| Revision as of 21:07, 17 December 2010 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi← Previous edit |
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{{chembox |
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{{chembox |
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| verifiedrevid = 372450487 |
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| Watchedfields = changed |
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| verifiedrevid = 402916257 |
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| Name = Zirconium nitride |
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| Name = Zirconium nitride |
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| ImageFile =NaCl polyhedra.png |
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| ImageFile = ZrN-polyhedral.png |
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| ImageName = |
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| ImageSize = 160px |
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| ImageName = Zirconium nitride in the unit cell |
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| IUPACName = Zirconium nitride |
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| IUPACName = Zirconium nitride |
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| OtherNames = |
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| OtherNames = Zirconium(III) nitride, Nitridozirconium |
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| Section1 = {{Chembox Identifiers |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|CAS}} |
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| CASNo = 25658-42-8 |
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| CASNo = 25658-42-8 |
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| CASNo_Ref = {{cascite}} |
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| PubChem = 94359 |
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| ChEBI = 197403 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID = 85159 |
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| SMILES = N# |
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| SMILES_Comment = (Zr≡N) |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChI = 1S/N.Zr |
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| StdInChI_Comment = (Zr≡N) |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChIKey = ZVWKZXLXHLZXLS-UHFFFAOYSA-N |
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| EC_number = 247-166-2 |
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| Section2 = {{Chembox Properties |
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|Section2={{Chembox Properties |
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| Formula = ZrN |
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| Formula = ZrN<ref name=crc>{{CRC90}}</ref> |
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| Appearance = Yellow-brown crystals |
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| MolarMass = 105.23 g/mol |
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| Odor = Odorless |
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| Appearance = yellow-brown crystals |
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| Density = 7.09 g/cm<sup>3</sup> (20 °C) |
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| Density = 7.09 g/cm<sup>3</sup> (24 °C)<ref name=crc>{{CRC90}}</ref> |
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| MeltingPt = 2980 °C |
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| MeltingPtC = 2952 |
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| MeltingPt_notes = <br> at 760 mmHg<ref name=crc /> |
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| BoilingPt = |
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| Solubility = Insoluble |
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| BoilingPtC = |
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| Solubility = Insoluble |
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| SolubleOther = Soluble in concentrated ], ]s<ref name=crc /> |
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| Section3 = {{Chembox Structure |
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|Section3={{Chembox Structure |
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| CrystalStruct = ], ]<ref name=aip>{{Cite journal | doi = 10.1063/1.4879798| title = FP-LAPW investigation of electronic, magnetic, elastic and thermal properties of Fe-doped zirconium nitride| journal = AIP Advances| volume = 4| issue = 5| pages = 057121| year = 2014| last1 = Sirajuddeen | first1 = M. Md. Sheik. | last2 = Banu | first2 = I. B. S. | bibcode = 2014AIPA....4e7121S| doi-access = free}}</ref> |
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| CrystalStruct = ], ] |
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| SpaceGroup = Fm<u style="text-decoration:overline">3</u>m, No. 225 |
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| SpaceGroup = Fm{{overline|3}}m, No. 225<ref name=aip /> |
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| Coordination = Octahedral |
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| Coordination = Octahedral<ref name=aip /> |
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| LattConst_a = 4.5675 Å<ref name=aip /> |
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| LattConst_b = |
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| LattConst_c = |
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| LattConst_alpha = 90 |
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| LattConst_beta = 90 |
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| LattConst_gamma = 90 |
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| Section7 = {{Chembox Hazards |
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|Section4={{Chembox Thermochemistry |
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| DeltaHf = −365.26 kJ/mol<ref name=nist>{{nist|name=Zirconium nitride|id=C25658428|accessdate=2014-06-30|mask=FFFF|units=SI}}</ref> |
