| Revision as of 16:46, 16 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 448284002 of page 1-Tetradecanol for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 14:41, 6 February 2022 edit Smokefoot (talk | contribs)Autopatrolled, Extended confirmed users, Pending changes reviewers, Rollbackers74,602 edits LD50 |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{Chembox |
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{{Chembox |
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| Verifiedfields = changed |
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| verifiedrevid = 413094121 |
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| verifiedrevid = 477208632 |
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| Reference=<ref>'']'', 12th Edition, '''6418'''.</ref> |
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| Reference=<ref>'']'', 12th Edition, '''6418'''.</ref> |
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| Name = 1-Tetradecanol |
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| Name = 1-Tetradecanol |
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| ImageSize1 = 220px |
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| ImageSize1 = 220px |
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| ImageName1 = Space-filling model |
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| ImageName1 = Space-filling model |
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| IUPACName = Tetradecan-1-ol |
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| PIN = Tetradecan-1-ol |
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| OtherNames = Myristyl alcohol<br />Tetradecyl alcohol |
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| OtherNames = Myristyl alcohol<br />Tetradecyl alcohol |
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| Section1 = {{Chembox Identifiers |
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| Section1 = {{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo = 112-72-1 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 7917 |
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| ChemSpiderID = 7917 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| ChEBI_Ref = {{ebicite|correct|EBI}} |
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| UNII = V42034O9PU |
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| ChEBI = 77417 |
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| ChEMBL_Ref = {{ebicite|correct|EBI}} |
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| ChEMBL = 24022 |
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| EINECS = 204-000-3 |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| KEGG = D05097 |
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| KEGG = D05097 |
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| PubChem = 8209 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = V42034O9PU |
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| InChI = 1/C14H30O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h15H,2-14H2,1H3 |
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| InChI = 1/C14H30O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h15H,2-14H2,1H3 |
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| InChIKey = HLZKNKRTKFSKGZ-UHFFFAOYAP |
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| InChIKey = HLZKNKRTKFSKGZ-UHFFFAOYAP |
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| ChEMBL_Ref = {{ebicite|correct|EBI}} |
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| ChEMBL = 24022 |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/C14H30O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h15H,2-14H2,1H3 |
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| StdInChI = 1S/C14H30O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h15H,2-14H2,1H3 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = HLZKNKRTKFSKGZ-UHFFFAOYSA-N |
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| StdInChIKey = HLZKNKRTKFSKGZ-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo = 112-72-1 |
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| SMILES = OCCCCCCCCCCCCCC |
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| SMILES = OCCCCCCCCCCCCCC |
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}} |
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| Section2 = {{Chembox Properties |
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| Section2 = {{Chembox Properties |
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| C=14 | H = 30 | O = 1 |
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| C=14 | H = 30 | O = 1 |
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| Density = 0.824 g/cm³ |
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| Density = 0.824 g/cm<sup>3</sup> |
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| MeltingPtC = 38 |
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| MeltingPtC = 38 |
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| BoilingPt = >260 °C |
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| BoilingPt = >260 °C |
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}} |
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| Section7={{Chembox Hazards |
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| GHSPictograms = {{GHS07}} |
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| GHSSignalWord = Warning |
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| HPhrases = {{H-phrases|410}} |
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| PPhrases = {{P-phrases|273|391|501}} |
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}} |
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}} |
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'''1-Tetradecanol''', or commonly '''myristyl alcohol''' (from ''Myristica fragrans'' – the ] plant), is a straight-chain ] ], with the molecular formula CH<sub>3</sub>(CH<sub>2</sub>)<sub>12</sub>CH<sub>2</sub>OH. It is a white waxy solid that is practically insoluble in water, soluble in ], and slightly soluble in ].<ref name=Ullmann>{{Ullmann|first1=Klaus|last1=Noweck|first2=Wolfgang|last2=Grafahrend|title=Fatty Alcohols|doi=10.1002/14356007.a10_277.pub2}}</ref> |
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==Production== |
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1-Tetradecanol may be prepared by the ] of ] (or its esters); myristic acid itself can be found in nutmeg (from where it gains its name) but is also present in ] and ] and it is from these that the majority of 1-tetradecanol is produced.<ref>{{cite journal|last1=Kreutzer|first1=Udo R.|title=Manufacture of Fatty Alcohols Based on Natural Fats and Oils|journal=Journal of the American Oil Chemists' Society|date=February 1984|volume=61|issue=2|pages=343–348|doi=10.1007/BF02678792|s2cid=84849226}}</ref> It may also be produced from petrochemical feedstocks via either the ]. |
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==Uses== |
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As with other fatty alcohols, 1-tetradecanol is used as an ingredient in cosmetics such as cold creams for its ] properties. It is also used as an intermediate in the chemical synthesis of other products such as ]. |
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==Toxicity== |
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Like other fatty alcohols, myristyl alcohol has very low acute toxicity, with ] >5000 mg/kg (oral, rat).<ref name=Ullmann/> |
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==References== |
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{{reflist}} |
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==External links== |
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*{{cite web |title=MSDS Number: ALCH414-1 |url=http://www.pgchemicals.com/resources/msds/CO1495_CO1498.pdf |archiveurl=https://web.archive.org/web/20060311040153/http://www.pgchemicals.com/resources/msds/CO1495_CO1498.pdf |archivedate=2006-03-11 |publisher=Procter and Gamble Chemicals |date=2002-06-17 }} (MSDS for 1-tetradecanol / Myristyl Alcohol) |
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{{alcohols}} |
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{{DEFAULTSORT:Tetradecanol, 1-}} |
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] |
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] |
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] |
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] |