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{{Unreferenced|date=October 2006}} |
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{{Chembox |
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{{Chembox |
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| verifiedrevid = 399906783 |
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| verifiedrevid = 436551287 |
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|ImageFile=Diisopropylzinc.png |
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| Name = |
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|ImageSize=120px |
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| ImageFile = Diisopropylzinc.png |
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|IUPACName= |
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| ImageSize = 120px |
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|OtherNames= |
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| ImageAlt = Skeletal formula of diisopropylzinc |
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|Section1={{Chembox Identifiers |
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| ImageFile1 = Diisopropylzinc 3D ball.png |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ImageSize1 = 170px |
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| ImageAlt1 = Ball-and-stick model of the diisopropylzinc molecule |
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| IUPACName = |
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| OtherNames = |
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| SystematicName = |
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| Section1 = {{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 11347073 |
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| ChemSpiderID = 11347073 |
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| InChI = 1/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;/rC6H14Zn/c1-5(2)7-6(3)4/h5-6H,1-4H3 |
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| InChI = 1/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;/rC6H14Zn/c1-5(2)7-6(3)4/h5-6H,1-4H3 |
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| InChIKey = KDUNMLRPPVCIGP-LSPCJBSIAV |
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| InChIKey = KDUNMLRPPVCIGP-LSPCJBSIAV |
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| SMILES1 = CC(C)C(C)C |
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| SMILES = CC(C)C(C)C |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3; |
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| StdInChI = 1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3; |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = KDUNMLRPPVCIGP-UHFFFAOYSA-N |
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| StdInChIKey = KDUNMLRPPVCIGP-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo=625-81-0 |
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| CASNo=625-81-0 |
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| PubChem=5207587 |
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| PubChem=5207587 |
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| SMILES=CC.CC. |
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|Section2={{Chembox Properties |
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| Section2 = {{Chembox Properties |
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| Formula=C<sub>6</sub>H<sub>14</sub>Zn |
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| Formula=C<sub>6</sub>H<sub>14</sub>Zn |
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| MolarMass=151.58 g/mol |
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| MolarMass=151.56 g/mol |
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|Section3={{Chembox Hazards |
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| Section3 = {{Chembox Hazards |
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| AutoignitionPt = |
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| Section4 = |
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| Section5 = |
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| Section6 = |
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'''Diisopropylzinc''' is an ] with the ] |
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'''Diisopropylzinc''' is an ] with the ] |
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ZnC<sub>6</sub>H<sub>14</sub>.<ref name="BedersonWalther2002">{{cite book|author1=Benjamin Bederson|author2=Herbert Walther|title=Advances in Atomic, Molecular, and Optical Physics|url=https://books.google.com/books?id=74hBmEjf5DMC&pg=PA250|access-date=2013-08-06|year=2002|publisher=Gulf Professional Publishing|isbn=978-0-12-003848-0|pages=250–}}</ref> |
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ZnC<sub>6</sub>H<sub>14</sub>. |
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It is the key reagent in the ], which is both autocatalytic and enantiospecific.<ref>{{cite journal | last1 = Shibata | first1 = Takanori | last2 = Morioka | first2 = Hiroshi | last3 = Hayase | first3 = Tadakatsu | last4 = Choji | first4 = Kaori | last5 = Soai | first5 = Kenso | title = Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol | journal = Journal of the American Chemical Society | volume = 118 | pages = 471–472 | year = 1996 | issue = 2 | doi = 10.1021/ja953066g}}</ref> This chemical is ], bursting into flame in air or in contact with water. It is generally packaged in toluene. |
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] |
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<ref>{{cite web |title=Diisopropylzinc 1.0M toluene 625-81-0 |url=https://www.sigmaaldrich.com/CA/en/product/aldrich/568112 |website=MilliporeSigma |access-date=8 January 2022}}</ref> |
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==References== |
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{{Reflist}} |
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{{Zinc compounds}} |
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] |
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] |
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{{Organic-compound-stub}} |
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{{Organic-compound-stub}} |