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Systematic IUPAC name 1,4,7,10,13-Pentaoxacyclopentadecane | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
Beilstein Reference | 1618144 |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.046.694 |
EC Number |
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Gmelin Reference | 3897 |
MeSH | 15-Crown-5 |
PubChem CID | |
RTECS number |
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CompTox Dashboard (EPA) | |
InChI
| |
SMILES
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Properties | |
Chemical formula | C10H20O5 |
Molar mass | 220.265 g·mol |
Appearance | Transparent liquid |
Density | 1.113 g cm (at 20 °C) |
Boiling point | 116 °C (241 °F; 389 K) |
log P | -0.639 |
Refractive index (nD) | 1.465 |
Thermochemistry | |
Std enthalpy of formation (ΔfH298) |
-881.1--877.1 kJ mol |
Std enthalpy of combustion (ΔcH298) |
-5.9157--5.9129 MJ mol |
Hazards | |
GHS labelling: | |
Pictograms | |
Signal word | Warning |
Hazard statements | H302, H315, H319 |
Precautionary statements | P305+P351+P338 |
NFPA 704 (fire diamond) | 2 1 0 |
Flash point | 113 °C |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). N verify (what is ?) Infobox references |
15-Crown-5 is a crown ether with the formula C10H20O5. It is a cyclic pentamer of ethylene oxide that has been shown to complex with various cations, including sodium (Na) and potassium (K), but selective binding to lead (Pb).
As a functional group, research has been conducted to probe its application in liquid crystalline studies, ion-selective membranes, chromo- and fluoroionophores.
See also
References
- "15-crown-5 - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 11 October 2011.
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Takeda, Y.; et al. (1998). "A Conductance Study of 1:1 Complexes of 15-Crown-5, 16-Crown-5, and Benzo-15-crown-5 with Alkali Metal Ions in Nonaqueous Solvents". Bulletin of the Chemical Society of Japan. 61 (3): 627–632.
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Chen, Chun-Yen; et al. (2006). "Potassium ion recognition by 15-crown-5 functionalized CdSe/ZnS quantum dots in H2O". Chem. Comm. (3): 263–265. doi:10.1039/B512677K.
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(help) - "Mesogenic Properties of 15-Crown-5-Ether - Derivatives" (PDF). Retrieved 2008-11-19.
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Klok, H.A.; et al. (1997). "Novel benzo-15-crown-5 functionalized α-olefin/CO terpolymers for membrane applications". Macromolecular Chemistry and Physics. 198 (9): 2759–2768. doi:10.1002/macp.1997.021980908.
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Fedorova, O.A.; et al. (2005). "Facile synthesis of novel styryl ligands containing a 15-crown-5 ether moiety". Arkivoc. xv: 12–24.
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External links
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