| Revision as of 11:47, 19 May 2011 editCitation bot (talk | contribs)Bots5,457,714 editsm +: title, year, last1, first1, journal, volume, issue, pages. Formatted dashes.← Previous edit |
Latest revision as of 09:56, 29 November 2024 edit undoCitation bot (talk | contribs)Bots5,457,714 edits Altered title. Added bibcode. | Use this bot. Report bugs. | Suggested by Graeme Bartlett | #UCB_toolbar |
| (70 intermediate revisions by 49 users not shown) |
| Line 1: |
Line 1: |
|
{{chembox |
|
{{chembox |
|
|
| Watchedfields = changed |
|
| verifiedrevid = 411006503 |
|
| verifiedrevid = 429868421 |
|
| ImageFile = Chlorine azide.svg |
|
| ImageFile1 = Chlorine azide.svg |
|
| ImageSize = 200px |
|
|
| IUPACName = |
|
| ImageSize1 = 120px |
|
| OtherNames = Chlorine nitride; Nitrogen chloride |
|
| ImageFileL2 = Chlorine-azide-from-MW-3D-bs-17.png |
|
|
| ImageFileR2 = Chlorine-azide-from-MW-3D-sf.png |
| ⚫ |
| Section1 = {{Chembox Identifiers |
|
|
|
| IUPACName = Chlorine azide |
| ⚫ |
| CAS No = 13973-88-1 |
|
|
⚫ |
|Section1={{Chembox Identifiers |
|
| UN Number = |
|
|
|
| CASNo_Ref = {{cascite|correct|??}} |
| ⚫ |
| PubChem = 61708 |
|
|
⚫ |
| CASNo = 13973-88-1 |
|
|
| ChemSpiderID = 55609 |
|
⚫ |
| PubChem = 61708 |
|
|
| StdInChI=1S/ClN3/c1-3-4-2 |
|
|
| StdInChIKey = ZGNIYAPHJAPRMA-UHFFFAOYSA-N |
|
| SMILES = ==NCl}} |
|
| SMILES = ==NCl}} |
|
| Section2 = {{Chembox Properties |
|
|Section2={{Chembox Properties |
|
| Formula = ClN<sub>3</sub> |
|
| Formula = {{chem2|ClN3}} |
|
| MolarMass = 77.4731 |
|
| MolarMass = 77.4731 g/mol |
|
| Appearance = yellow orange liquid |
|
| Appearance = Yellow-orange liquid; colorless gas |
|
| Density = |
|
| Density = |
|
|
| MeltingPtC = -100 |
|
| MeltingPt = freezes at -100C |
|
|
| BoilingPt = approx -15C |
|
| BoilingPtC = -15 |
|
| Solubility = |
|
| Solubility = |
|
| SolubleOther = soluble in ], ], ], ], ], ], ], ], ], and ]; slightly soluble in water |
|
| SolubleOther = Soluble{{vague|date=March 2013}} in ], ], ], ], ], ], ], ], ], and ]; slightly soluble in water }} |
|
⚫ |
|Section3={{Chembox Structure |
| ⚫ |
}} |
|
|
|
| CrystalStruct = orthorhombic |
| ⚫ |
| Section3 = {{Chembox Explosive |
|
|
|
| SpaceGroup = Cmc 2<sub>1</sub>, No. 36<ref>{{Cite journal|last1=Lyhs|first1=Benjamin|last2=Bläser|first2=Dieter|last3=Wölper|first3=Christoph|last4=Schulz|first4=Stephan|last5=Jansen|first5=Georg|date=2012|title=A Comparison of the Solid-State Structures of Halogen Azides XN<sub>3</sub> (X=Cl, Br, I)|url=https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.201206028|journal=Angewandte Chemie International Edition|volume=51|issue=51|pages=12859–12863|doi=10.1002/anie.201206028|pmid=23143850}}</ref> }} |
|
| ShockSens = High |
|
|
|
|Section5={{Chembox Explosive |
| ⚫ |
| FrictionSens = High |
|
|
| ExplosiveV = |
|
| ShockSens = Extreme |
|
⚫ |
| FrictionSens = Extreme |
|
|
| DetonationV = |
|
| REFactor = }} |
|
| REFactor = }} |
|
| Section4 = {{Chembox Hazards |
|
|Section7={{Chembox Hazards |
|
| MainHazards = Harmful, Explosive |
|
| MainHazards = Extremely sensitive explosive |
|
|
| NFPA-H = |
|
|
| NFPA-F = 0 |
|
|
| NFPA-R = 4 |
|
|
| NFPA-S = |
|
| FlashPt = |
|
| FlashPt = |
|
| Autoignition = }} |
|
| AutoignitionPt = }} |
|
| Section8 = {{Chembox Related |
|
|Section8={{Chembox Related |
|
| OtherAnions = |
|
| OtherAnions = |
|
| OtherCations = |
|
| OtherCations = |
|
| OtherFunctn = |
|
| OtherFunction = |
|
| Function = |
|
| OtherFunction_label = |
|
| OtherCpds = ] }} |
|
| OtherCompounds = ]<br>]<br>]<br>] |
|
⚫ |
}} |
|
}} |
|
}} |
|
|
|
|
|
'''Chlorine azide ''' (]]<sub>3</sub>) is an ]. It was discovered by ] in 1908.<ref>Frierson, Joe; Browne, A. W.; Chlorine Azide. II. Interaction of Chlorine Azide and Silver Azide. Azino Silver Chloride, N<sub>3</sub>AgCl ], 1943, 65 (9), pp1698–1700 DOI: 10.1021/ja01249a013 Publication Date: September 1943</ref> |
|
'''Chlorine azide ''' ({{chem2|]]3}}) is an ] that was discovered in 1908 by ].<ref>{{ cite journal |author1=Frierson, W. J. |author2=Browne, A. W. | title = Chlorine Azide. II. Interaction of Chlorine Azide and Silver Azide. Azino Silver Chloride, N<sub>3</sub>AgCl | journal = ] | year = 1943 | volume = 65 | issue = 9 | pages = 1698–1700 | doi = 10.1021/ja01249a013 |bibcode=1943JAChS..65.1698F }}</ref> |
|
More so than other ]s, {{chem|ClN|3}} is highly explosive. In undiluted condition, it usually detonates violently whatever the temperature, without apparent provocation.<ref> Frierson, W. Joe; Kronrad, J.; Browne, A. W.; Chlorine Azide, ClN<sub>3</sub>, JACS., 1943, 65 (9), pp 1696–1698 DOI: 10.1021/ja01249a012 Publication Date: September 1943 </ref> |
|
Concentrated {{chem2|ClN3}} is notoriously unstable and may spontaneously detonate at any temperature.<ref>{{ cite journal |author1=Frierson, W. J. |author2=Kronrad, J. |author3=Browne, A. W. | title = Chlorine Azide, ClN<sub>3</sub>. I. | journal = ] | year = 1943 | volume = 65 | issue = 9 | pages = 1696–1698 | doi = 10.1021/ja01249a012 |bibcode=1943JAChS..65.1696F }}</ref> |
|
|
|
|
|
|
|
|
==Preparation and handling== |
|
==Preparation and handling== |
|
Chlorine azide is prepared by passing ] over ] or by an addition of ] to a solution of ] and ].<ref>{{cite journal | doi = 10.1002/cber.190804103130 | title = Über Chlorazid N3 Cl | year = 1908 | last1 = Raschig | first1 = F. | journal = Berichte der deutschen chemischen Gesellschaft | volume = 41 | issue = 3 | pages = 4194–4195}}</ref> |
|
Chlorine azide is prepared by passing ] over ], or by an addition of ] to a solution of ] and ].<ref>{{cite journal | last1 = Raschig | first1 = F. | title = Über Chlorazid N<sub>3</sub>Cl | journal = Berichte der Deutschen Chemischen Gesellschaft | year = 1908 | volume = 41 | issue = 3 | pages = 4194–4195 | doi = 10.1002/cber.190804103130 | url = https://zenodo.org/record/1426305 }}</ref> |
|
|
|
|
When treated with ] it is conceivable that one or more of the three possible ]s, NH<sub>2</sub>N<sub>3</sub>, NH(N<sub>3</sub>)<sub>2</sub>, and N(N<sub>3</sub>)<sub>3</sub> may be formed. |
|
|
|
|
|
|
==Explosive characteristics== |
|
==Explosive characteristics== |
|
Chlorine azide is highly sensitive. It will explode without provocation and is too sensitive to be used commercially. Explosive reaction with ], ], ], ], ], ], ], ]. Reacts with water or steam to produce toxic and corrosive fumes of ].<ref> </ref> |
|
Chlorine azide is extremely sensitive. It may explode, sometimes even without apparent provocation; it is thus too sensitive to be used commercially unless first diluted in solution. Chlorine azide reacts explosively with ], ], ], ], ], ], ], and ]. On contact with ], chlorine azide decomposes, evolving toxic and corrosive ] gas.<ref>{{PubChem|61708}}</ref> |
|
|
|
|
|
==Regulatory information== |
|
==Regulatory information== |
|
] forbids shipment. |
|
Its shipment is subject to strict reporting requirements and regulations by the ]. |
|
|
|
|
|
==References== |
|
==References== |
|
{{reflist}} |
|
{{Reflist}} |
|
|
|
|
|
==External links== |
|
|
*{{Commonscatinline}} |
|
|
|
|
|
{{Chlorine compounds}} |
|
|
{{Nitrogen compounds}} |
|
|
{{Azides}} |
|
|
|
|
|
] |
|
] |
|
] |
|
] |
|
] |
|
] |
|
|
] |
|
|
] |
|
|
] |