| Revision as of 14:10, 29 November 2010 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi← Previous edit |
Latest revision as of 21:36, 10 March 2022 edit undoCitation bot (talk | contribs)Bots5,428,992 edits Alter: pages. Formatted dashes. | Use this bot. Report bugs. | Suggested by Whoop whoop pull up | Category:Hexafluorophosphates | #UCB_Category 15/22 |
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{{chembox |
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{{chembox |
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| Watchedfields = changed |
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| verifiedrevid = 399518177 |
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| verifiedrevid = 399519634 |
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| ImageFile = ammonium hexafluorophosphate.png |
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| ImageFile = ammonium hexafluorophosphate.png |
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| ImageSize = 200px |
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| ImageFileL1 = Ammonium-3D-balls.png |
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| ImageFileL1 = Ammonium-3D-balls.png |
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| ImageNameL1 = Ball-and-stick model of the ammonium cation |
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| ImageNameL1 = Ball-and-stick model of the ammonium cation |
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| ImageFileR1 = Hexafluorophosphate-3D-balls.png |
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| ImageFileR1 = Hexafluorophosphate-3D-balls.png |
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| ImageSizeR1 = 120px |
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| ImageNameR1 = Ball-and-stick model of the hexafluorophosphate anion |
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| ImageNameR1 = Ball-and-stick model of the hexafluorophosphate anion |
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|IUPACName=ammonium hexafluorophosphate |
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| IUPACName=ammonium hexafluorophosphate |
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|OtherNames= |
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|Section1={{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 7969679 |
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| ChemSpiderID = 7969679 |
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| EC_number = 241-009-1 |
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| UNII = NS308031PJ |
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| InChI = 1/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1 |
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| InChI = 1/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1 |
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| InChIKey = NIZXKAYXSNUDOU-IKLDFBCSAF |
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| InChIKey = NIZXKAYXSNUDOU-IKLDFBCSAF |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = NIZXKAYXSNUDOU-UHFFFAOYSA-O |
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| StdInChIKey = NIZXKAYXSNUDOU-UHFFFAOYSA-O |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo=16941-11-0 |
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| CASNo=16941-11-0 |
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| PubChem=9793912 |
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| PubChem=9793912 |
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| SMILES=.F(F)(F)(F)(F)F |
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| SMILES=.F(F)(F)(F)(F)F |
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}} |
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|Section2={{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula=F<sub>6</sub>H<sub>4</sub>NP |
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| Formula=(NH<sub>4</sub>) |
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| MolarMass=163.00264 |
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| MolarMass=163.00264 |
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| Appearance= |
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| Appearance= white solid |
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| Density= |
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| Density=2.180 g/cm<sup>3</sup> |
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| Solubility=74.8 g/100 mL(20 °C) |
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|Section3={{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| ExternalMSDS = |
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| ExternalSDS = |
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| GHSPictograms = {{GHS05}} |
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| EUClass = Harmful (Xn); Corrosive (C) |
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| GHSSignalWord = Danger |
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| Autoignition= |
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| HPhrases = {{H-phrases|314}} |
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| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}} |
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'''Ammonium hexafluorophosphate''' is the ] with the formula NH<sub>4</sub>PF<sub>6</sub>. It is a white water-soluble, hygroscopic solid. The compound is a salt consisting of the ] cation and ] anion. It is commonly used as a source of the hexafluorophosphate anion, a ]. It is prepared by combining neat ] and ]. Alternatively it can also be produced from ]:<ref>{{cite book|author=W. Kwasnik|chapter=Ammonium Hexafluorophosphate (V)|title=Handbook of Preparative Inorganic Chemistry, 2nd Ed. |editor=G. Brauer|publisher=Academic Press|year=1963|place=NY, NY|volume=1|pages=195–196}}</ref> |
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'''Ammonium hexafluorophosphate''' is a commonly available form of the ] anion. |
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:PCl<sub>5</sub> + 6 NH<sub>4</sub>F → NH<sub>4</sub>PF<sub>6</sub> + 5 NH<sub>4</sub>Cl |
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:PNCl<sub>2</sub> + 6 HF → NH<sub>4</sub>PF<sub>6</sub> + 2 HCl |
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==References== |
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<references /> |
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{{Hexafluorophosphates}} |
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] |
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] |
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] |
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] |
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{{inorganic-compound-stub}} |
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{{inorganic-compound-stub}} |
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] |
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] |
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] |
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