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Revision as of 21:44, 26 March 2011 editRjwilmsi (talk | contribs)Extended confirmed users, Pending changes reviewers, Rollbackers932,073 editsm clean up (PMC fields) using AWB (7658)← Previous edit Latest revision as of 20:28, 15 December 2024 edit undo176.88.36.224 (talk) error fixed 
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{{chembox {{Chembox
| verifiedrevid = 396492685 | verifiedrevid = 420876606
| Name = Hexafluoropropylene | Name = Hexafluoropropylene
| ImageFileL1 = Hexafluoropropylene.svg | ImageFile =
| ImageFileL1 = Hexafluoropropylene.svg
| ImageSizeL1 = 125
| ImageSizeL1 = 100px
| ImageAltL1 = Structural formula of hexafluoropropylene
| ImageFileR1 = Hexafluoropropylene 3D.png | ImageFileR1 = Hexafluoropropylene 3D.png
| ImageSizeR1 = 120px
| ImageFile2 = Liquified Hexafluoropropylene.png
| IUPACName = Hexafluoropropene
| ImageSizeR1 = 125
| OtherNames = Perfluoropropene,<br /> Perfluoropropylene,<br /> freon R 1216,<br /> halocarbon R 1216,<br /> fluorocarbon 1216
| ImageAltR1 = Ball-and-stick model of the hexafluoropropylene molecule
| Section1 = {{Chembox Identifiers
| ImageSize2 = 200px
| SMILES = F/C(F)=C(/F)C(F)(F)F
| PIN = 1,1,2,3,3,3-Hexafluoroprop-1-ene
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| OtherNames = Perfluoropropene,<br /> Perfluoropropylene,<br /> freon R 1216,<br /> halocarbon R 1216,<br /> fluorocarbon 1216
| Section1 = {{Chembox Identifiers
| SMILES = F/C(F)=C(/F)C(F)(F)F
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 8001 | ChemSpiderID = 8001
| InChI = 1/C3F6/c4-1(2(5)6)3(7,8)9 | InChI = 1/C3F6/c4-1(2(5)6)3(7,8)9
Line 20: Line 25:
| CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 116-15-4 | CASNo = 116-15-4
| UNII_Ref = {{fdacite|correct|FDA}}
| RTECS = UD0350000
| UNII = TRW23XOS20
}}
| RTECS = UD0350000
| Section2 = {{Chembox Properties
| C=3|F=6 | PubChem = 8302
| UNNumber = 1858
| Appearance = Colorless, odorless gas
| EINECS = 204-127-4
| Density = 1.332 g/ml, liquid at 20 °C
}}
| Solubility = Insoluble
| Section2 = {{Chembox Properties
| MeltingPtC = -153
| BoilingPtC = -28 | C=3 | F=6
| Appearance = Colorless, odorless gas
}}
| Density = 1.332 g/ml, liquid at 20 °C
| Section7 = {{Chembox Hazards
| Solubility = Insoluble
| ExternalMSDS =
| MeltingPtC = -153
| MainHazards = Harmful ('''Xn''')
| BoilingPtC = -28
| NFPA-H = 2
}}
| NFPA-F =
| Section7 = {{Chembox Hazards
| NFPA-R =
| ExternalSDS =
| FlashPt = Non flammable gas
| MainHazards = Suffocation
| RPhrases = {{R20}}, {{R37}}
| SPhrases = {{S41}} | NFPA-H = 1
| NFPA-F = 0
}}
| NFPA-R = 1
| Section8 = {{Chembox Related
| FlashPt = Non flammable gas
| Function = ]s
| GHSPictograms = {{GHS07}}{{GHS08}}
| OtherFunctn = ]
| GHSSignalWord = Warning
| Function = organofluorides
| HPhrases = {{H-phrases|332|335|351|371|373}}
| OtherFunctn = ],<br />]
| PPhrases = {{P-phrases|201|202|260|261|264|270|271|281|304+312|304+340|308+313|309+311|312|314|403+233|405|410+403|501}}
}}
}}
| Section8 = {{Chembox Related
| OtherFunction_label = ]s;<br>organofluorides
| OtherFunction = ];<br>], ]
}}
}} }}


'''Hexafluoropropylene''' is a compound with the formula C<sub>3</sub>F<sub>6</sub>. It is a ] ] in which all of the hydrogen atoms in ] are replaced by ] atoms. It is used as a chemical intermediate.<ref>{{cite journal '''Hexafluoropropylene''' is the ] with the formula CF<sub>3</sub>CF=CF<sub>2</sub>. It is the ] counterpart to the hydrocarbon ]. It is mainly used to produce copolymers with ]. Hexafluoropropylene is used as a chemical intermediate.<ref name=Ullmann>{{Ullmann|first1=Günter |last1=Siegemund|first2=Werner|last2=Schwertfeger|first3=Andrew|last3=Feiring|first4=Bruce|last4=Smart|first5=Fred|last5=Behr|first6=Herward|last6=Vogel|first7=Blaine |last7=McKusick|first8=Peer|last8= Kirsch|title=Fluorine Compounds, Organic|year=2016|doi=10.1002/14356007.a11_349.pub2}}</ref>

|last=Lehmler |first=HJ
==Preparation==
|title=Synthesis of environmentally relevant fluorinated surfactants—a review
Hexafluoropropylene can be produced by pyrolysis of ]:<ref name=Ullmann/><ref>{{cite journal
|journal=Chemosphere |volume=58 |issue=11 |pages=1471–96 |month=March |year=2005
| last=Lehmler |first=HJ
|doi=10.1016/j.chemosphere.2004.11.078 |pmid=15694468 |pmc=2587313}}</ref>
| title=Synthesis of environmentally relevant fluorinated surfactants—a review
| journal=Chemosphere |volume=58 |issue=11 |pages=1471–96 |date=March 2005
| doi=10.1016/j.chemosphere.2004.11.078 |pmid=15694468 |bibcode=2005Chmsp..58.1471L
}}</ref>
:3{{nbsp}}CF<sub>2</sub>=CF<sub>2</sub> → 2{{nbsp}}CF<sub>3</sub>CF=CF<sub>2</sub>
It can also be prepared from ], or produced from various ].<ref name="dupontsynth">
{{cite patent|country=United States|number=5043491A|title=Multistep synthesis of hexafluoropropylene|status=patent (expires 5-20-2020)|pubdate=1991-08-27|fdate=1989-12-19|pridate=1989-12-19|gdate=1991-08-27|inventor=James L. Webster, Elrey L. McCann, Douglas W. Bruhnke, Jan J. Lerou|assign1=E. I. Du Pont de Nemours and Company|url=https://patents.google.com/patent/US5043491A/en?q=~patent%2fUS5057634A}}
</ref>


==References== ==References==
<references/> <references/>


] ]



{{organohalide-stub}} {{organohalide-stub}}

]
]
]