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1-Hexadecene

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1-Hexadecene
Names
Preferred IUPAC name Hexadec-1-ene
Other names 1-Hexadecene; Cetene; 1-Cetene; Hexadecylene-1
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.010.097 Edit this at Wikidata
EC Number
  • 211-105-8
PubChem CID
UNII
CompTox Dashboard (EPA)
SMILES
  • CCCCCCCCCCCCCCC=C
Properties
Chemical formula C16H32
Molar mass 224.432 g·mol
Appearance Colorless liquid
Density 0.781 g/cm
Melting point 4 °C (39 °F; 277 K)
Boiling point 285 °C (545 °F; 558 K)
Hazards
Flash point 132 °C (270 °F; 405 K)
Autoignition
temperature 		240 °C (464 °F; 513 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

1-Hexadecene, also known as 1-cetene, is a long-chain hydrocarbon and an alkene with the molecular formula CH2=CH(CH2)13CH3. It is one of many isomers of hexadecene. Classified as an alpha-olefin, 1-hexadecene is a colorless liquid.

Uses

1-Hexadecene is used as a surfactant in lubricating fluid, a drilling fluid in the boring and drilling industry, and in paper sizing. It is used to functionalize hydrogen-terminated silicon surfaces by hydrosilation.

However, the high reactivity of 1-hexadecene means that exposure to air could cause oxidation of its surface layer, forming unwanted impurities. It is stored with the use of tank blanketing, and handled in a dry, inert atmosphere.

References

  1. ^ "1-Hexadecene for synthesis. CAS 629-73-2, chemical formula CH
    3(CH
    2)
    13CH=CH
    2"    . merckmillipore.com. Retrieved 2021-02-14.
  2. ^ "AlphaPlus 1-Hexadecene Safety Data Sheet" (PDF). Archived from the original (PDF) on 2019-09-24.
  3. Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke, Hartmut (2000). "Hydrocarbons". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a13_227. ISBN 3527306730.
  4. ^ "1-Hexacedene (Alpha Olefin C16)". Archived from the original on 2017-08-25. Retrieved 2017-07-07.
  5. "1-HEXADECENE (ALPHA-OLEFIN C16)". chemicalland21.com. Retrieved 2021-02-14.
  6. Sieval, A. B.; Demirel, A. L.; Nissink, J. W. M.; Linford, M. R.; Van Der Maas, J. H.; De Jeu, W. H.; Zuilhof, H.; Sudhölter, E. J. R. (1998). "Highly Stable Si−C Linked Functionalized Monolayers on the Silicon (100) Surface". Langmuir. 14 (7): 1759–1768. doi:10.1021/la971139z.
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