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{{DISPLAYTITLE:''para''-Azoxyanisole}} |
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{{DISPLAYTITLE:''para''-Azoxyanisole}} |
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{{Orphan|att=May 2008|date=December 2010}} |
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{{chembox |
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{{chembox |
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| Watchedfields = changed |
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| Watchedfields = changed |
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| verifiedrevid = 407275534 |
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| verifiedrevid = 456075721 |
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| Name = '''''para''-Azoxyanisole''' |
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| Name = ''para''-Azoxyanisole |
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| ImageFile = Para-Azoxyanisole.png |
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| ImageFile = Para-azoxyanisole.svg |
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| ImageSize = 200px |
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| ImageSize = 200px |
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| ImageName = Para-Azoxyanisole |
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| ImageName = Para-Azoxyanisole |
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| IUPACName = 1-methoxy-4-benzene |
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| IUPACName = 1-Methoxy-4-benzene |
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| OtherNames=''p''-Azoxyanisole |
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| OtherNames =''p''-Azoxyanisole |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo = 1562-94-3 |
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| CASNo = 1562-94-3 |
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| SMILES = COc2ccc(\N=(/)c1ccc(OC)cc1)cc2 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| PubChem = 15277 |
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| UNII = 4G08S4XUIX |
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| ChemSpiderID = 14542 |
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| SMILES = COc2ccc(\N=(/)c1ccc(OC)cc1)cc2 |
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| InChI = 1/C14H14N2O3/c1-18-13-7-3-11(4-8-13)15-16(17)12-5-9-14(19-2)10-6-12/h3-10H,1-2H3/b16-15- |
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| PubChem = 15277 |
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| InChIKey = KAEZRSFWWCTVNP-NXVVXOECBU |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| StdInChI = 1S/C14H14N2O3/c1-18-13-7-3-11(4-8-13)15-16(17)12-5-9-14(19-2)10-6-12/h3-10H,1-2H3/b16-15- |
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| ChemSpiderID = 14542 |
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| StdInChIKey = KAEZRSFWWCTVNP-NXVVXOECSA-N |
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| InChI = 1/C14H14N2O3/c1-18-13-7-3-11(4-8-13)15-16(17)12-5-9-14(19-2)10-6-12/h3-10H,1-2H3/b16-15- |
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| InChIKey = KAEZRSFWWCTVNP-NXVVXOECBU |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/C14H14N2O3/c1-18-13-7-3-11(4-8-13)15-16(17)12-5-9-14(19-2)10-6-12/h3-10H,1-2H3/b16-15- |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = KAEZRSFWWCTVNP-NXVVXOECSA-N |
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}} |
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}} |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| C=14 | H= 14 | N=2 | O=3 |
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| Formula = C<sub>14</sub>H<sub>14</sub>N<sub>2</sub>O<sub>3</sub> |
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| Appearance = |
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| MolarMass = 258.27 g/mol |
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| Density = 1.14 g/cm<sup>3</sup> |
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| Appearance = |
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| Density = 1.14g/cm3 |
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| MeltingPtC = 114.9 |
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| MeltingPtC = 114.9 |
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| BoilingPtC = 417.9 |
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| BoilingPt_notes = at 760 mmHg{{dubious|reason=418 °C is way too high to be real - it will surely decompose well below this temperature|date=September 2021}}{{cn|date=September 2021}} |
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| BoilingPt = 417.9°C @ 760mmHg |
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}} |
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}} |
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| Section3 = {{Chembox Hazards |
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|Section3={{Chembox Hazards |
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| FlashPt = 206.6°C |
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| FlashPtC = 206.6 |
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'''''para''-Azoxyanisole''' (PAA) is an organic, aromatic compound. In a solid state, it appears as a white powder, but when heated it forms a liquid crystal. As one of the first known and most readily prepared liquid crystals,<ref name="Shao">{{cite journal|title=Phase Transitions of Liquid Crystal PAA in Confined Geometries|author=Shao, Y.; Zerda, T. W.|journal=Journal of Physical Chemistry B|year=1998|volume=102|issue=18|pages=3387–3394|doi=10.1021/jp9734437}}</ref> PAA has been played an important role in the development of ]s.<ref>''Liquid Gold: The Story of Liquid Crystal Displays and the Creation of an Industry'', Joseph A. Castellano, ISBN 978-9812389565</ref> |
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'''''para''-Azoxyanisole''' ('''PAA''') is an ], ]. Its ] is '''C<sub>14</sub>H<sub>14</sub>N<sub>2</sub>O<sub>3</sub>'''. In a ], it appears as a white ], but when heated it forms a ]. As one of the first known and most readily prepared liquid crystals,<ref name="Shao">{{cite journal|title=Phase Transitions of Liquid Crystal PAA in Confined Geometries|author1=Shao, Y. |author2=Zerda, T. W. |journal=Journal of Physical Chemistry B|year=1998|volume=102|issue=18|pages=3387–3394|doi=10.1021/jp9734437}}</ref> PAA has played an important role in the development of ]s.<ref>''Liquid Gold: The Story of Liquid Crystal Displays and the Creation of an Industry'', Joseph A. Castellano, {{ISBN|978-981-238-956-5}}</ref> |
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Its liquid crystal range is from 118 °C to 136 °C. The solid to nematic transition is at 118 °C and the nematic to isotropic liquid transition at 136 °C.<ref name="Shao"/> |
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Its liquid crystal range is from 118 °C to 136 °C. The solid to ] ] is at 118 °C and the nematic to ] liquid transition at 136 °C.<ref name="Shao"/> |
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==References== |
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==References== |
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