| Revision as of 11:13, 7 August 2011 edit117.207.88.3 (talk) →External links | Latest revision as of 12:29, 19 December 2023 edit JWBE (talk | contribs)Extended confirmed users10,127 edits removed Category:Butyl compounds; added Category:Butyl esters using HotCat | ||
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| {{Other uses|Butyl acetate (disambiguation)}} | |||
| {{Infobox Indian politician | |||
| {{chembox | |||
| | caption = | |||
| |Watchedfields = changed | |||
| | birth_name = '''Narendera Devidas Rajwani''' | |||
| |verifiedrevid = 443492007 | |||
| | birth_date = {{birth date|1990|18|2|df=y}} | |||
| |Name = ''n''-Butyl acetate | |||
| | birth_place = ], ] | |||
| |ImageFile_Ref = {{chemboximage|correct|??}} | |||
| | residence = ], ], ] | |||
| |ImageFile = Butylacetat.svg | |||
| | predecessor = | |||
| |ImageAlt = Skeletal formula of butyl acetate | |||
| | successor = | |||
| |ImageFile1 = Butyl acetate 3D ball.png | |||
| | party =] | |||
| |ImageSize1 = 220px | |||
| | religion = Hindu | |||
| |ImageAlt1 = Ball-and-stick model of the butyl acetate molecule | |||
| | occupation = ],] | |||
| |PIN = Butyl acetate | |||
| | height = {{convinfobox|6|ft||m}} | |||
| |SystematicName = Butyl ethanoate | |||
| | year = 2010 | |||
| |OtherNames = ''n''-Butyl acetate<br>Acetic acid ''n''-butyl ester<br />Butile | |||
| | source = | |||
| |Section1={{Chembox Identifiers | |||
| |Abbreviations = BuAcO | |||
| |ChEBI_Ref = {{ebicite|correct|EBI}} | |||
| |ChEBI = 31328 | |||
| |SMILES = CCCCOC(=O)C | |||
| |ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | |||
| |ChemSpiderID = 29012 | |||
| |UNII_Ref = {{fdacite|correct|FDA}} | |||
| |UNII = 464P5N1905 | |||
| |KEGG_Ref = {{keggcite|correct|kegg}} | |||
| |KEGG = C12304 | |||
| |InChI = 1/C6H12O2/c1-3-4-5-8-6(2)7/h3-5H2,1-2H3 | |||
| |InChIKey = DKPFZGUDAPQIHT-UHFFFAOYAF | |||
| |ChEMBL_Ref = {{ebicite|correct|EBI}} | |||
| |ChEMBL = 284391 | |||
| |StdInChI_Ref = {{stdinchicite|correct|chemspider}} | |||
| |StdInChI = 1S/C6H12O2/c1-3-4-5-8-6(2)7/h3-5H2,1-2H3 | |||
| |StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | |||
| |StdInChIKey = DKPFZGUDAPQIHT-UHFFFAOYSA-N | |||
| |CASNo = 123-86-4 | |||
| |CASNo_Ref = {{cascite|correct|CAS}} | |||
| |PubChem = 31272 | |||
| |UNNumber = 1123 | |||
| |RTECS = AF7350000 | |||
| |EINECS = 204-658-1 | |||
| }} | |||
| |Section2={{Chembox Properties | |||
| |Formula = {{Chem2|CH3CO2(CH2)3CH3}} | |||
| |C=6 | H=12 | O=2 | |||
| |Appearance = Colorless liquid | |||
| |Odor = Fruity | |||
| |Density = 0.8825{{nbsp}}g/cm<sup>3</sup> (20{{nbsp}}°C)<ref name=crc>{{CRC90}}</ref> | |||
| |Solubility = 0.68{{nbsp}}g/100 mL (20{{nbsp}}°C)<ref name=crc /> | |||
| |SolubleOther = Miscible in ]<br> Soluble in ], ]<ref name=crc /> | |||
| |MeltingPtC = −78 | |||
| |MeltingPt_ref = <ref name=crc /> | |||
| |BoilingPtC = 126.1 | |||
| |BoilingPt_notes = at 760{{nbsp}}mmHg<ref name=crc /> | |||
| |RefractIndex = 1.3941 (20{{nbsp}}°C)<ref name=crc /> | |||
| |Viscosity = {{ubl | |||
| | 1.002{{nbsp}}cP (0{{nbsp}}°C) | |||
| | 0.685{{nbsp}}cP (25{{nbsp}}°C) | |||
| | 0.5{{nbsp}}cP (50{{nbsp}}°C) | |||
| | 0.305{{nbsp}}cP (100{{nbsp}}°C)<ref name=crc /> | |||
| }} | |||
| |VaporPressure = {{ubl | |||
| | 0.1{{nbsp}}kPa (−19{{nbsp}}°C) | |||
| | 1.66{{nbsp}}kPa (24{{nbsp}}°C)<ref name=crc /> | |||
| | 44.5{{nbsp}}kPa (100{{nbsp}}°C)<ref name=nist /> | |||
| }} | |||
| |LogP = 1.82<ref name=crc /> | |||
| |ThermalConductivity = {{ubl | |||
| | 0.143{{nbsp}}W/m·K (0{{nbsp}}°C) | |||
| | 0.136{{nbsp}}W/m·K (25{{nbsp}}°C) | |||
| | 0.130{{nbsp}}W/m·K (50{{nbsp}}°C) | |||
| | 0.116{{nbsp}}W/m·K (100{{nbsp}}°C)<ref name=crc /> | |||
| }} | |||
| |HenryConstant = 0.281{{nbsp}}L·atm/mol | |||
| |MagSus = −77.47·10<sup>−6</sup>{{nbsp}}cm<sup>3</sup>/mol | |||
| }} | |||
| |Section3={{Chembox Structure | |||
| |Dipole = 1.87 D (24 °C)<ref name=crc /> | |||
| }} | |||
| |Section4={{Chembox Thermochemistry | |||