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| ExternalMSDS = |
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| Entropy = 38.83 J/mol·K<ref name=nist /> |
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| EUIndex = not listed |
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| HeatCapacity = 40.442 J/mol·K<ref name=nist /> |
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| Section8 = {{Chembox Other |
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|Section8={{Chembox Related |
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| OtherAnions = |
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| OtherAnions = |
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| OtherCations = ]<br/>] |
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| OtherCations = |
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| OtherFunction = ]<br> ]<br> ] |
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| OtherFunction_label = refractory ceramic materials |
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| Section8 = {{Chembox Related |
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| OtherAnions = |
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| OtherCations = |
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| OtherFunctn = ], ], ] |
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| Function = Refractory ceramic materials |
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'''Zirconium nitride''' ({{Zirconium}}{{Nitrogen}}) is an ] found in a variety of uses. |
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'''Zirconium nitride''' ({{chem2|auto=1|ZrN}}) is an ] used in a variety of ways due to its properties. |
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==Properties== |
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==Properties== |
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ZrN grown by ] (PVD) is a light gold color similar to elemental gold. ZrN has a room-temperature ] of 12.0 μΩ·cm, a ] of resistivity of 5.6·10<sup>−8</sup> Ω·cm/K, a ] transition temperature of 10.4 K, and a relaxed lattice parameter of 0.4575 nm. The ] of single-crystal ZrN is 22.7±1.7 GPa and ] is 450 GPa.<ref>{{Cite journal | doi = 10.1116/1.4825349| title = Physical properties of epitaxial ZrN/MgO(001) layers grown by reactive magnetron sputtering| journal = Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films| volume = 31| issue = 6| pages = 061516| year = 2013| last1 = Mei | first1 = A. B.| last2 = Howe | first2 = B. M.| last3 = Zhang | first3 = C.| last4 = Sardela | first4 = M.| last5 = Eckstein | first5 = J. N.| last6 = Hultman | first6 = L.| last7 = Rockett | first7 = A.| last8 = Petrov | first8 = I.| last9 = Greene | first9 = J. E. |
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ZrN applied by the ] coating process is a light gold color similar to elemental gold. |
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| bibcode = 2013JVSTA..31f1516M}}</ref> |
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ZrN ] below {{convert|10|K}} <ref name=nitrides>{{cite journal| doi =10.1002/sia.740150606| title =Characterization of nitrogen distribution profiles in fcc transition metal nitrides by means ofTc measurements| year =1990| author =Lengauer, Walter| journal =Surface and Interface Analysis| volume =15| pages =377 }}</ref>. |
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==Uses== |
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==Uses== |
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] |
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Zirconium nitride is a hard ceramic material similar to ] and is a cement like ] material.Thus it is used in ], ]s and laboratory ]s. When applied using the ] coating process it is commonly used for coating medical devices<ref></ref>, industrial parts (notably ]), automotive and aerospace components and other parts subject to high wear and corrosive environments.<ref></ref> |
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Zirconium nitride is a hard ceramic material similar to ] and is a cement-like ] material. Thus it is used in ]s and laboratory ]s. When applied using the ] coating process it is commonly used for coating medical devices,<ref>{{cite journal|url = https://doi.org/10.1038/s41598-018-20013-z|title = Slate, A.J., Wickens, D.J., El Mohtadi, M. et al. Antimicrobial activity of Ti-ZrN/Ag coatings for use in biomaterial applications. Sci Rep 8, 1497 (2018)| date=2018 | doi=10.1038/s41598-018-20013-z | pmid=29367635 | last1=Slate | first1=A. J. | last2=Wickens | first2=D. J. | last3=El Mohtadi | first3=M. | last4=Dempsey-Hibbert | first4=N. | last5=West | first5=G. | last6=Banks | first6=C. E. | last7=Whitehead | first7=K. A. | journal=Scientific Reports | volume=8 | issue=1 | page=1497 | pmc=5784091 }}</ref> industrial parts (notably ]), automotive and aerospace components and other parts subject to high wear and corrosive environments. |
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Zirconium nitride was suggested as a ] fuel tank liner for rockets and aircraft.<ref>{{cite patent|number = 7736751|country=US|title=Coating for components requiring hydrogen peroxide compatibility|pubdate=2010-06-15|assign=]|inventor1-last=Yousefiani |inventor1-first=Ali}}</ref> |
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==References== |
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==References== |
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{{Zirconium compounds}} |
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{{Zirconium compounds}} |
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{{Nitrides}} |
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{{inorganic-compound-stub}} |
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] |
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