Misplaced Pages

1,1'-Dihydroxydicyclohexyl peroxide

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
1,1′-Dihydroxydicyclohexyl peroxide
Names
IUPAC name 1-(1-hydroxycyclohexyl)peroxycyclohexan-1-ol
Other names Bis(1-hydroxycyclohexyl) peroxide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
EC Number
  • 219-306-2
PubChem CID
UNII
UN number 3106
CompTox Dashboard (EPA)
InChI
  • InChI=1S/C12H22O4/c13-11(7-3-1-4-8-11)15-16-12(14)9-5-2-6-10-12/h13-14H,1-10H2Key: ZPOUDMYDJJMHOO-UHFFFAOYSA-N
SMILES
  • C1CCC(CC1)(O)OOC2(CCCCC2)O
Properties
Chemical formula C12H22O4
Molar mass 230.304 g·mol
Appearance white solid
Melting point 66–68 °C (151–154 °F; 339–341 K)
Hazards
GHS labelling:
Pictograms GHS01: ExplosiveGHS05: CorrosiveGHS07: Exclamation mark
Signal word Danger
Hazard statements H240, H302, H314
Precautionary statements P210, P220, P234, P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P370+P378, P370+P380+P375, P403+P235, P405, P411, P420, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

1,1′-Dihydroxydicyclohexyl peroxide is an organic compound with the formula (C6H10OH)2O2. It is one of the peroxides derived from the reaction of cyclohexanone and hydrogen peroxide. Upon treatment with acid and additional peroxide, it converts to the cyclic diperoxide, bis(cyclohexylidene peroxide), (C6H10)2(O2)2.

1,1′-Dihydroxydicyclohexyl peroxide is a catalyst for radical-initiated vulcanization.

References

  1. Story, Paul R.; Lee, Bunge; Bishop, Clyde E.; Denson, Donald D.; Busch, Peter (1970). "Macrocyclic Synthesis. II. Cyclohexanone Peroxides". The Journal of Organic Chemistry. 35 (9): 3059–3062. doi:10.1021/jo00834a042.
  2. McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J. (1980). "Ketone-Derived Peroxides. Part 1. Synthetic Methods". Journal of Chemical Research, Synopses: 34.
Categories: