| Revision as of 15:19, 12 November 2010 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref') per Chem/Drugbox validation (report errors or [[u← Previous edit |
Latest revision as of 23:00, 2 September 2023 edit undoTrappist the monk (talk | contribs)Administrators479,893 editsm cite repair; |
| (32 intermediate revisions by 20 users not shown) |
| Line 1: |
Line 1: |
|
{{chembox |
|
{{chembox |
|
| verifiedrevid = 396328361 |
|
|verifiedrevid = 396330050 |
|
|ImageFile=Cl2Ptcod.png |
|
|ImageFile=Cl2Ptcod.png |
|
|ImageSize=150 |
|
|ImageSize=150 |
|
|ImageFile1=Dichloro(cycloocta-1,5-diene)platinum(II)-from-xtal-3D-balls-A.png |
|
|ImageFile1=Dichloro(cycloocta-1,5-diene)platinum(II)-from-xtal-3D-balls-A.png |
|
|IUPACName= |
|
|
|OtherNames= |
|
|
|Section1={{Chembox Identifiers |
|
|Section1={{Chembox Identifiers |
|
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
| ChemSpiderID = 4642949 |
|
|ChemSpiderID = 4642949 |
|
|
|EC_number = 235-144-5 |
|
| InChI = 1/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
|
|InChI = 1/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
|
| InChIKey = VVAOPCKKNIUEEU-AUZMAREFBX |
|
|InChIKey = VVAOPCKKNIUEEU-AUZMAREFBX |
| ⚫ |
| StdInChI = 1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
|
|
|
|StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
| ⚫ |
| StdInChIKey = VVAOPCKKNIUEEU-PHFPKPIQSA-L |
|
|
⚫ |
|StdInChI = 1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
| ⚫ |
| CASNo_Ref = {{cascite|correct|CAS}} |
|
|
|
|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
| ⚫ |
| CASNo=12080-32-9 |
|
|
⚫ |
|StdInChIKey = VVAOPCKKNIUEEU-PHFPKPIQSA-L |
| ⚫ |
| PubChem=5702648 |
|
|
⚫ |
|CASNo_Ref = {{cascite|correct|CAS}} |
| ⚫ |
| SMILES = ClCl.C\1=C\CC/C=C\CC/1 |
|
|
⚫ |
|CASNo=12080-32-9 |
|
⚫ |
|PubChem=5702648 |
|
⚫ |
|SMILES = ClCl.C\1=C\CC/C=C\CC/1 |
|
}} |
|
}} |
|
|Section2={{Chembox Properties |
|
|Section2={{Chembox Properties |
|
| C = 8 | H = 12 | Cl = 2 | Pt = 1 |
|
|C=8 | H=12 | Cl=2 | Pt=1 |
|
⚫ |
|MeltingPtC=285 |
|
| Appearance= |
|
|
⚫ |
}} |
|
| Density= |
|
| ⚫ |
| MeltingPtC=285 |
|
|
| BoilingPt= |
|
|
| Solubility= |
|
| ⚫ |
}} |
|
|
|Section3={{Chembox Hazards |
|
|Section3={{Chembox Hazards |
|
| EUClass = {{Hazchem Xi}} |
|
|GHSPictograms = {{GHS07}} |
|
|
|GHSSignalWord = Warning |
|
| RPhrases = {{R36/37/38}} |
|
|
| SPhrases = {{S26}}-{{S37/39}} |
|
|HPhrases = {{H-phrases|315|319|335}} |
|
|
|PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}} |
|
| FlashPt= |
|
|
| Autoignition= |
|
| ⚫ |
}} |
|
|
}} |
|
}} |
|
⚫ |
}} |
|
|
|
|
⚫ |
'''Dichloro(1,5-cyclooctadiene)platinum(II)''' ('''Pt(cod)Cl<sub>2</sub>''') is an ] of ]. This colourless solid is an entry point to other platinum compounds through the displacement of the cod and/or chloride ]s. It is one of several complexes of ]. |
|
|
|
|
|
Dichloro(1,5-cyclooctadiene)platinum(II) is prepared by treating ] with the diene:<ref>{{cite journal |author1=E. Costa |author2=P. G. Pringle |author3=M. Ravetz | title = Dimethyl-Platinum(II)| journal = ] | year = 1997 | volume = 31 | pages = 284–286 | doi = 10.1002/9780470132623.ch49 | isbn = 978-0-470-13262-3}}</ref> |
|
|
|
|
|
:K<sub>2</sub>PtCl<sub>4</sub> + C<sub>8</sub>H<sub>12</sub> → PtCl<sub>2</sub>C<sub>8</sub>H<sub>12</sub> + 2 KCl |
|
|
] |
|
|
|
|
|
According to ], the complex is square planar.<ref>{{cite journal|journal=Inorganica Chimica Acta|volume=65|year=1982|pages=L205–L206|title=Chemistry of Metal diene complexes: X-ray crystal structure of dichloro(1,5-cyclooctadine)platinum(II)|author=Anil B. Goel |author2=Sarla Goel |author3=Don Van Der Veer |doi=10.1016/S0020-1693(00)93548-5}}</ref><ref>{{cite journal | title = Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum |author1=Ashfaquzzaman Syed |author2=Edwin D. Stevens |author3=Sandra G. Cruz | journal = ] | year = 1984 | volume = 23 | issue = 22 | pages = 3673–3674 | doi = 10.1021/ic00190a053}}</ref> |
|
|
|
|
|
|
==See also== |
| ⚫ |
'''Dichloro(1,5-cyclooctadiene)platinum(II)''' ('''Pt(cod)Cl<sub>2</sub>''') is an ] of ]. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ]s. It is prepared from ] and the diene.<ref>{{cite journal | author = E. Costa, P. G. Pringle, M. Ravetz | title = Dimethyl-Platinum(II)| journal = ] | year = 1997 | volume = 31 | pages = 284–286 | doi = 10.1002/9780470132623.ch49}}</ref> |
|
|
|
*] |
|
|
|
|
|
==References== |
|
==References== |
| Line 41: |
Line 47: |
|
|
|
|
|
==Further reading== |
|
==Further reading== |
|
|
*J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, "The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II)," Acta Crystallogr. C. 2004, m353-m354. |
|
* {{cite journal | title = Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum | author = Ashfaquzzaman Syed, Edwin D. Stevens, Sandra G. Cruz | journal = ] | year = 1984 | volume = 23 | issue = 22 | pages = 3673–3674 | doi = 10.1021/ic00190a053}} |
|
|
|
{{Platinum compounds}} |
|
|
|
|
|
] |
|
] |
|
] |
|
] |
|
|
] |