| Revision as of 04:53, 17 February 2012 editBeetstra (talk | contribs)Edit filter managers, Administrators172,031 edits Saving copy of the {{chembox}} taken from revid 477243716 of page Tin(II)_sulfate for the Chem/Drugbox validation project (updated: ''). |
Latest revision as of 19:08, 10 December 2024 edit Marbletan (talk | contribs)Extended confirmed users5,452 edits no longer a stub |
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{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid of page ] with values updated to verified values.}} |
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| verifiedrevid = 405329170 |
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| Name = Tin(II) sulfate |
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| verifiedrevid = 477315237 |
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| ImageFile = |
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| Name = Tin(II) sulfate |
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| ImageName = Tin(II) sulfate |
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| ImageFile = Zinn(II)-sulfat.png |
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| ImageAlt = Tin(II) sulfate crystallizes in an heavily distorted barium sulfrate structure. |
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| OtherNames = Stannous sulfate |
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| ImageCaption = Unit cell of tin(II) sulfate. |
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| Section1 = {{Chembox Identifiers |
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| ImageName = Tin(II) sulfate |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| OtherNames = Stannous sulfate |
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|Section1={{Chembox Identifiers |
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} |
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| ChemSpiderID = 21106484 |
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| ChemSpiderID = 21106484 |
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| InChI = 1/H2O4S.Sn.2H/c1-5(2,3)4;;;/h(H2,1,2,3,4);;;/q;+2;;/p-2/rH2O4S.H2Sn/c1-5(2,3)4;/h(H2,1,2,3,4);1H2/q;+2/p-2 |
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| InChI = 1/H2O4S.Sn.2H/c1-5(2,3)4;;;/h(H2,1,2,3,4);;;/q;+2;;/p-2/rH2O4S.H2Sn/c1-5(2,3)4;/h(H2,1,2,3,4);1H2/q;+2/p-2 |
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| StdInChIKey = RCIVOBGSMSSVTR-UHFFFAOYSA-L |
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| StdInChIKey = RCIVOBGSMSSVTR-UHFFFAOYSA-L |
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| CASNo = 7488-55-3 |
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| CASNo = 7488-55-3 |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| EINECS = 231-302-2 |
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| PubChem = 24854690 |
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| UNII = 0MFE10J96E |
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| EINECS = 231-302-2 |
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| PubChem = 62643 |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = SnSO<sub>4</sub> |
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| Formula = SnSO<sub>4</sub> |
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| MolarMass = 214.77 g/mol |
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| MolarMass = 214.773 g/mol |
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| Appearance = white-yellowish crystalline solid <br> ] |
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| Appearance = white-yellowish crystalline solid <br> ] |
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| Density = 4.15 g/cm<sup>3</sup> |
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| Density = 4.15 g/cm<sup>3</sup> |
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| Solubility = 33g/100mL water (25°C) |
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| Solubility = 33 g/100 mL (25 °C) |
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| MeltingPt = 378 °C |
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| MeltingPtC = 378 |
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| BoilingPt = decomposes to ] and ] |
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| BoilingPt = decomposes to ] and ] |
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| Section7 = {{Chembox Hazards |
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|Section3={{Chembox Structure |
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|Structure_ref = <ref name="ReferenceA">{{Cite journal|doi=10.1107/S0567740872003322|title=The crystal structure of tin(II) sulphate|year=1972|last1=Donaldson|first1=J. D.|last2=Puxley|first2=D. C.|journal=Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry|volume=28|issue=3|pages=864–867|bibcode=1972AcCrB..28..864D }}</ref> |
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| EUIndex = Not listed |
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|CrystalStruct = Primitive ] |
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| NFPA-H = 1 |
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|LattConst_a = 8.80 Å |
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| NFPA-F = 0 |
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|LattConst_b = 5.32 Å |
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| NFPA-R = 0 |
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|LattConst_c = 7.12 Å |
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| FlashPt = Non-flammable |
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|LattConst_ref = <ref name="ReferenceA">{{Cite journal|doi=10.1107/S0567740872003322|title=The crystal structure of tin(II) sulphate|year=1972|last1=Donaldson|first1=J. D.|last2=Puxley|first2=D. C.|journal=Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry|volume=28|issue=3|pages=864–867|bibcode=1972AcCrB..28..864D }}</ref> |
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|SpaceGroup = Pnma, No. 62 |
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| Section8 = {{Chembox Related |
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| OtherAnions = ], ], ] |
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|Section7={{Chembox Hazards |
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| OtherCations = ] |
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| NFPA-H = 1 |
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| Function = |
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| NFPA-F = 0 |
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| NFPA-R = 0 |
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| FlashPt = Non-flammable |
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| LD50 = 2207 mg/kg (oral, rat)<br/>2152 mg/kg (oral, mouse)<ref>{{IDLH|7440315|Tin (inorganic compounds, as Sn)}}</ref> |
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| OtherAnions = ], ], ] |
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'''Tin(II) sulfate''' (]]]) is a ]. It is a white solid that can absorb enough moisture from the air to become fully dissolved, forming an aqueous solution; this property is known as ]. It can be prepared by a displacement reaction between metallic ] and ]:<ref name="Greenwood">{{Greenwood&Earnshaw1st|page=451}}</ref> |
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:{{chem2 | Sn (s) + CuSO4 (aq) -> Cu (s) + SnSO4 (aq) }} |
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Tin(II) sulfate is a convenient source of tin(II) ions uncontaminated by tin(IV) species. |
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==Structure== |
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In the solid state the sulfate ions are linked together by O-Sn-O bridges. The tin atom has three oxygen atoms arranged pyramidally at 226 pm with the three O-Sn-O bond angles of 79°, 77.1° and 77.1°. Other Sn-O distances are longer ranging from 295 - 334pm.<ref name="Greenwood"/><ref name="DonaldsonPuxley1972">{{cite journal|last1=Donaldson|first1=J. D.|last2=Puxley|first2=D. C.|title=The crystal structure of tin(II) sulphate|journal=Acta Crystallographica Section B|volume=28|issue=3|year=1972|pages=864–867|issn=0567-7408|doi=10.1107/S0567740872003322|bibcode=1972AcCrB..28..864D }}</ref> |
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==References== |
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{{reflist}} |
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{{Tin compounds}} |
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{{Sulfates}} |
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{{sulfur compounds}} |
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] |
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] |
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] |