV) fluoride
Uranium(IV) fluoride
Neptunium(IV) fluoride
Plutonium(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Thorium(IV) fluoride (ThF4) is an inorganic chemical compound. It is a white, hygroscopic powder which can be produced by reacting thorium with fluorine gas. At temperatures above 500 °C, it reacts with atmospheric moisture to produce ThOF2.

Uses

Despite its (mild) radioactivity, thorium fluoride is used as an antireflection material in multilayered optical coatings. It has excellent optical transparency in the range 0.35–12 µm, and its radiation is primarily due to alpha particles, which can be easily stopped by a thin cover layer of another material.

Thorium fluoride was used in manufacturing carbon arc lamps, which provided high-intensity illumination for movie projectors and search lights.

References

  1. Dale L. Perry, Sidney L. Phillips (1995). Handbook of inorganic compounds. CRC Press. p. 412. ISBN 0849386713.
  2. Rancourt, James D. (1996). Optical thin films: user handbook. SPIE Press. p. 196. ISBN 0819422851.
  3. W. Heitmann and E. Ritter (1968). "Production and properties of vacuum evaporated films of thorium fluoride". Appl. Opt. 7 (2): 307. doi:10.1364/AO.7.000307. PMID 20062461.
  4. McKetta, John J. (1996). Encyclopedia of Chemical Processing and Design: Thermoplastics to Trays, Separation, Useful Capacity. CRC Press. p. 81. ISBN 082472609X.


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