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Latest revision as of 10:54, 3 September 2024 edit undoCitation bot (talk | contribs)Bots5,431,781 edits Altered template type. Add: page, volume, journal, date, doi, title, authors 1-2. Changed bare reference to CS1/2. | Use this bot. Report bugs. | Suggested by Grimes2 | #UCB_webform 337/994 |
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{{chembox |
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{{chembox |
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| verifiedrevid = 404192641 |
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| verifiedrevid = 413074115 |
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| Name = Diphenylsilanediol |
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| ImageFile = Diphenylsilanediol-2D-skeletal.png |
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| Name = Diphenylsilanediol |
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| ImageFile = Diphenylsilanediol-2D-skeletal.png |
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| ImageFile1 = Diphenylsilanediol-1-from-xtal-3D-balls.png |
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| ImageFile1 = Diphenylsilanediol-1-from-xtal-3D-balls.png |
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| PIN = Diphenylsilanediol |
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| IUPACName = |
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| OtherNames = dihydroxydiphenylsilane |
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| OtherNames = dihydroxydiphenylsilane |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 947-42-2 |
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| PubChem = 24867114 |
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| CASNo = 947-42-2 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| SMILES = |
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| UNII = 36X37P8NBB |
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| InChI = 1/C12H12O2Si/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13-14H/i1-12,2-12,3-12,4-12,5-12,6-12,7-12,8-12,9-12,10-12,11-12,12-12,13-16,14-16,15-28 |
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| PubChem = 13693 |
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| ChemSpiderID = 13100 |
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| SMILES = c1ccc(cc1)(c2ccccc2)(O)O |
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| StdInChI = 1S/C12H12O2Si/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13-14H |
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| StdInChIKey = OLLFKUHHDPMQFR-UHFFFAOYSA-N |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = C<sub>12</sub>H<sub>12</sub>O<sub>2</sub>Si |
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| Formula = C<sub>12</sub>H<sub>12</sub>O<sub>2</sub>Si |
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| MolarMass = 216.308 g/mol |
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| MolarMass = 216.308 g/mol |
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| Appearance = Colorless crystals<ref name=gestis>{{cite web | url=https://gestis.dguv.de/data?name=002740&lang=en | title=GESTIS-Stoffdatenbank }}</ref> |
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| Density = 1.255 g/cm<sup>3</sup><ref>{{ cite journal | journal = J. Appl. Cryst. | year = 1978 | volume = 11 | issue = 5 | month = October | pages = 670–671 | title = Crystal data for diphenylsilanediol, (C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>Si(OH)<sub>2</sub> | author = T. J. Kistenmacher, M. Rossi, L. K. Frevel | doi = 10.1107/S002188987801420X }}</ref> |
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| Odor = Odorless<ref name=gestis></ref> |
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| MeltingPt = 144-148 °C |
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| Density = 1.255 g/cm<sup>3</sup><ref>{{ cite journal | journal = J. Appl. Crystallogr. |date=October 1978 | volume = 11 | issue = 5 | pages = 670–671 | title = Crystal data for diphenylsilanediol, (C<sub>6</sub>H<sub>3</sub>)<sub>2</sub>Si(OH)<sub>2</sub> |author1=T. J. Kistenmacher |author2=M. Rossi |author3=L. K. Frevel | doi = 10.1107/S002188987801420X }}</ref> |
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| BoilingPt = |
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| MeltingPtC = 144 to 148 |
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| MeltingPt_notes = |
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| BoilingPt = |
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| Section3 = {{Chembox Hazards |
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| Section3 = {{Chembox Structure |
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| Structure_ref = <ref name=pubs>{{cite journal | url=https://pubs.acs.org/doi/abs/10.1021/ac60157a047 | doi=10.1021/ac60157a047 | title=Crystallographic Data. 187. Diphenylsilanediol | date=1960 | last1=Neal | first1=D. J. | last2=Blaumanis | first2=R. D. | journal=Analytical Chemistry | volume=32 | page=139 }}</ref> |
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| ExternalMSDS = |
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| CrystalStruct = ] |
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'''Diphenylsilanediol''', Ph<sub>2</sub>Si(OH)<sub>2</sub>, is a ]. The tetrahedral molecule forms ] columns in the solid state<ref name="Fawcett">{{ cite journal | journal = Can. J. Chem. | volume = 55 | issue = 20 | year = 1977 | pages = 3631–3635 | author = J. K. Fawcett, N. Camerman, A. Camerman | doi = 10.1139/v77-510 | title = Stereochemical basis of anticonvulsant drug action. VI. Crystal and molecular structure of diphenylsilanediol }}</ref>. It can be prepared by ] of diphenyldichlorosilane Ph<sub>2</sub>SiCl<sub>2</sub>. Diphenylsilanediol can act as an ], in a similar way to ].<ref name="Fawcett "/> |
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'''Diphenylsilanediol''', Ph<sub>2</sub>Si(OH)<sub>2</sub>, is a ]. The tetrahedral molecule forms ] columns in the solid state.<ref name="Fawcett">{{ cite journal | journal = Can. J. Chem. | volume = 55 | issue = 20 | year = 1977 | pages = 3631–3635 |author1=J. K. Fawcett |author2=N. Camerman |author3=A. Camerman | doi = 10.1139/v77-510 | title = Stereochemical basis of anticonvulsant drug action. VI. Crystal and molecular structure of diphenylsilanediol }}</ref> It can be prepared by ] of diphenyldichlorosilane Ph<sub>2</sub>SiCl<sub>2</sub>. Diphenylsilanediol can act as an ], in a similar way to ].<ref name="Fawcett "/> Although the compound is stable in normal conditions, the presence of basic impurities can accelerate the condensation of the silanol groups. |
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==References== |
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==References== |
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