| Revision as of 13:48, 6 December 2011 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 444099818 of page Sec-Butylamine for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 10:55, 1 July 2024 edit Michael D. Turnbull (talk | contribs)Extended confirmed users13,731 edits Undid revision 1231982200 by 2.101.54.127 (talk) WP:BANREVERTTag: Undo |
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{{DISPLAYTITLE:''sec''-Butylamine}} |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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{{Use dmy dates|date=September 2020}} |
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{{chembox |
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{{Chembox |
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| verifiedrevid = 444097918 |
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| Verifiedfields = changed |
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| Name = ''sec''-Butylamine |
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| Watchedfields = changed |
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| ImageFile = Sec-butylamine.svg |
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| verifiedrevid = 464388153 |
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| ImageSize = 120px |
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| ImageName = ''sec''-butylamine |
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| Name = ''sec''-Butylamine |
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| ImageFile = 2-Aminobutane Racemate Structural Formulae V.1.svg |
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| IUPACName = butan-2-amine |
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| ImageFile_Ref = {{chemboximage|correct|??}} |
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| OtherNames = 2-Butanamine<br />s-Butylamine<br />2-Aminobutane<br />2-AB<br />DL-sec-Butylamine<br />(+-)-sec-Butylamine<br />Mono-sec-butylamine<ref></ref><br />deccotane<br />frucote<br />1-methylpropylamine<br />tutane<br />butafume<ref></ref> |
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| ImageSize = 250 |
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| Section1 = {{Chembox Identifiers |
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| ImageName = Skeletal formula of sec-butylamine |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| ImageFile1 = |
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| UNII = QAZ452YGSG |
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| SMILES = NC(C)CC |
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| ImageSize1 = 150 |
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| ImageName1 = Space-filling model of ''sec''-Butylamine |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| PIN = Butan-2-amine |
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| ChemSpiderID = 23255 |
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| OtherNames = {{Unbulleted list|2-Aminobutane|2-Butanamine|(±)-''sec''-Butylamine|<small>DL</small>-''sec''-Butylamine|1-Methylpropylamine|Mono-''sec''-butylamine |
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}} |
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|Section1={{Chembox Identifiers |
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| Abbreviations = 2-AB |
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| CASNo = 13952-84-6 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo1 = 13250-12-9 |
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| CASNo1_Ref = {{cascite|correct|CAS}} |
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| CASNo1_Comment = (''R'') |
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| CASNo2 = 513-49-5 |
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| CASNo2_Ref = {{cascite|correct|CAS}} |
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| CASNo2_Comment = (''S'') |
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| PubChem = 24874 |
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| PubChem = 24874 |
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| PubChem1 = 2724537 |
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| InChI = 1/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3 |
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| PubChem1_Comment = (''R'') |
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| InChIKey = BHRZNVHARXXAHW-UHFFFAOYAA |
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| PubChem2 = 6713753 |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| PubChem2_Comment = (''S'') |
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| ChemSpiderID = 23255 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID1 = 2006669 |
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| ChemSpiderID1_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID1_Comment = (''R'') |
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| ChemSpiderID2 = 5145745 |
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| ChemSpiderID2_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID2_Comment = (''S'') |
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| UNII = QAZ452YGSG |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII1_Ref = {{fdacite|correct|FDA}} |
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| UNII1 = 29HC5ICB6K |
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| UNII1_Comment = (''R'') |
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| UNII2_Ref = {{fdacite|correct|FDA}} |
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| UNII2 = Z192XWH21O |
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| UNII2_Comment = (''S'') |
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| EINECS = 237-732-7 |
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| UNNumber = 2733 |
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| ChEBI_Ref = {{ebicite|changed|EBI}} |
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| ChEBI = 74526 |
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| KEGG = C18706 |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| Beilstein = 1361345, 1718761 (''R''), 1718760 (''S'') |
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| SMILES = CCC(C)N |
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| StdInChI = 1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3 |
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| StdInChI = 1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = BHRZNVHARXXAHW-UHFFFAOYSA-N |
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| StdInChIKey = BHRZNVHARXXAHW-UHFFFAOYSA-N |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| CASNo = 13952-84-6 |
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| RTECS = EO3325000 |
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}} |
