Browse history interactively

Page 1

Page 1Revision 1

Page 2

Page 2Revision 2

← Previous editContent deleted Content addedVisualWikitext

Revision as of 18:21, 6 August 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'ChemSpiderID_Ref', 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per [[Misplaced Pages:WikiProject Chemicals/Chembox validatio← Previous edit		Latest revision as of 09:18, 13 September 2024 edit undoLaundryPizza03 (talk | contribs)Extended confirmed users54,395 edits added Category:Diatomic molecules using HotCat
(41 intermediate revisions by 30 users not shown)
Line 1:		Line 1:
	{{chembox		{{chembox
			| Verifiedfields = changed
⚫	| verifiedrevid = 443381187
			| Watchedfields = changed
	| ImageFile =
		⚫	| verifiedrevid = 443382758
⚫	| ImageSize =
			| Name =
	| IUPACName = Aluminium monofluoride
			| ImageFile = Fluoridoaluminium-3D-vdW.png
⚫	| OtherNames =
		⚫	| ImageSize =
⚫	| Section1 = {{Chembox Identifiers
			| IUPACName = Fluoridoaluminium
		⚫	| OtherNames =
			| SystematicName =
		⚫	| Section1 = {{Chembox Identifiers
	| Abbreviations =		| Abbreviations =
			<!-- InChI and InChIKey do not match / June 2015 -->
	| InChIKey = RSCDSAGMXGBEFR-REWHXWOFAJ
	| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3		| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3
	| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC		| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC
		⚫	| InChI = 1/Al.FH/h;1H/q+1;/p-1/rAlF/c1-2
⚫	| SMILES1 = F(F)F
			| InChIKey = APURLPHDHPNUFL-GBQYYLROAD
		⚫	| StdInChI = 1S/Al.FH/h;1H/q+1;/p-1
		⚫	| StdInChIKey = APURLPHDHPNUFL-UHFFFAOYSA-M
			| CASNo_Ref = {{cascite|correct|??}}
	| CASNo = 13595-82-9		| CASNo = 13595-82-9
	| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}		| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
	| ChemSpiderID = 2039		| ChemSpiderID = 4576555
	| EINECS =		| EINECS =
	| PubChem =		| PubChem = 5464153
	| StdInChI_Ref = {{stdinchicite|correct|chemspider}}		| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
		⚫	| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
⚫	| StdInChI = 1S/Al.3FH/h;3*1H/q+3;;;/p-3
		⚫	| SMILES = F
⚫	| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
⚫	| StdInChIKey = KLZUFWVZNOTSEM-UHFFFAOYSA-K
	| SMILES = .
⚫	| InChI = 1/Al.FH/h;1H/q+3;/p-1
	| RTECS =		| RTECS =
	| MeSHName =		| MeSHName =
Line 28:		Line 33:
	| KEGG_Ref = {{keggcite|correct|kegg}}		| KEGG_Ref = {{keggcite|correct|kegg}}
	| KEGG =		| KEGG =
			}}
	| ATCCode_prefix =
		⚫	| Section2 = {{Chembox Properties
	| ATCCode_suffix =
		⚫	| Formula =
	| ATC_Supplemental =}}
			| Al=1 | F=1
⚫	| Section2 = {{Chembox Properties
⚫	| Formula = AlF
	| MolarMass = 45.98 g/mol		| MolarMass = 45.98 g/mol
	| Appearance =		| Appearance =
	| Density =		| Density =
	| MeltingPt =		| MeltingPt =
	| Melting_notes =		| MeltingPt_notes =
	| BoilingPt =		| BoilingPt =
	| Boiling_notes =		| BoilingPt_notes =
	| Solubility =		| Solubility =
	| SolubleOther =		| SolubleOther =
Line 52:		Line 56:
	| Viscosity =		| Viscosity =
	| Dipole = }}		| Dipole = }}
	| Section3 = {{Chembox Structure		| Section3 = {{Chembox Structure
	| CrystalStruct =		| CrystalStruct =
	| Coordination =		| Coordination =
	| MolShape =		| MolShape =
	| Dipole = }}		| Dipole = }}
	| Section4 = {{Chembox Thermochemistry		| Section4 = {{Chembox Thermochemistry
	| DeltaHf =		| DeltaHf =
	| DeltaHc =		| DeltaHc =
	| Entropy =		| Entropy =
	| HeatCapacity = }}		| HeatCapacity = }}
	| Section5 = {{Chembox Pharmacology		| Section5 =
		⚫	| Section6 = {{Chembox Explosive
	| AdminRoutes =
	| Bioavail =
	| Metabolism =
	| HalfLife =
	| ProteinBound =
	| Excretion =
	| Legal_status =
	| Legal_US =
	| Legal_UK =
	| Legal_AU =
	| Legal_CA =
	| PregCat =
	| PregCat_AU =
	| PregCat_US = }}
⚫	| Section6 = {{Chembox Explosive
	| ShockSens =		| ShockSens =
