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Revision as of 18:18, 12 November 2011 editThe chemistds (talk | contribs)Extended confirmed users5,761 edits added CSID, (Std)InChI & (Std)InChIKey← Previous edit Latest revision as of 15:30, 8 October 2024 edit undoJWBE (talk | contribs)Extended confirmed users10,126 edits removed Category:Anilines; added Category:4-Aminophenyl compounds using HotCat 
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{{chembox {{Chembox
| Verifiedfields = changed
⚫ | verifiedrevid = 431958979
| Watchedfields = changed
⚫ |ImageFile=Asulam.png
⚫ | verifiedrevid = 460319166
⚫ |ImageSize=
⚫ | ImageFile = Asulam.png
|IUPACName=''N''-(4-Aminophenyl)sulfonylcarbamic acid methyl ester
⚫ | ImageSize = 240
⚫ |OtherNames=
| ImageAlt = Skeletal formula
| ImageFile1 = Asulam-3D-balls.png
| ImageSize1 = 240
| ImageAlt1 = Ball-and-stick model
| PIN = Methyl (4-aminobenzene-1-sulfonyl)carbamate
⚫ | OtherNames =
|Section1={{Chembox Identifiers |Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}} | CASNo_Ref = {{cascite|correct|??}}
| CASNo=3337-71-1 | CASNo = 3337-71-1
| UNII_Ref = {{fdacite|correct|FDA}}
⚫ | PubChem=18752
| UNII = 0Y5ASM7P5S
⚫ | PubChem = 18752
| KEGG_Ref = {{keggcite|correct|kegg}} | KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG = C18350 | KEGG = C18350
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| PubChem = 18752
| ChemSpiderID = 17707 | ChemSpiderID = 17707
| ChEBI_Ref = {{ebicite|changed|EBI}}
⚫ | SMILES = O=S(=O)(c1ccc(N)cc1)NC(=O)OC
| ChEBI = 81696
⚫ | InChI = 1/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11)
⚫ | SMILES = O=S(=O)(c1ccc(N)cc1)NC(=O)OC
⚫ | InChIKey = VGPYEHKOIGNJKV-UHFFFAOYAJ
| StdInChI = 1S/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11) | InChI = 1/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11)
| StdInChIKey = VGPYEHKOIGNJKV-UHFFFAOYSA-N | InChIKey = VGPYEHKOIGNJKV-UHFFFAOYAJ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
⚫ }}
⚫ | StdInChI = 1S/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
⚫ | StdInChIKey = VGPYEHKOIGNJKV-UHFFFAOYSA-N
⚫ }}
|Section2={{Chembox Properties |Section2={{Chembox Properties
| Formula=C<sub>8</sub>H<sub>10</sub>N<sub>2</sub>O<sub>4</sub>S | Formula = C<sub>8</sub>H<sub>10</sub>N<sub>2</sub>O<sub>4</sub>S
| MolarMass=230.241 g/mol | MolarMass = 230.241 g/mol
| Appearance= | Appearance =
| Density= | Density = 1.419 g/mL
| MeltingPt= | MeltingPt =
| BoilingPt= | BoilingPt =
| Solubility= | Solubility =
}} }}
|Section3={{Chembox Hazards |Section3={{Chembox Hazards
| MainHazards= | MainHazards =
| FlashPt= | FlashPt =
| AutoignitionPt =
| Autoignition=
}} }}
}} }}


'''Asulam''' is a ] invented by ], and internally called M&B9057<ref>{{cite web|url=http://www.chemspider.com/Chemical-Structure.17707.html?rid=5a4054d2-3aa3-4364-942b-6e3bfa42cd9c|title=ChemSpider | Asulam | C8H10N2O4S|accessdate=30 September 2011}}</ref> and used in ] and ]. It is used to kill ]<ref>{{cite journal '''Asulam''' is a ] invented by ], internally called M&B9057,<ref>{{cite web|url=http://www.chemspider.com/Chemical-Structure.17707.html?rid=5a4054d2-3aa3-4364-942b-6e3bfa42cd9c|title=ChemSpider – Asulam – C8H10N2O4S|accessdate=30 September 2011}}</ref> that is used in ] and ] to kill ]<ref>{{cite journal
| title = An assessment of aerially applied asulam as a method of long-term bracken control | title = An assessment of aerially applied asulam as a method of long-term bracken control
| author = R. J. Pakemana, M. G. Le Ducb and R. H. Marrs | author = R. J. Pakemana, M. G. Le Ducb and R. H. Marrs
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| pages = 255–262 | pages = 255–262
| year = 1998 | year = 1998
| url = | url =
| doi = 10.1006/jema.1998.0207 }}</ref><ref>{{cite journal | doi = 10.1006/jema.1998.0207 | bibcode = 1998JEnvM..53..255P
}}</ref><ref>{{cite journal
| title = Restoration of Calluna heathland on a bracken Pteridium-infested site in north west England | title = Restoration of Calluna heathland on a bracken Pteridium-infested site in north west England
| author = C. S. R. Snow and R. H. Marrs | author = C. S. R. Snow and R. H. Marrs
| journal = Biological Conservation | journal = Biological Conservation
| volume = 81 | volume = 81
| issue = 1-2 | issue = 1–2
| pages = 35–42 | pages = 35–42
| year = 1997 | year = 1997
| url = | url =
| doi = 10.1016/S0006-3207(96)00147-4}}</ref> and ]<ref>{{cite journal | doi = 10.1016/S0006-3207(96)00147-4| bibcode = 1997BCons..81...35S
}}</ref> and ].<ref>{{cite journal
| title = Interactions Between the Chrysomelid Beetle Gastrophysa viridula, the Weed Rumex obtusifolius and the Herbicide Asulam | title = Interactions Between the Chrysomelid Beetle Gastrophysa viridula, the Weed Rumex obtusifolius and the Herbicide Asulam
| author = R. I. Speight and J. B. Whittaker | author = R. I. Speight and J. B. Whittaker
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| pages = 119–129 | pages = 119–129
| year = 1987 | year = 1987
| doi =10.2307/2403791 | doi = 10.2307/2403791
| jstor = 2403791 | jstor = 2403791
| bibcode = 1987JApEc..24..119S
| publisher = British Ecological Society }}</ref> also used as an antiviral agent. It is currently marketed, by ], as "Asulox" which contains 400 g/L of asulam sodium salt. }}</ref> It is also used as an antiviral agent. It is currently marketed, by ] - UPL, as "Asulox" which contains 400 g/L of asulam sodium salt.


Asulam was declared not approved by the "Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam, in accordance with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC (http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2011:275:0023:0024:EN:PDF). Asulam was declared not approved by the Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam.<ref>{{CELEX|32011R1045|format=PDF|text=Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam, in accordance with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC}}</ref> Concerns included: lack of evidence concerning the fate of the toxic metabolite ] and other metabolites; the poorly characterised nature of the impurities potentially present in the ] product; toxicity to birds. This decision is given in with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC.<ref>{{CELEX|02009R1107-20221121|format=PDF|text=Regulation (EC) No 1107/2009 of the European Parliament and of the Council of 21 October 2009 concerning the placing of plant protection products on the market and repealing Council Directives 79/117/EEC and 91/414/EEC (consolidated tex)}}</ref>


==References== ==References==
{{reflist}} {{reflist}}

==Further reading==
* {{PPDB|1551}}


{{Herbicides}} {{Herbicides}}
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{{organic-compound-stub}} {{organic-compound-stub}}
{{agri-stub}} {{agri-stub}}

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