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| Name = Terbium(III) chloride |
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| ImageFileL1 = UCl3.png |
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| verifiedrevid = 312039212 |
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| Name = Terbium(III) chloride |
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| ImageFileL1 = UCl3 without caption.png |
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| ImageFileR1 = Cerium bromide (space filling) 2.png |
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| ImageFileR1 = Cerium bromide (space filling) 2.png |
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| ImageName = Terbium(III) chloride |
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| ImageFile2 = Terbium(III) chloride hexahydrate.jpg |
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| ImageName = Terbium(III) chloride |
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| OtherNames = terbium trichloride |
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| OtherNames = terbium trichloride |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo = 10042-88-3 |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 10042-88-3 |
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| UNII_Ref = {{fdacite|changed|FDA}} |
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| UNII = 804HI855F8 |
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| PubChem = 61458 |
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| EINECS = 233-132-4 |
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| InChI = 1S/3ClH.Tb/h3*1H;/q;;;+3/p-3 |
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| SMILES = Cl(Cl)Cl |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = TbCl<sub>3</sub> |
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| Formula = TbCl<sub>3</sub> |
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| MolarMass = 265.2834 g/mol |
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| MolarMass = 265.2834 g/mol |
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| Appearance = white powder |
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| Appearance = white powder |
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| Density = 4.35 g/cm³, solid |
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| Density = 4.35 g/cm<sup>3</sup>, solid |
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| Solubility = soluble |
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| Solubility = soluble |
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| MeltingPt = 558°C |
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| MeltingPtC = 558 |
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| BoilingPt = 180-200°C (in ] gas atmosphere) |
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| BoilingPtC = 180 to 200 |
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| BoilingPt_notes = (in ] gas atmosphere) |
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| Section3 = {{Chembox Structure |
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|Section3={{Chembox Structure |
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| Coordination = Tricapped trigonal prismatic<br />(nine-coordinate) |
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| Coordination = Tricapped trigonal prismatic<br />(nine-coordinate) |
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| CrystalStruct = ] (]), ] |
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| CrystalStruct = ] (]), ] |
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| SpaceGroup = P6<sub>3</sub>/m, No. 176 |
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| SpaceGroup = P6<sub>3</sub>/m, No. 176 |
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| Section7 = {{Chembox Hazards |
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|Section7={{Chembox Hazards |
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| GHS_ref = <ref>GHS: </ref> |
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| EUClass = not listed |
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| GHSPictograms = {{GHS07}} |
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| GHSSignalWord = warning |
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| HPhrases = {{HPhrases|H315 | H319}} |
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| PPhrases = {{PPhrases|P302 + P352 | P305 + P351 + P338}} |
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|Section8={{Chembox Related |
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| OtherAnions = ] |
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| OtherCations = ]<br>] |
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'''Terbium(III) chloride''' (]]) is a ]. In the solid state TbCl<sub>3</sub> has the ] layer structure.<ref> Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications ISBN 0-19-855370-6 </ref> Terbium(III) chloride frequently forms a hexahydrate. |
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'''Terbium(III) chloride''' (]]) is a ]. In the solid state TbCl<sub>3</sub> has the ] layer structure.<ref>Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications {{ISBN|0-19-855370-6}}</ref> Terbium(III) chloride frequently forms a hexahydrate. |
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==Hazards== |
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== Preparation == |
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The hexahydrate of terbium(III) chloride can be obtained by the reaction of ] and ]:<ref name = Xu>{{cite journal | doi = 10.1016/S1002-0721(08)60253-7 | author = XU Lijuan (许丽娟), LI Yanqiu (李艳秋), LI Xia (李 夏) | title = Synthesis, crystal structure and characterization of one-dimension complex constructed by terbium(III) and 2-iodobenzoate | journal = ] | volume = 27 | pages = 372–375 | year = 2009 | issue = 3| bibcode = 2009JREar..27..372X }}</ref> |
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Terbium(III) chloride causes ] of the ].<ref>{{cite book |
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| title = Ophthalmic toxicology |
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:Tb<sub>2</sub>O<sub>3</sub> + 6 HCl → 2 TbCl<sub>3</sub> + 3 H<sub>2</sub>O |
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| author = George C. Y. Chiou |
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| edition = 2nd |
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It can also be obtained by direct reaction of the elements:<ref>Webelements: </ref> |
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| publisher = CRC Press |
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| year = 1999 |
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:2 Tb + 3 Cl<sub>2</sub> → 2 TbCl<sub>3</sub> |
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| isbn = 1560327227 |
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}}</ref> |
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== Properties == |
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Terbium(III) chloride is a white, ] powder.<ref>{{Cite book |title=CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data |date=2006 |publisher=CRC, Taylor & Francis |isbn=978-0-8493-0487-3 |editor-last=Lide |editor-first=David R. |edition=87. ed., 2006-2007 |location=Boca Raton, Fla. |editor-last2=CRC Press}}</ref> It crystallizes in an ] ] crystal structure with ] Cmcm (No. 63).<ref>{{Cite book |last=Paetzold |first=Peter |url=https://books.google.com/books?id=rVuSsDZr5CAC&pg=PA204 |title=Chemie: Eine Einführung |date=2009-09-10 |publisher=Walter de Gruyter |isbn=978-3-11-021135-1 |language=de}}</ref><ref>{{Cite book |title=Metals |publisher=Reidel |isbn=978-90-277-2385-7 |editor-last=Trotter |editor-first=J. |series=Structure reports A |date=30 November 1986 |location=Dordrecht}}</ref> It can form a complex Tb(gly)<sub>3</sub>Cl<sub>3</sub>·3H<sub>2</sub>O with glycine.<ref>郑平, 陈文生, 张洪权,等. 量热法测定氯化铽甘氨酸配合物及其配离子的标准生成焓. 湖北大学学报(自科版), 2011, 33(3):270-274.</ref> |
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== Applications == |
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The hexahydrate plays an important role as an activator of green ]s in color TV tubes and is also used in specialty lasers and as a ] in ]s.<ref>METALL RARE EARTH LIMITED: </ref> |
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== Hazards == |
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Terbium(III) chloride causes ] of the ].<ref>{{cite book| title = Ophthalmic toxicology| author = George C. Y. Chiou| edition = 2nd| publisher = CRC Press| year = 1999| isbn = 1-56032-722-7}}</ref> |
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Conditions/substances to avoid are: ], ]s and acid fumes. |
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Conditions/substances to avoid are: ], ]s and acid fumes. |
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==References== |
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== References == |
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{{reflist}} |
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{{reflist}} |
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{{Terbium compounds}} |
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{{Terbium compounds}} |
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{{Chlorides}} |
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{{Lanthanide halides}} |
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] |
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] |
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] |
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] |
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] |
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] |
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{{inorganic-compound-stub}} |
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