| Revision as of 12:29, 12 October 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'ChEBI_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:WikiProject_Chemicals|er...← Previous edit |
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{{chembox |
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{{Chembox |
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| verifiedrevid = 442806442 |
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| verifiedrevid = 455196803 |
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| ImageFile = Bromofluoromethane.png |
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| ImageFile = Bromofluoromethane.png |
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| ImageSize = 120px |
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| ImageSize = 175px |
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| IUPACName = Bromofluoromethane |
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| ImageFile1 = Bromofluoromethane-3D-vdW.png |
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| ImageSize1 = 175px |
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| OtherNames = Bromofluoromethylene, CFC 31B1, R 31B1 |
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| PIN = Bromo(fluoro)methane <!-- Parentheses are used according to Subsection P-16.5.1.3 of Nomenclature of Organic Chemistry – IUPAC Recommendations and Preferred Names 2013 (Blue Book) --> |
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| Section1 = {{Chembox Identifiers |
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| OtherNames = Bromofluoromethane<br />Bromofluoromethylene<br />CFC 31B1<br />R 31B1 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 55059 |
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| ChemSpiderID = 55059 |
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| SMILES1 = BrCF |
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| SMILES1 = BrCF |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = LHMHCLYDBQOYTO-UHFFFAOYSA-N |
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| StdInChIKey = LHMHCLYDBQOYTO-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 373-52-4 |
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| CASNo = 373-52-4 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| PubChem = 61108 |
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| SMILES = C(F)Br |
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| UNII = 22205E7CEM |
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| PubChem = 61108 |
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| InChI = 1/CH2BrF/c2-1-3/h1H2 |
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| SMILES = C(F)Br |
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| InChI = 1/CH2BrF/c2-1-3/h1H2 |
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| Section2 = {{Chembox Properties |
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}} |
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| Formula = CH<sub>2</sub>BrF |
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|Section2={{Chembox Properties |
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| MolarMass = 112.93 g/mol |
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| Formula = CH<sub>2</sub>BrF |
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| Appearance = Gas |
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| MolarMass = 112.93 g/mol |
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| Density = |
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| MeltingPt = |
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| Appearance = Gas |
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| BoilingPt = 19 °C |
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| Density = |
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| Solubility = |
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| MeltingPt = |
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| BoilingPtC = 19 |
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| Solubility = |
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| Section3 = {{Chembox Structure |
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| CrystalStruct = |
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|Section3={{Chembox Structure |
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| Coordination = |
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| CrystalStruct = |
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| MolShape = Tetrahedral |
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| Coordination = |
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| MolShape = Tetrahedral |
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| Section3 = {{Chembox Hazards |
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| MainHazards = |
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|Section4={{Chembox Hazards |
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| FlashPt = |
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| Autoignition = |
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| MainHazards = |
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| FlashPt = |
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| AutoignitionPt = |
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'''Bromofluoromethane''' is a mixed gaseous ] soluble in ] and very soluble in ]. |
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'''Bromofluoromethane''' is a mixed gaseous ] soluble in ] and very soluble in ]. |
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Its ], ''S''<sup><s>o</s></sup><sub>gas</sub> is 276.3 J/(mol K) and ], ''c<sub>p</sub>'' is 49.2 J/(mol K). |
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Its ], ''S''<sup><s>o</s></sup><sub>gas</sub> is 276.3 J/(mol K) and ], ''c<sub>p</sub>'' is 49.2 J/(mol K). |
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# From ] by reductive debromination with a Swarts reagent. |
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# From ] by reductive debromination with a Swarts reagent. |
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# From a dihalomethane by an halogen exchange reaction or from a halomethane by catalyzed ] or ]. |
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# From a dihalomethane by an halogen exchange reaction or from a halomethane by catalyzed ] or ]. |
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The method with the highest yield is reductive debromination of dibromofluoromethane using an organotin hydride<ref></ref>. |
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The method with the highest yield is reductive debromination of dibromofluoromethane using an organotin hydride.<ref></ref> |
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== Uses == |
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== Uses == |
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Bromofluoromethane is an important reagent in the manufacture of intermediates, pharmaceuticals and other chemicals. Usage of bromofluoromethane is regulated due to its ] (0.73). Its isotopomer CH<sub>2</sub>Br<sup>18</sup>F is used in radiochemistry. |
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Bromofluoromethane is an important reagent in the manufacture of intermediates, pharmaceuticals and other chemicals. Usage of bromofluoromethane is regulated due to its ] (0.73). Its isotopomer CH<sub>2</sub>Br<sup>18</sup>F contains ] and is used in radiochemistry. |
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== References == |
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== References == |
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<references/> |
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<references/> |
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*{{cite journal | author = G. Cazzoli, C. Puzzarini, A. Baldacci and A. Baldan | year = 2007 | title = Determination of the molecular dipole moment of bromofluoromethane: microwave Stark spectra and ab initio calculations | journal = J. Mol. Spectrosc. | volume = 241 | issue = 115 | pages = | pmid = | doi = | url = | accessdate = 2007-06-29}} |
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*{{cite journal | author = G. Cazzoli |author2=C. Puzzarini |author3=A. Baldacci |author4=A. Baldan |name-list-style=amp | year = 2007 | title = Determination of the molecular dipole moment of bromofluoromethane: microwave Stark spectra and ab initio calculations | journal = J. Mol. Spectrosc. | volume = 241 | issue = 115 |pages=112–115 | doi = 10.1016/j.jms.2006.11.004|bibcode=2007JMoSp.241..112C }}<!--| accessdate = 2007-06-29--> |
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== External sources == |
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== External sources == |
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* {{Dead link|date=August 2023 |bot=InternetArchiveBot |fix-attempted=yes }} |
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* http://www.valliscor.com/bromofluoromethane |
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{{Halomethanes}} |
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{{Halomethanes}} |
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