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{{chembox |
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{{chembox |
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| verifiedrevid = 401619203 |
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| verifiedrevid = 414397405 |
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| ImageFile |
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| ImageFile = |
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| ImageSize = |
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| ImageSize = |
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| ImageName = |
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| ImageName = |
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| OtherNames = tellurium(VI) oxide |
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| OtherNames = tellurium(VI) oxide |
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| Section1 = {{Chembox Identifiers |
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| Section1 = {{Chembox Identifiers |
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| CASNo = 13451-18-8 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = GC5SXW83F8 |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 75319 |
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| ChemSpiderID = 75319 |
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| EC_number = 236-620-5 |
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| PubChem = 83481 |
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| PubChem = 83481 |
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| InChI = 1/O3Te/c1-4(2)3 |
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| InChI = 1/O3Te/c1-4(2)3 |
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| InChIKey = IIXQANVWKBCLEB-UHFFFAOYAH |
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| InChIKey = IIXQANVWKBCLEB-UHFFFAOYAH |
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| SMILES = O=(=O)=O |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChI = 1S/O3Te/c1-4(2)3 |
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| StdInChI = 1S/O3Te/c1-4(2)3 |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
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| StdInChIKey = IIXQANVWKBCLEB-UHFFFAOYSA-N |
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| StdInChIKey = IIXQANVWKBCLEB-UHFFFAOYSA-N |
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| CASNo = 13451-18-8 |
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| SMILES = O=(=O)=O |
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| Section2 = {{Chembox Properties |
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| Section2 = {{Chembox Properties |
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| MolarMass = 175.6 g/mol |
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| MolarMass = 175.6 g/mol |
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| Appearance = yellow-orange crystals (α-TeO<sub>3</sub>) |
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| Appearance = yellow-orange crystals (α-TeO<sub>3</sub>) |
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| Density = 5.07 g/cm³, solid |
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| Density = 5.07 g/cm<sup>3</sup>, solid |
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| MeltingPt = 430°C |
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| MeltingPtC = 430 |
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| Section3 = {{Chembox Structure |
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| Section7 = {{Chembox Hazards |
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| Section7 = {{Chembox Hazards |
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| EUClass = not listed |
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==Polymorphs== |
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==Polymorphs== |
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There are two forms, yellow-red α-TeO<sub>3</sub> and grey, rhombohedral, β-TeO<sub>3</sub> which is less reactive.<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref><br /> |
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There are two forms, yellow-red α-TeO<sub>3</sub> and grey, rhombohedral, β-TeO<sub>3</sub> which is less reactive.<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 {{ISBN|0-12-352651-5}}</ref><br /> |
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α-TeO<sub>3</sub> has a structure similar to ] with octahedral TeO<sub>6</sub> units that share all vertices.<ref name= "Greenwood">{{Greenwood&Earnshaw}}</ref> <br /> |
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α-TeO<sub>3</sub> has a structure similar to ] with octahedral TeO<sub>6</sub> units that share all vertices.<ref name= "Greenwood">{{Greenwood&Earnshaw}}</ref> |
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==Preparation== |
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==Preparation== |
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α-TeO3 can be prepared by heating ], Te(OH)<sub>6</sub> at over 300°C .<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref> The β-TeO<sub>3</sub> form can be prepared by heating α-TeO<sub>3</sub> in a sealed tube with O<sub>2</sub> and H<sub>2</sub>SO<sub>4</sub>.<br /> |
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α-TeO<sub>3</sub> can be prepared by heating ], Te(OH)<sub>6</sub>, at over 300 °C.<ref name="Wiberg&Holleman"/> The β-TeO<sub>3</sub> form can be prepared by heating α-TeO<sub>3</sub> in a sealed tube with O<sub>2</sub> and H<sub>2</sub>SO<sub>4</sub>.<br /> |
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α-TeO<sub>3</sub> is unreactive to water but is a powerful oxidising agent when heated.<ref name= "Greenwood"/> With alkalis it forms tellurates.<ref name= "Greenwood"/><br /> |
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α-TeO<sub>3</sub> is unreactive to water but is a powerful oxidising agent when heated.<ref name= "Greenwood"/> With alkalis it forms ].<ref name= "Greenwood"/><br /> |
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α-TeO<sub>3</sub> when heated loses oxygen to form firstly Te<sub>2</sub>O<sub>5</sub> and then ].<ref name = "Wiberg&Holleman">''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5</ref> |
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α-TeO<sub>3</sub> when heated loses oxygen to form firstly Te<sub>2</sub>O<sub>5</sub> and then ].<ref name="Wiberg&Holleman"/> |
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==References== |
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==References== |
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{{Tellurium compounds}} |
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{{Tellurium compounds}} |
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{{Oxides}} |
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{{inorganic-compound-stub}} |
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{{inorganic-compound-stub}} |
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