	| FrictionSens =		| FrictionSens =
	| ExplosiveV =		| DetonationV =
	| REFactor = }}		| REFactor = }}
	| Section7 = {{Chembox Hazards		| Section7 = {{Chembox Hazards
	| ExternalMSDS =		| ExternalSDS =
	| EUClass =
	| EUIndex =
	| MainHazards =		| MainHazards =
	| NFPA-H =		| NFPA-H =
	| NFPA-F =		| NFPA-F =
	| NFPA-R =		| NFPA-R =
	| NFPA-O =		| NFPA-S =
	| RPhrases =
	| SPhrases =
	| RSPhrases =
	| FlashPt =		| FlashPt =
	| Autoignition =		| AutoignitionPt =
	| ExploLimits =		| ExploLimits =
	| PEL = }}		| PEL = }}
	| Section8 = {{Chembox Related		| Section8 = {{Chembox Related
	| OtherAnions = ]		| OtherAnions = ]
	| OtherCations = ], ], ]		| OtherCations = ], ], ]
	| OtherFunctn =		| OtherFunction =
	| Function =		| OtherFunction_label =
	| OtherCpds = }}		| OtherCompounds = }}
	}}		}}
	'''Aluminium monofluoride''' is the ] with the ] AlF. This elusive species is formed by the reaction between ] and metallic aluminium at elevated temperatures but quickly reverts back to the reactants when cooled.<ref>{{cite journal | last1 = Dyke | first1 = C.Kirby | last2 = Morris | first2 = B.W.J.Gravenor | year = 1984 | title = A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy | url = | journal = Chemical Physics | volume = 88 | issue = 2| page = 289 | doi = 10.1016/0301-0104(84)85286-6 }}</ref> Clusters of derived from related aluminium(I) halides can be stabilized using specialized ]s.<ref>{{cite journal | last1 = Dohmeier | first1 = C. | last2 = Loos | first2 = D. | last3 = Schnöckel | first3 = H. | year = 1996 | title = Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions | url = | journal = Angewandte Chemie International Edition in English | volume = 35 | issue = 2| pages = 129–149 | doi = 10.1002/anie.199601291 }}</ref>		'''Aluminium monofluoride''', also known as '''fluoridoaluminium''', is the ] with the ] AlF. This elusive species is formed by the reaction between ] and metallic ] at elevated temperatures but quickly reverts to the reactants when cooled.<ref>{{cite journal | last1 = Dyke | first1 = C.Kirby | last2 = Morris | first2 = B.W.J.Gravenor | year = 1984 | title = A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy | journal = Chemical Physics | volume = 88 | issue = 2| page = 289 | doi = 10.1016/0301-0104(84)85286-6 |bibcode = 1984CP.....88..289D }}</ref> ] derived from related aluminium(I) ] can be stabilized using specialized ]s.<ref>{{cite journal | last1 = Dohmeier | first1 = C. | last2 = Loos | first2 = D. | last3 = Schnöckel | first3 = H. | year = 1996 | title = Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions | journal = Angewandte Chemie International Edition in English | volume = 35 | issue = 2| pages = 129–149 | doi = 10.1002/anie.199601291 }}</ref>
	This molecule has been detected in the ], where molecules are so dilute that intermolecular ] are unimportant.<ref>{{cite journal | author=L. M. Ziurys, A. J. Apponi, T. G. Phillips | title=Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF | journal=Astrophysical Journal | year=1994 | volume=433 | issue=2 | pages=729–732 | bibcode=1994ApJ...433..729Z | doi=10.1086/174682 }}</ref>		This molecule has been detected in the ], where molecules are so dilute that intermolecular ] are unimportant.<ref>{{cite journal |author1=L. M. Ziurys|author1-link= Lucy Ziurys |author2=A. J. Apponi |author3=T. G. Phillips | title=Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF | journal=Astrophysical Journal | year=1994 | volume=433 | issue=2 | pages=729–732 | bibcode=1994ApJ...433..729Z | doi=10.1086/174682 }}</ref>
			==See also==
			*]
			*]
		⚫	*]
	==References==		==References==
			{{reflist}}
	<references />
	{{Aluminium compounds}}		{{Aluminium compounds}}
			{{Fluorides}}
⚫	{{inorganic-compound-stub}}
			{{Molecules detected in outer space}}
⚫	]
			]
	]		]
			]
			]
	]
		⚫	{{inorganic-compound-stub}}