Revision as of 12:36, 10 January 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 406832303 of page Tetraethylgermanium for the Chem/Drugbox validation project (updated: 'CASNo'). |
Latest revision as of 00:50, 4 September 2023 edit 2405:4802:1f94:64e0:18b6:788d:c0f1:3a0 (talk)No edit summary |
Line 1: |
Line 1: |
|
{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
|
|
{{Chembox |
|
{{Chembox |
|
|
| Verifiedfields = changed |
⚫ |
| verifiedrevid = 401622463 |
|
|
|
| Watchedfields = changed |
⚫ |
| ImageFile = Tetraethylgermanium.svg |
|
|
⚫ |
| verifiedrevid = 470603839 |
⚫ |
| ImageFile_Ref = {{Chemboximage|correct|??}} |
|
|
⚫ |
| ImageFileL1 = Tetraethylgermanium.svg |
|
| ImageSize = 121 |
|
|
⚫ |
| ImageFileL1_Ref = {{Chemboximage|correct|??}} |
⚫ |
| ImageName = Structural formula of tetraethylgermanium |
|
|
|
| ImageSizeL1 = 125 |
⚫ |
| IUPACName = Tetraethylgermanium |
|
|
⚫ |
| ImageAltL1 = Structural formula of tetraethylgermanium |
|
⚫ |
| ImageFileR1 = Tetraethylgermanium-3D-balls.png |
|
|
| ImageSizeR1 = 135 |
|
|
| ImageAltR1 = Ball-and-stick model of the tetraethylgermanium molecule |
|
|
| PIN = Tetraethylgermane |
|
| SystematicName = <!-- Tetraethylgermane (substitutive) OR Tetraethylgermanium (additive) --> |
|
| SystematicName = <!-- Tetraethylgermane (substitutive) OR Tetraethylgermanium (additive) --> |
|
|
| OtherNames = |
|
| Section1 = {{Chembox Identifiers |
|
|Section1={{Chembox Identifiers |
|
| Abbreviations = TEG |
|
| Abbreviations = TEG |
|
| CASNo = <!-- blanked - oldvalue: 597-63-7 --> |
|
|
| CASNo_Ref = {{cascite|correct|??}} |
|
| CASNo = 597-63-7 |
|
|
| CASNo_Ref = {{cascite|correct|CAS}} |
|
| PubChem = 11703 |
|
| PubChem = 11703 |
|
⚫ |
| ChemSpiderID = 11211 |
|
| PubChem_Ref = {{Pubchemcite|correct|PubChem}} |
|
|
⚫ |
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
⚫ |
| ChemSpiderID = 11211 |
|
|
|
| EINECS = 209-905-7 |
⚫ |
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
|
|
| EINECS = 209-905-7 |
|
| UNNumber = 1993 |
|
| UNNumber = 1993 |
|
| RTECS = LY5290000 |
|
⚫ |
| SMILES = CC(CC)(CC)CC |
|
| RTECS = LY5290000 |
|
|
⚫ |
| StdInChI = 1S/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3 |
⚫ |
| SMILES = CC(CC)(CC)CC |
|
|
⚫ |
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
⚫ |
| StdInChI = 1S/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3 |
|
|
⚫ |
| InChI = 1/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3 |
⚫ |
| StdInChI_Ref = {{stdinchicite|correct|chemspider}} |
|
|
⚫ |
| StdInChIKey = QQXSEZVCKAEYQJ-UHFFFAOYSA-N |
⚫ |
| InChI = 1/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3 |
|
|
⚫ |
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
⚫ |
| StdInChIKey = QQXSEZVCKAEYQJ-UHFFFAOYSA-N |
|
|
⚫ |
| InChIKey = QQXSEZVCKAEYQJ-UHFFFAOYAH}} |
⚫ |
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |
|
|
⚫ |
|Section2={{Chembox Properties |
⚫ |
| InChIKey = QQXSEZVCKAEYQJ-UHFFFAOYAH}} |
|
|
⚫ |
| C = 8 |
⚫ |
| Section2 = {{Chembox Properties |
|
|
| C = 8 |
|
| H = 20 |
|
| H = 20 |
|
| Ge = 1 |
|
⚫ |
| Appearance = Colourless liquid |
⚫ |
| Ge = 1 |
|
|
| ExactMass = 190.077678853 g mol<sup>-1</sup> |
|
| Density = 0.998 g cm<sup>−3</sup> |
|
|
| BoilingPtC = 163 to 165}} |
⚫ |
| Appearance = Colourless liquid |
|
|
⚫ |
|Section3={{Chembox Hazards |
|
| Density = 0.998 g cm<sup>-3</sup> |
|
|
|
| GHSPictograms = {{GHS02}}{{GHS07}} |
|
| BoilingPtCL = 163 |
|
|
|
| GHSSignalWord = Warning |
|
| BoilingPtCH = 165}} |
|
|
|
| HPhrases = {{H-phrases|226|302|315|319|335}} |
⚫ |
| Section3 = {{Chembox Hazards |
|
|
|
| PPhrases = {{P-phrases|210|233|240|241|242|243|261|264|270|271|280|301+312|302+352|303+361+353|304+340|305+351+338|312|321|330|332+313|337+313|362|370+378|403+233|403+235|405|501}} |
|
| EUClass = {{Hazchem Xn}} |
|
|
⚫ |
| NFPA-H = 2 |
|
| RPhrases = {{R10}}, {{R22}}, {{R36/37/38}} |
|
|
|
| NFPA-F = 3 |
|
| SPhrases = {{S16}}, {{S26}}, {{S36}} |
|
|
| NFPA-H = 2 |
|
| NFPA-R = 2 |
|
| NFPA-F = 3 |
|
| FlashPtC = 35}} |
|
⚫ |
|Section4={{Chembox Related |
⚫ |
| NFPA-R = 2 |
|
|
|
| OtherCompounds = {{unbulleted list|]|]|]|]}} |
|
| FlashPt = 35 °C}} |
|
⚫ |
| Section4 = {{Chembox Related |
|
|
| OtherCpds = ]<br /> |
|
|
]}} |
|
|
}} |
|
}} |
|
|
}} |
|
|
'''Tetraethylgermanium''' (IUPAC name: '''tetraethylgermane'''), abbreviated TEG, is an ] with the formula (])<sub>4</sub>]. Tetraethylgermanium is an important ] used in vapour deposition of germanium which is in a tetrahedral shape. |
|
|
|
|
|
==Synthesis== |
|
|
] first reported the compound in 1887 from ] and ], shortly after germanium was discovered in 1887.<ref name=Winkle2> {{cite journal | author = Clemens Winkler | journal = J. Prak. Chemie | volume = 36 | year = 1887 |pages = 177–209 | title = Mittheilungen über des Germanium. Zweite Abhandlung |doi = 10.1002/prac.18870360119 | url = http://gallica.bnf.fr/ark:/12148/bpt6k90799n/f183.table| accessdate = 2008-08-20}}</ref> |
|
|
|
|
|
==References== |
|
|
{{Reflist}} |
|
|
|
|
|
==External links== |
|
|
* Tetraethylgermanium |
|
|
|
|
|
] |
|
|
] |