| Revision as of 03:28, 24 December 2009 editRjwilmsiBot (talk | contribs)Bots, Pending changes reviewers1,602,950 editsm fixing page range dashes using Project:AWB← Previous edit |
Latest revision as of 20:24, 17 January 2024 edit undoPraseodymium-141 (talk | contribs)Autopatrolled, Extended confirmed users, New page reviewers22,365 edits removed Category:Sulfides; added Category:Disulfides using HotCat |
| (32 intermediate revisions by 22 users not shown) |
| Line 1: |
Line 1: |
|
{{chembox |
|
{{chembox |
|
|
| verifiedrevid = 333719065 |
|
| Name = Zirconium(IV) sulfide |
|
| Name = Zirconium(IV) sulfide |
|
| Reference = <ref name="hand"> |
|
| Reference = <ref name="hand"> |
|
{{Citation |
|
{{Citation |
|
| last = Lide |
|
| last = Lide |
|
| first = David R. |
|
| first = David R. |
|
| author-link = |
|
| year = 1998 |
|
⚫ |
| title = Handbook of Chemistry and Physics |
|
| last2 = |
|
|
| first2 = |
|
| edition = 87 |
|
⚫ |
| location = Boca Raton, Florida |
|
| author2-link = |
|
|
⚫ |
| publisher = CRC Press |
|
| publication-date = |
|
|
|
| isbn = 0-8493-0594-2 |
|
| date = |
|
|
| year = 1998 |
|
| pages = 4–96 |
| ⚫ |
| title = Handbook of Chemistry and Physics |
|
|
| edition = 87 |
|
|
| volume = |
|
|
| series = |
|
| ⚫ |
| publication-place = Boca Raton, FL |
|
|
| place = |
|
| ⚫ |
| publisher = CRC Press |
|
|
| id = |
|
|
| isbn = 0849305942 |
|
|
| doi = |
|
|
| oclc = |
|
|
| pages = 4–96 |
|
|
| url = |
|
|
| accessdate = |
|
|
}}</ref> |
|
}}</ref> |
|
| ImageFile=Cadmium-iodide-3D-layers.png |
|
| ImageFile =Cadmium-iodide-3D-layers.png |
|
| IUPACName = Zirconium(IV) sulfide |
|
| IUPACName = Zirconium(IV) sulfide |
|
| OtherNames = |
|
| OtherNames = |
|
| Section1 = {{Chembox Identifiers |
|
|Section1={{Chembox Identifiers |
|
| CASNo = 12039-15-5 |
|
| CASNo = 12039-15-5 |
|
|
| EINECS = 234-885-1 |
|
|
| PubChem = 10219558 |
|
|
| ChemSpiderID = 8395050 |
|
|
| StdInChI=1S/2S.Zr/q2*-2;+4 |
|
|
| StdInChIKey = XWPGCGMKBKONAU-UHFFFAOYSA-N |
|
|
| SMILES = .. |
|
}} |
|
}} |
|
| Section2 = {{Chembox Properties |
|
|Section2={{Chembox Properties |
|
| Formula = ZrS<sub>2</sub> |
|
| Formula = ZrS<sub>2</sub> |
|
| MolarMass = 155.356 g/mol |
|
| MolarMass = 155.356 g/mol |
|
| Appearance = red-brown crystals |
|
| Appearance = red-brown crystals |
|
| Density = 3.82 g/cm<sup>3</sup> |
|
| Density = 3.82 g/cm<sup>3</sup> |
|
| MeltingPt = 1480°C |
|
| MeltingPtC = 1480 |
|
| BoilingPt = |
|
| BoilingPt = |
|
| Soluble = insoluble |
|
| Solubility = insoluble |
|
}} |
|
}} |
|
| Section3 = {{Chembox Structure |
|
|Section3={{Chembox Structure |
|
| Coordination = octahedral |
|
| Coordination = octahedral |
|
| CrystalStruct = ], ], SpaceGroup = P-3m1, No. 164 |
|
| CrystalStruct = ], ]|SpaceGroup = P-3m1, No. 164 |
|
| Dipole = |
|
| Dipole = |
|
}} |
|
}} |
|
| Section7 = {{Chembox Hazards |
|
|Section7={{Chembox Hazards |
|
⚫ |
| ExternalSDS = |
|
| EUClass = not listed |
|
| ⚫ |
| ExternalMSDS = |
|
|
}} |
|
}} |
|
}} |
|
}} |
|
|
'''Zirconium(IV) sulfide''' is the ] with the formula ]]. It is a violet-brown solid. It adopts a layered structure similar to that of ]. |
|
|
|
|
|
|
Like the closely related ], ZrS<sub>2</sub> is prepared by heating sulfur and zirconium metal. It can be purified by ] using iodine.<ref>Lawrence E. Conroy "Group IV Sulfides" Inorganic Synthesis 1970, XII, 158. {{doi|10.1002/9780470132432.ch28}}</ref> |
|
'''Zirconium(IV) sulfide''' (]]) is a ]. |
|
|
|
|
|
|
==References== |
|
==References== |
|
{{reflist}} |
|
{{reflist}} |
|
|
|
|
{{Zirconium compounds}} |
|
{{Zirconium compounds}} |
|
|
{{Sulfides}} |
|
|
{{sulfur compounds}} |
|
|
|
|
|
] |
|
] |
|
] |
|
] |
|
|
] |
|
|
|
|
|
|
|
|
|
{{inorganic-compound-stub}} |
|
{{inorganic-compound-stub}} |
|
|
|
|
] |
|