| |HeatCapacity = 225.11 J/mol·K<ref name=nist>{{nist|name=Acetic acid, butyl ester|id=C123864|accessdate=2014-06-28|mask=FFFF|units=SI}}</ref> | |||
| |DeltaHf = −609.6 kJ/mol<ref name=nist /> | |||
| |DeltaHc = 3467 kJ/mol<ref name=nist /> | |||
| }} | |||
| |Section7={{Chembox Hazards | |||
| |MainHazards = Flammable | |||
| |GHSPictograms = {{GHS02}}{{GHS07}}<ref name="sigma">{{Sigma-Aldrich|id=w217409|name=Butyl acetate|accessdate=2014-06-28}}</ref> | |||
| |GHSSignalWord = Warning | |||
| |HPhrases = {{H-phrases|226|336}}<ref name="sigma" /> | |||
| |PPhrases = {{P-phrases|261}}<ref name="sigma" /> | |||
| |NFPA-H = 2 | |||
| |NFPA-F = 3 | |||
| |NFPA-R = 0 | |||
| |NFPA_ref = <ref name=fca>{{cite web|url = https://www.fishersci.ca/viewmsds.do?catNo=B3954|title = MSDS of n-Butyl acetate|website = fishersci.ca|access-date = 2014-06-28|publisher = Fisher Scientific}}</ref> | |||
| |FlashPtC = 22 | |||
| |FlashPt_ref = <ref name=fca /> | |||
| |AutoignitionPtC = 370 | |||
| |AutoignitionPt_ref = <ref name=fca /> | |||
| |TLV-TWA = 150 ppm<ref name=crc /> | |||
| |TLV-STEL = 200 ppm<ref name=crc /> | |||
| |PEL = TWA 150 ppm (710 mg/m<sup>3</sup>)<ref name=fca /> | |||
| |LD50 = 10768 mg/kg (rats, oral)<ref name=fca /> | |||
| |REL = TWA 150 ppm (710 mg/m<sup>3</sup>) ST 200 ppm (950 mg/m<sup>3</sup>)<ref name=PGCH/> | |||
| |IDLH = 1700 ppm<ref name=PGCH>{{PGCH|0072}}</ref> | |||
| |LC50 = 160 ppm (rat, 4 hr)<br/>2000 ppm (rat, 4 hr)<br/>391 ppm (rat, 4 hr)<br/>1242 ppm (mouse, 2 hr)<ref name=IDLH>{{IDLH|123864|n-Butyl acetate}}</ref> | |||
| |LCLo = 14,079 ppm (cat, 72 min)<br/>13,872 ppm (guinea pig, 4 hr)<ref name=IDLH/> | |||
| }} | |||
| |Section8={{Chembox Related | |||
| |OtherFunction_label = ]s | |||
| |OtherFunction = ]<br> ]<br> ] | |||
| |OtherCompounds = ] | |||
| }} | |||
| }} | |||
| '''''n''-Butyl acetate''' is an ] with the formula {{Chem2|CH3CO2(CH2)3CH3}}. A colorless, flammable liquid, it is the ester derived from n-] and ]. It is found in many types of fruit, where it imparts characteristic flavors and has a sweet smell of banana or apple. It is used as an industrial solvent.<ref name=Ullmann>{{Ullmann|doi=10.1002/14356007.a01_045|title=Acetic Acid |year=2000 |last1=Cheung |first1=Hosea |last2=Tanke |first2=Robin S. |last3=Torrence |first3=G. Paul |isbn=3527306730 }}</ref> | |||
| The other three isomers (four, including ]s) of butyl acetate are ], ], and ] (two ]s). | |||
| ==Production and use== | |||
| Butyl acetate is commonly manufactured by the ] of ] (or its isomer to make an isomer of butyl acetate) and ] with the presence of ]:<ref name=Ullmann/> | |||
| :] | |||
| Butyl acetate is mainly used as a solvent for coatings and inks.<ref name=Ullmann/> It is a component of fingernail polish.<ref>{{cite book |doi=10.1002/14356007.a24_219|chapter=Skin Cosmetics |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2001 |last1=Schneider |first1=Günther |last2=Gohla |first2=Sven |last3=Schreiber |first3=Jörg |last4=Kaden |first4=Waltraud |last5=Schönrock |first5=Uwe |last6=Schmidt-Lewerkühne |first6=Hartmut |last7=Kuschel |first7=Annegret |last8=Petsitis |first8=Xenia |last9=Pape |first9=Wolfgang |last10=Ippen |first10=Hellmut |last11=Diembeck |first11=Walter |isbn=3527306730 }}</ref> | |||
| ==Occurrence in nature== | |||
| Apples, especially of the ']' variety, are flavored in part by this chemical. The ]s emitted by the ] of ]s contain butyl acetate. | |||
| ==References== | |||
| {{reflist}} | |||
| ==External links== | ==External links== | ||
| {{Commons category|Butyl acetate}} | |||
| {{Persondata <!-- Metadata: see ]. --> | |||
| * | |||
| | NAME = Rajwani, Hitesh | |||
| * | |||
| | ALTERNATIVE NAMES = RAJWANI | |||
| * | |||
| | SHORT DESCRIPTION = HITU | |||
| {{Esters}} | |||
| | DATE OF BIRTH = 18 February 1990 | |||
| | PLACE OF BIRTH = ], ] | |||
| ] | |||
| {{DEFAULTSORT:Rajwani, Hitesh}} | |||
| ] | |||
| ] | ] | ||
| ] | ] | ||
| ] | ] | ||
| ] | ] | ||
| ] | |||
| ] | |||