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Tellurium trioxide: Difference between revisions

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Revision as of 08:05, 17 February 2011 editRjwilmsiBot (talk | contribs)Bots, Pending changes reviewers1,602,950 editsm Per WP:ISBN formatted 3 ISBNs using AWB (7596)← Previous edit Latest revision as of 07:58, 24 September 2023 edit undoMasterTriangle12 (talk | contribs)Extended confirmed users1,291 editsm PreparationTag: Visual edit 
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{{chembox {{chembox
| verifiedrevid = 401619203 | verifiedrevid = 414397405
| ImageFile | ImageFile =
| ImageSize = | ImageSize =
| ImageName = | ImageName =
| OtherNames = tellurium(VI) oxide | OtherNames = tellurium(VI) oxide
| Section1 = {{Chembox Identifiers | Section1 = {{Chembox Identifiers
| CASNo = 13451-18-8
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = GC5SXW83F8
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 75319 | ChemSpiderID = 75319
| EC_number = 236-620-5
| PubChem = 83481 | PubChem = 83481
| InChI = 1/O3Te/c1-4(2)3 | InChI = 1/O3Te/c1-4(2)3
| InChIKey = IIXQANVWKBCLEB-UHFFFAOYAH | InChIKey = IIXQANVWKBCLEB-UHFFFAOYAH
| SMILES = O=(=O)=O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/O3Te/c1-4(2)3 | StdInChI = 1S/O3Te/c1-4(2)3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = IIXQANVWKBCLEB-UHFFFAOYSA-N | StdInChIKey = IIXQANVWKBCLEB-UHFFFAOYSA-N
| CASNo = 13451-18-8 | SMILES = O=(=O)=O
}} }}
| Section2 = {{Chembox Properties | Section2 = {{Chembox Properties
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| MolarMass = 175.6 g/mol | MolarMass = 175.6 g/mol
| Appearance = yellow-orange crystals (α-TeO<sub>3</sub>) | Appearance = yellow-orange crystals (α-TeO<sub>3</sub>)
| Density = 5.07 g/cm³, solid | Density = 5.07 g/cm<sup>3</sup>, solid
| MeltingPt = 430°C | MeltingPtC = 430
| BoilingPt = | BoilingPt =
}} }}
| Section3 = {{Chembox Structure
| CrystalStruct =
}}
| ]
|
|-
-->
| Section7 = {{Chembox Hazards | Section7 = {{Chembox Hazards
| EUClass = not listed
}} }}
}} }}
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==Polymorphs== ==Polymorphs==
There are two forms, yellow-red α-TeO<sub>3</sub> and grey, rhombohedral, β-TeO<sub>3</sub> which is less reactive.<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref><br /> There are two forms, yellow-red α-TeO<sub>3</sub> and grey, rhombohedral, β-TeO<sub>3</sub> which is less reactive.<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 {{ISBN|0-12-352651-5}}</ref><br />
α-TeO<sub>3</sub> has a structure similar to ] with octahedral TeO<sub>6</sub> units that share all vertices.<ref name= "Greenwood">{{Greenwood&Earnshaw}}</ref> <br /> α-TeO<sub>3</sub> has a structure similar to ] with octahedral TeO<sub>6</sub> units that share all vertices.<ref name= "Greenwood">{{Greenwood&Earnshaw}}</ref>


==Preparation== ==Preparation==
α-TeO3 can be prepared by heating ], Te(OH)<sub>6</sub> at over 300°C .<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref> The β-TeO<sub>3</sub> form can be prepared by heating α-TeO<sub>3</sub> in a sealed tube with O<sub>2</sub> and H<sub>2</sub>SO<sub>4</sub>.<br /> α-TeO<sub>3</sub> can be prepared by heating ], Te(OH)<sub>6</sub>, at over 300&nbsp;°C.<ref name="Wiberg&Holleman"/> The β-TeO<sub>3</sub> form can be prepared by heating α-TeO<sub>3</sub> in a sealed tube with O<sub>2</sub> and H<sub>2</sub>SO<sub>4</sub>.<br />
α-TeO<sub>3</sub> is unreactive to water but is a powerful oxidising agent when heated.<ref name= "Greenwood"/> With alkalis it forms tellurates.<ref name= "Greenwood"/><br /> α-TeO<sub>3</sub> is unreactive to water but is a powerful oxidising agent when heated.<ref name= "Greenwood"/> With alkalis it forms ].<ref name= "Greenwood"/><br />
α-TeO<sub>3</sub> when heated loses oxygen to form firstly Te<sub>2</sub>O<sub>5</sub> and then ].<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref> α-TeO<sub>3</sub> when heated loses oxygen to form firstly Te<sub>2</sub>O<sub>5</sub> and then ].<ref name="Wiberg&Holleman"/>


==References== ==References==
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{{Tellurium compounds}} {{Tellurium compounds}}
{{Oxides}}


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{{inorganic-compound-stub}}
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