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Copper(I) thiophene-2-carboxylate

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Revision as of 15:03, 30 November 2010 by CheMoBot (talk | contribs) (Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi)(diff) ← Previous revision | Latest revision (diff) | Newer revision → (diff) "CuTC" redirects here. For other uses, see CUTC (disambiguation).
Copper(I) thiophene-2-carboxylate
Names
IUPAC name Copper(I) thiophene-2-carboxylate
Other names CuTC
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.161.358 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1Key: SFJMFSWCBVEHBA-UHFFFAOYSA-M
  • InChI=1/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1Key: SFJMFSWCBVEHBA-REWHXWOFAY
SMILES
  • O=C()C1=CC=CS1.
  • .C(=O)c1sccc1
Properties
Chemical formula C5H3CuO2S
Molar mass 190.68 g·mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Irritant (Xi)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Copper(I)-thiophene-2-carboxylate or CuTC is a thiophene and a reagent in organic chemistry that especially promotes the Ullmann reaction between aryl halides.


CuTC catalyzed Ullmann coupling
CuTC catalyzed Ullmann coupling

References

  1. Copper(I) thiophene-2-carboxylate at Sigma-Aldrich
  2. Jwanro Hassan, Marc Sévignon, Christel Gozzi, Emmanuelle Schulz, and Marc Lemaire (2002). "Aryl-Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction" (PDF). Chem. Rev. 102 (5): 1359–1470. doi:10.1021/cr000664r. PMID 11996540.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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