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{{Distinguish|ethanol|Vinyl alcohol}} |
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{{chembox |
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{{Chembox |
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| Name = Ethynol |
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| Verifiedfields = changed |
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| ImageFile = Ethynol.svg |
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| Watchedfields = changed |
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| ImageSize = |
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| verifiedrevid = 406159855 |
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| ImageName = Structural formula of ethynol |
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| ImageFile1 = Ethynol-3D-vdW.png |
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| ImageFileL1 = Ethynol.svg |
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| ImageFileL1_Ref = {{chemboximage|correct|??}} |
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| ImageName1 = Ball-and-stick model |
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| ImageNameL1 = Structural formula of ethynol |
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| IUPACName = Ethynol |
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| SystematicName = Ethynol |
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| ImageFileR1 = Ethynol-3D-vdW.png |
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| ImageFileR1_Ref = {{chemboximage|correct|??}} |
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| OtherNames = Ynol |
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| ImageNameR1 = Spacefill model of ethynol |
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| Section1 = {{Chembox Identifiers |
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| SystematicName = Ethynol<ref>{{cite web|url= https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=123441|title= Ethynol|work= The PubChem Project|location= USA|publisher= National Center for Biotechnology Information}}</ref> |
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| Abbreviations = |
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| OtherNames = Ynol, ethynyl alcohol, hydroxyacetylene |
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| CASNo = 32038-79-2 |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = |
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| CASNo = 32038-79-2 |
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| CASNos = |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASOther = |
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| PubChem = 123441 |
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| PubChem = 123441 |
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| SMILES = C#CO |
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| ChemSpiderID = 110037 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| InChI = InChI=1S/C2H2O/c1-2-3/h1,3H |
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| SMILES = OC#C |
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| Beilstein = |
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| SMILES1 = C#CO |
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| Gmelin = |
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| StdInChI = 1S/C2H2O/c1-2-3/h1,3H |
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| ChemSpiderID = |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| 3DMet =}} |
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| StdInChIKey = QFXZANXYUCUTQH-UHFFFAOYSA-N |
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| Section2 = {{Chembox Properties |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| Formula = ]<sub>2</sub>]<sub>2</sub>] |
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| MolarMass = 42.0367 g/mol |
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| Appearance = |
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| Density = |
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| MeltingPt = |
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| Melting_notes = |
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| BoilingPt = |
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| Boiling_notes = |
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| Solubility = |
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| SolubleOther = |
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| Solvent = |
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| LogP = |
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| VaporPressure = |
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| HenryConstant = |
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| AtmosphericOHRateConstant = |
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| pKa = |
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| pKb = }} |
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| Section3 = {{Chembox Structure |
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| CrystalStruct = |
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| Coordination = |
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| MolShape = }} |
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| Section4 = {{Chembox Thermochemistry |
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| DeltaHf = 41.6 ]/] |
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| DeltaHc = |
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| Entropy = |
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| HeatCapacity = }} |
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| Section5 = {{Chembox Pharmacology |
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| AdminRoutes = |
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| Bioavail = |
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| Metabolism = |
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| HalfLife = |
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| ProteinBound = |
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| Excretion = |
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| Legal_status = |
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| Legal_US = |
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| Legal_AU = |
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| Legal_CA = |
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| PregCat = |
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| PregCat_AU = |
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| PregCat_US = }} |
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| Section6 = {{Chembox Explosive |
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| ShockSens = |
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| FrictionSens = |
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| ExplosiveV = |
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| REFactor = }} |
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| Section7 = {{Chembox Hazards |
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| ExternalMSDS = |
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| EUClass = |
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| EUIndex = |
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| MainHazards = |
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| NFPA-H = |
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| NFPA-F = |
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| NFPA-R = |
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| NFPA-O = |
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| RPhrases = |
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| SPhrases = |
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| RSPhrases = |
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| FlashPt = |
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| Autoignition = |
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| ExploLimits = |
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| LD50 = |
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| PEL = }} |
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| Section8 = {{Chembox Related |
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| OtherAnions = |
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| OtherCations = |
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| OtherFunctn = |
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| Function = |
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| OtherCpds = }} |
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}} |
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}} |
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|Section2={{Chembox Properties |
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| C=2 | H=2 | O=1 |
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| Appearance = |
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| Density = 0.981 g·cm<sup>−3</sup> |
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| MeltingPt = |
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| BoilingPtC = 77.1 |
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| BoilingPt_notes = @ 760mmHg |
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| Solubility = |
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}} |
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|Section3={{Chembox Hazards |
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| MainHazards = |
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| FlashPtC = 14.7 |
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| AutoignitionPtC = |
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}} |
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|Section4={{Chembox Thermochemistry |
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| DeltaHf = 41.6 kJ mol<sup>−1</sup> |
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}} |
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| Section5 = {{Chembox Related |
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| OtherCompounds = ] |
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}} |
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}} |
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'''Ethynol''' (or '''hydroxyacetylene''', '''ethynyl alcohol''') is an ]–] (]) with the ] C<sub>2</sub>H<sub>2</sub>O. It is the much-less-stable ] of ]. |
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At low temperature in a ] it is possible to tautomerise ethenone to form ethynol.<ref>{{cite journal |doi= 10.1002/ange.19901020438 |title= Reversible Photoisomerisierung von Keten zu Ethinol |year= 1990 |last1= Hochstrasser |first1= Remo |last2= Wirz |first2= Jakob |journal= Angewandte Chemie |volume= 102 |pages= 454 |issue= 4|bibcode= 1990AngCh.102..454H }}</ref><ref>{{cite journal |doi= 10.1002/ange.19891010209 |title= Ethinol: Photochemische Erzeugung in einer Argonmatrix, IR-Spektrum und Photoisomerisierung zu Keten |year= 1989 |last1= Hochstrasser |first1= Remo |last2= Wirz |first2= Jakob |journal= Angewandte Chemie |volume= 101 |pages= 183 |issue= 2|bibcode= 1989AngCh.101..183H }}</ref> |
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'''Ethynol''' is an ] with the ] C<sub>2</sub>H<sub>2</sub>O. It is the much less stable ] of ]. |
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At low temperature in a ] it is possible to isomerize ethenone to form ethynol.<ref>{{cite journal | doi = 10.1002/ange.19901020438 | title = Reversible Photoisomerisierung von Keten zu Ethinol | year = 1990 | last1 = Hochstrasser | first1 = Remo | last2 = Wirz | first2 = Jakob | journal = Angewandte Chemie | volume = 102 | pages = 454}}</ref><ref>{{cite journal | doi =10.1002/ange.19891010209 | title =Ethinol: Photochemische Erzeugung in einer Argonmatrix, IR-Spektrum und Photoisomerisierung zu Keten | year =1989 | last1 =Hochstrasser | first1 =Remo | last2 =Wirz | first2 =Jakob | journal =Angewandte Chemie | volume =101 | pages =183}}</ref> |
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==See also== |
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==See also== |
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*] (ethyl alcohol) |
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*] (ethyl alcohol) |
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*] (vinyl alcohol) |
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*] (vinyl alcohol) |
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*] |
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==References== |
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==References== |
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{{Reflist}} |
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{{Reflist}} |
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] |
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{{iw-ref|sv|Etynol|2009-12-16|oldid=http://sv.wikipedia.org/search/?title=Etynol&oldid=10690839}} |
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{{organic-chem-stub}} |
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] |
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{{Alcohol-stub}} |
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] |
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] |
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] |
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] |
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