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| RTECS = |
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|Section2={{Chembox Properties |
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| UNNumber =<!-- UN 1125 --> |
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| C=4 | H=11 | N=1 |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
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| Appearance = Colorless liquid |
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| KEGG = C18706 |
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| Odor = Fishy, ammoniacal |
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}} |
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| Density = 0.724 g cm<sup>−3</sup> |
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| Section2 = {{Chembox Properties |
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| MeltingPtK = 168.65 |
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| Formula = C<sub>4</sub>H<sub>11</sub>N |
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| BoilingPtK = 336 |
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| MolarMass = 73.14 g/mol |
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| Solubility = ]<ref>{{Cite web|url=http://www.inchem.org/documents/icsc/icsc/eics0401.htm|title=ICSC 0401 - sec-BUTYLAMINE}}</ref> |
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| Appearance = colorless liquid with amine odor |
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| RefractIndex = 1.3928 |
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| Density = 0.724 g/cm<sup>3</sup>, liquid |
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| Viscosity = 500 μPa s (at 20 °C) |
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| Solubility = highly soluble |
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}} |
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| MeltingPtC = -72 |
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|Section3={{Chembox Thermochemistry |
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| BoilingPtC = 63 |
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| DeltaHf = −138.5 to −136.5 kJ mol<sup>−1</sup> |
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| Refractive Index = 1.3932 |
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| DeltaHc = −3.0095 to −3.0077 MJ mol<sup>−1</sup> |
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| pKa = 10.56<ref>Hall, H.K., ''J. Am. Chem. Soc.'', '''1957''', ''79'', 5441.</ref> |
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}} |
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| Viscosity =<!-- 0.5 ] at 20 °C --> |
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|Section4={{Chembox Hazards |
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}} |
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| GHSPictograms = {{GHS flame}} {{GHS corrosion}} {{GHS exclamation mark}} {{GHS environment}} |
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| Section7 = {{Chembox Hazards |
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| GHSSignalWord = '''DANGER''' |
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| ExternalMSDS =<!-- --> |
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| HPhrases = {{H-phrases|225|302|314|332|400}} |
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| MainHazards = Corrosive, Highly Flammable |
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| PPhrases = {{P-phrases|210|273|280|305+351+338|310}} |
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| NFPA-H = 3 |
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| NFPA-R = 0 |
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| NFPA-H = 3 |
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| NFPA-F = 3 |
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| NFPA-R = 0 |
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| FlashPt = -19 °C |
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| NFPA-F = 3 |
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| FlashPtC = 19 |
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| RSPhrases =<!-- ]: {{R11}} {{R35}} {{R20}} {{R21}} {{R22}}<br /> ]: {{S3}} {{S16}} {{S26}} {{S29}} {{S45}} {{S36}} {{S37}} {{S39}} --> |
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| LD50 = {{Unbulleted list|152 mg kg<sup>−1</sup> <small>(oral, rat)</small>|2.5 g kg<sup>−1</sup> <small>(dermal, rabbit)</small>}} |
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}} |
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}} |
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| Section8 = {{Chembox Related |
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|Section5={{Chembox Related |
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| OtherCpds = ]<br />]<br />]<br />]<br />] |
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| OtherFunction_label = alkanamines |
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}} |
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| OtherFunction = {{Unbulleted list|]|]|]|]|]}} |
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| OtherCompounds = ] |
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}} |
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}} |
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'''''sec''-Butylamine''' is an organic chemical compound (specifically, an ]) with the formula CH<sub>3</sub>CH<sub>2</sub>CH(NH<sub>2</sub>)CH<sub>3</sub>. It is a colorless liquid. ''sec''-Butylamine is one of the four isomeric amines of ], the others being ], ], and ]. ''sec''-Butylamine is ] and therefore can exist in either of two ]ic forms. |
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''sec''-Butylamine is used in the production of some pesticides.<ref name=Ullmann>{{Ullmann|first1=Karsten|last1=Eller|first2=Erhard|last2=Henkes|first3=Roland|last3=Rossbacher|first4=Hartmut|last4=Höke|title=Amines, Aliphatic|year=2005|doi=10.1002/14356007.a02_001}}</ref> |
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:], is produced from ''sec''-butylamine.<ref name="EPA">United States Environmental Protection Agency. "Bromacil". 1996, pp. 1–11. Accessed 9 October 2012</ref>]] |
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==Safety== |
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The ] (rat) for primary alkylamines is 100 – 1 mg/kg.<ref name=Ullmann/> |
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==References== |
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{{Reflist}} |
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{{DEFAULTSORT:Butylamine, sec-}} |
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] |
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] |