| Revision as of 04:44, 17 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 465836856 of page Allylmagnesium_bromide for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 13:48, 19 January 2024 edit Maxim Masiutin (talk | contribs)Extended confirmed users, IP block exemptions, Pending changes reviewers31,052 edits Removed parameters. |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{chembox |
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{{chembox |
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| verifiedrevid = 399358928 |
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| verifiedrevid = 477314130 |
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|ImageFile=Allylmagnesium bromide.png |
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| ImageFile = Allylmagnesium bromide.png |
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|ImageSize=150px |
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| ImageSize = 150px |
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|OtherNames= |
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| OtherNames = |
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| IUPACName = Allylmagnesium bromide |
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|Section1={{Chembox Identifiers |
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| SystematicName = Prop-2-enylmagnesium bromide |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 10796765 |
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| ChemSpiderID = 10796765 |
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| InChI = 1/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.BrH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1 |
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| InChI = 1/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.BrH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo=1730-25-2 |
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| CASNo=1730-25-2 |
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| PubChem=74413 |
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| PubChem=74413 |
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|Section2={{Chembox Properties |
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| Section2 = {{Chembox Properties |
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| C = 3 | H = 5 | Mg =1 | Br = 1 |
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| C=3 | H=5 | Mg=1 | Br=1 |
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|Section3={{Chembox Hazards |
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'''Allylmagnesium bromide''' is a ] used for introducing the ]. It is commonly available as a solution in ]. It may be synthesized by treatment of ] with ] while maintaining the reaction temperature below 0 °C to suppress formation of hexadiene.<ref>{{OrgSynth | author = Benson, R. E. |author2=McKusick, B. C. | title = 1,4-Pentadiene | year = 1958 | volume = 38 | pages = 78 }}</ref> Allyl chloride can also be used in place of the bromide to give '''allylmagnesium chloride'''.<ref>{{cite book |doi=10.1002/9780470132449.ch14|chapter=Isoleptic Allyl Derivatives of Various Metals |year=1972 |last1=O'Brien |first1=S. |last2=Fishwick |first2=M. |last3=McDermott |first3=B. |last4=Wallbridge |first4=M. G. H. |last5=Wright |first5=G. A. |title=Inorganic Syntheses |volume=13|pages=73–79|isbn=9780470132449 }}</ref> These reagents are used to prepare ]es. |
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==References== |
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{{reflist}} |
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==Further reading== |
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* {{cite book | author = Chabot, P. |editor1=Rakita, P. E. |editor2=Silverman, G. | chapter = 7. Infrared and Raman Spectroscopy | title = Handbook of Grignard Reagents | year = 1996 | pages = 93–102 | location = New York, N.Y. | publisher = Marcel Dekker | isbn = 0-8247-9545-8 }} |
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