This is an old revision of this page, as edited by CheMoBot (talk | contribs) at 14:42, 30 August 2011 (Updating {{chembox}} (no changed fields - added verified revid - updated 'ChemSpiderID_Ref', 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEBI_Ref') per [[WP:CHEMVALID|Chem/Drugbox validation). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.
Revision as of 14:42, 30 August 2011 by CheMoBot (talk | contribs) (Updating {{chembox}} (no changed fields - added verified revid - updated 'ChemSpiderID_Ref', 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEBI_Ref') per [[WP:CHEMVALID|Chem/Drugbox validation)(diff) ← Previous revision | Latest revision (diff) | Newer revision → (diff) | This article is an orphan, as no other articles link to it. Please introduce links to this page from related articles; try the Find link tool for suggestions. (August 2009) |
{{chembox | verifiedrevid = 428759792 | ImageFile = CatFsulf.png | ImageSize = 200px | IUPACName = Dicyclohexyl-{9--2-sulfonylfluoren-9-yl}phosphonium hydrogensulfate | OtherNames = CataCXium F sulf | Section1 = ! colspan=2 style="background: #f8eaba; text-align: center;" |Identifiers
|-
| ECHA InfoCard
| 100.221.684 
|-
|
CompTox Dashboard (EPA)|
|-
| Section2 = ! colspan=2 style="background: #f8eaba; text-align: center;" |Properties
|-
|
Chemical formula| C34H43O10PS3
|- | Molar mass
| 738.87 g/mol
|- | Appearance | pale yellow solid |-
| Solubility
| soluble in water
|-
| Section3 =
}}
CataCXium F sulf is a water-soluble organophosphorus compound derived from fluorene. The palladium complexes of the respective phosphine show an excellent activity in various palladium catalyzed cross coupling reactions, including Suzuki reactions, Sonogashira couplings and Buchwald-Hartwig reactions.
References
- C.A. Fleckenstein; H. Plenio, Highly efficient Suzuki-Miyaura coupling of heterocyclic substrates through rational reaction design. Chemistry-A European Journal 2008, 14(14), 4267-4279.
- C.A. Fleckenstein; H. Plenio, Aqueous/organic cross coupling: Sustainable protocol for Sonogashira reactions of heterocycles. Green Chemistry 2008, 10, 563-570.
- C.A. Fleckenstein; H. Plenio, Efficient Suzuki-Miyaura Coupling of (Hetero)aryl Chlorides with Thiophene- and Furanboronic Acids in Aqueous n-Butanol. Journal of Organic Chemistry 2008, 73, 3236-3244.
- C.A Fleckenstein; R. Kadyrov; H. Plenio, Efficient Large-Scale Synthesis of 9-Alkylfluorenyl Phosphines for Pd-Catalyzed Cross-Coupling Reactions. Organic Process Research & Development 2008, 12, 475-479.
- C.A. Fleckenstein; H. Plenio, Aqueous cross-coupling. Highly efficient Suzuki-Miyaura coupling of N-heteroaryl halides and N-heteroarylboronic acids. Green Chemistry 2007, 9, 1287-1291.