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{{chembox |
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| verifiedrevid = 389504938 |
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| Watchedfields = changed |
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| Name = Diethylmercury |
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| verifiedrevid = 424699118 |
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| ImageFile = Diethylmercury-2D-skeletal.png |
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| Name = Diethylmercury |
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| IUPACName = diethylmercury |
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| ImageFile = Diethyl mercury.svg |
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| Section1 = {{Chembox Identifiers |
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| IUPACName = diethylmercury |
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| CASNo = 627-44-1 |
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|Section1={{Chembox Identifiers |
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| RTECS = |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 627-44-1 |
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| EINECS = 211-000-7 |
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| MeSHName = C007378 |
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| RTECS = |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID = 11814 |
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| PubChem = 12318 |
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| SMILES = CCCC |
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| InChI = 1/2C2H5.Hg/c2*1-2;/h2*1H2,2H3;/rC4H10Hg/c1-3-5-4-2/h3-4H2,1-2H3 |
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| InChIKey = SPIUPAOJDZNUJH-KFYQOLPSAK |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChI = 1S/2C2H5.Hg/c2*1-2;/h2*1H2,2H3; |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChIKey = SPIUPAOJDZNUJH-UHFFFAOYSA-N |
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| UNII_Ref = {{fdacite|changed|FDA}} |
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| UNII = 323TG9BTE8 |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = C<sub>4</sub>H<sub>10</sub>Hg |
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| Formula = {{Chem|C|4|H|10|Hg}}<br>{{Chem|({{Chem|C|2|H|5}})|2|Hg}} |
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| MolarMass = 258.71 g/mol |
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| MolarMass = 258.71 g/mol |
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| Appearance = Colorless liquid |
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| Appearance = Colorless liquid |
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| Density = 2.446 g/ml, liquid |
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| Density = 2.446 g/ml |
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| Solubility = Insoluble |
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| Solubility = Insoluble |
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| SolubleOther = Ethers, hydrocarbons, ] |
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| MeltingPt = -45 °C |
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| BoilingPt = 56 - 57 °C |
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| MeltingPtC = -45 |
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| BoilingPtC = 156 to 157 |
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| Viscosity = ? ] at ? °C |
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| BoilingPt_notes = |
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| Odor = Sweet |
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| Section3 = {{Chembox Structure |
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|Section3={{Chembox Structure |
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| MolShape = |
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| Section7 = {{Chembox Hazards |
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|Section7={{Chembox Hazards |
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| ExternalMSDS = |
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| ExternalSDS = |
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| MainHazards = |
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| MainHazards = Flammable, extremely toxic |
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| FlashPt = N/A |
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| FlashPt = N/A |
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| RPhrases = {{R26}}, {{R27}}, {{R28}},<br /> {{R33}}, {{R50}}, {{R53}} |
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| GHSPictograms = {{GHS06}}{{GHS08}}{{GHS09}} |
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| GHSSignalWord = Danger |
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| SPhrases = {{S13}}, {{S28}}, {{S36}}, {{S45}},<br />{{S60}}, {{S61}} |
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| HPhrases = {{H-phrases|225|300+310+330|373|410}} |
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| PPhrases = {{P-phrases|260|262|264|270|271|273|280|284|301+310|302+350|304+340|310|314|320|321|322|330|361|363|391|403+233|405|501}} |
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'''Diethylmercury ''' is a flammable, colorless liquid, and one of the strongest known ]s. This ] is described as having a slightly sweet smell, though inhaling enough fumes to notice this would involve significant exposure to the chemical.<ref>http://www.chemicalbook.com/ChemicalProductProperty_EN.aspx?CBNumber=CB7165894</ref> |
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'''Diethylmercury ''' is a flammable, colorless liquid, and one of the strongest known ]s. This ] is described as having a slightly sweet smell, though inhaling enough fumes to notice this would be hazardous.<ref>{{Cite web|url=http://www.chemicalbook.com/ChemicalProductProperty_EN.aspx?CBNumber=CB7165894|title=Diethyl Mercury | 627-44-1|access-date=2009-01-28|archive-date=2018-10-27|archive-url=https://web.archive.org/web/20181027021631/https://www.chemicalbook.com/ChemicalProductProperty_EN.aspx?CBNumber=CB7165894|url-status=dead}}</ref> |
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This chemical has also the ability to cross the ] causing permanent brain damage and decrease in IQ. |
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This chemical can cross the ], causing permanent brain damage. It is, however, considerably less toxic than ]. |
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== Synthesis == |
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Diethylmercury can be obtained from the reaction between ] and ].<ref>{{Cite book|last=Brauer|first=Georg|url=https://www.worldcat.org/oclc/310719490|title=Handbuch der präparativen anorganischen Chemie Bd. 2.|others=Baudler, Marianne|date=1975 |isbn=978-3-432-87813-3|edition=3rd|location=Stuttgart|pages=1063|oclc=310719490}}</ref> |
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:2 C<sub>2</sub>H<sub>5</sub>MgBr + HgCl<sub>2</sub> → Hg(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub> + MgBr<sub>2</sub> + MgCl<sub>2</sub> |
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Other methods are also known.<ref>{{Cite book|last=Kolbe|first=Hermann|title=Ausführliches Lehrbuch der organischen Chemie, Volume 2|year=1860|pages=964|author-link=Hermann Kolbe|url=https://books.google.com/books?id=-qU5AAAAcAAJ&pg=PA964}}</ref> |
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==See also== |
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==See also== |
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* ] |
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* ] |
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==References== |
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==References== |
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<references/> |
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<references/> |
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{{Mercury compounds}} |
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{{DEFAULTSORT:Diethyl Mercury}} |
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{{DEFAULTSORT:Diethyl Mercury}} |
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